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Triclosan (TCS) is an anti-microbial agent used in down-the-drain consumer products. Following sewage treatment some of the triclosan will enter receiving waters. This study was designed to determine the die-away rate of triclosan released into a river as part of the sewage treatment plant effluent matrix. The study was conducted in Cibolo Creek, a moderate sized stream (discharge approximately 0.1 m(3)s(-1)) located in South Central Texas. Triclosan was analyzed from samples collected upstream of the sewage treatment plant, the sewage treatment plant effluent, and the river downstream from the effluent discharge. The first-order loss rate of parent triclosan from the water column was calculated from measured data (0.06 h(-1)) and this rate corresponded to a 76% reduction in triclosan over an 8 km river reach below the discharge. Mathematical modeling indicated that sorption and settling accounted for approximately 19% of total triclosan loss over 8 km. When removing sorption and settling, the remaining amount of triclosan had an estimated first-order loss rate of 0.25 h(-1). This loss rate was presumably due to other processes such as biodegradation and photolysis. These data show that loss of parent triclosan from the water column is rapid. Additional data are needed to fully document loss mechanisms. 相似文献
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Armin Kureck 《Die Naturwissenschaften》1992,79(12):533-540
Recently the fauna of the River Rhine (macrozoobenthos) has recovered, but the species composition has changed. Some formerly extinct species have returned, but new species, introduced from other regions, have successfully invaded the stream. These neozoans, mainly bivalves and crustaceans, obviously tolerate the changed conditions and the remaining pollution better than most of the original stream species 相似文献
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Phosphine by bio-corrosion of phosphide-rich iron 总被引:1,自引:0,他引:1
Dietmar Glindemann Frank Eismann Armin Bergmann Peter Kuschk Ulrich Stottmeister 《Environmental science and pollution research international》1998,5(2):71-74
Phosphine is a toxic agent and part of the phosphorus cycle. A hitherto unknown formation mechanism for phosphine in the environment was investigated. When iron samples containing iron phosphide were incubated in corrosive aquatic media affected by microbial metabolites, phosphine was liberated and measured by gas chromatography. Iron liberates phosphine especially in anoxic aquatic media under the influence of sulfide and an acidic pH. A phosphine-forming mechanism is suggested: Phosphate, an impurity of iron containing minerals, is reduced abioticly to iron phosphide. When iron is exposed to the environment (e.g. as outdoor equipment, scrap, contamination in iron milled food or as iron meteorites) and corrodes, the iron phosphide present in the iron is suspended in the medium and can hydrolyze to phosphine. Phosphine can accumulate to measurable quantities in anoxic microbial media, accelerating corrosion and preserving the phosphine formed from oxidation. 相似文献
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Schroeder Bruna Grosch Zanoni Patrícia Raquel Silva Magalhães Washington Luiz Esteves Hansel Fabricio Augusto Tavares Lorena Benathar Ballod 《Journal of Material Cycles and Waste Management》2017,19(1):463-472
Journal of Material Cycles and Waste Management - Finding innovative solutions to manage waste and to expand the production of biofuels are some of the current challenges. Pulp and paper sectors,... 相似文献
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Hora RR Ionescu-Hirsh A Simon T Delabie J Robert J Fresneau D Hefetz A 《Die Naturwissenschaften》2008,95(1):55-60
In the ectatommine ant Ectatomma tuberculatum, the visual appearance of queens changes after mating and ovarian development in that their cuticle turns from shiny to matte.
In this study, we have shown that this change seems to be caused by 15-fold accumulation of hydrocarbons, in particular heptacosane
that covers the multiple grooves present on the cuticular surface creating a wax coat in mated fully fertile queens. Analyses
of the scrapped wax revealed that it is composed largely of heptacosane. Peak-by-peak comparison of the cuticular hydrocarbon
(CHC) composition of mated, virgin with developed ovaries and virgin with nondeveloped ovaries revealed significant differences
between the queen groups. Although the total amount of the CHC of virgin queens with developed ovaries was not higher than
virgin queens that did not have developed ovaries, the composition showed a shift toward the mated queen. While it is possible
that the large accumulation of hydrocarbons may give extra physical and chemical protection to queens, we propose that the
switch in the relative abundance of heptacosane and nonacosane and perhaps of other components is indicative of being a mating
and fertility cue. This is the first report in social insects where external chemical changes are accompanied by changes in
visual appearance. 相似文献
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Realistic meteorological fields are a prerequisite for the determination of pollutant concentrations and depositions by means
of a chemistry transport model. Different configurations of the 5th generation NCAR/Penn State University mesoscale meteorological
model MM5 were tested to determine the optimum set up for long term hindcasts that cover several months up to years. Four
dimensional data assimilation (FDDA) significantly enhances the spatio temporal representation of temperature, humidity and
wind. Best agreement with radiosonde observations could be achieved when temperature, humidity and wind were grid nudged every
6 h. The quality of the resulting meteorological fields showed no significant systematic temporal or spatial variation over
Europe in a model run of the year 2000. It was found that the hydrological cycle was not correctly reproduced by the model
when no nudging was applied. The relevant model run showed too high relative humidity and too high rainfall when compared
to observations. This led to considerably lower aerosol concentrations close to ground and a shift in the deposition patterns
of particle bound pollutants like the carcinogenic benzo(a)pyrene (B(a)P).
Guest Editor: Dr. S. T. Rao. 相似文献