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31.
Sturm A  Radau TS  Hahn T  Schulz R 《Chemosphere》2007,69(4):605-612
Cadmium (Cd) adsorption on 14 non-calcareous New Jersey soils was investigated with a batch method. Both adsorption edge and isotherm experiments were conducted covering a wide range of soil composition, e.g. soil organic carbon (SOC) concentration ranging from 0.18% to 7.15%, and varying Cd concentrations and solution pH. The SOC and solution pH were the most important parameters controlling Cd partition equilibrium between soils and solutions in our experimental conditions. The Windermere humic aqueous model (WHAM) was used to calculate Cd adsorption on soils. The effect of solution chemistry (various pH and Cd concentrations) on Cd adsorption can be well accounted for by WHAM. For different soil compositions, SOC concentration is the most important parameter for Cd binding. Only a fraction of SOC, the so-called active organic carbon (AOC), is responsible for Cd binding. We found a linear relationship between SOC and AOC based on the adsorption edge data. The linear relationship was validated by the independent data sets: adsorption isotherm data, which presumably can be used to predict Cd partition equilibrium across a wide range of soil compositions. The modeling approach presented in this study helps to quantitatively predict Cd behavior in the environment.  相似文献   
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We performed a trace analytical study covering nine hormonally active UV-filters by LC-MS/MS and GC-MS in river water and biota. Water was analysed at 10 sites above and below wastewater treatment plants in the river Glatt using polar organic chemical integrative samplers (POCIS). Four UV-filters occurred in the following order of decreasing concentrations; benzophenone-4 (BP-4) > benzophenone-3 (BP-3) > 3-(4-methyl)benzylidene-camphor (4-MBC) > 2-ethyl-hexyl-4-trimethoxycinnamate (EHMC). BP-4 ranged from 0.27 to 24.0 μg/POCIS, BP-3, 4-MBC and EHMC up to 0.1 μg/POCIS. Wastewater was the most important source. Levels decreased with higher river water flow. No significant in-stream removal occurred. BP-3, 4-MBC and EHMC were between 6 and 68 ng/L in river water. EHMC was accumulated in biota. In all 48 macroinvertebrate and fish samples from six rivers lipid-weighted EHMC occurred up to 337 ng/g, and up to 701 ng/g in 5 cormorants, suggesting food-chain accumulation. UV-filters are found to be ubiquitous in aquatic systems.  相似文献   
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Ozone (O3) fluxes above a temperate mountain grassland were measured by means of the eddy covariance (EC) method using a slow-response O3 analyser. The resultant flux loss was corrected for by a series of transfer functions which model the various sources of high- and, in particular, low-pass filtering. The resulting correction factors varied on average between 1.7 and 3.5 during night and daytime, respectively. A cospectral analysis confirmed the accuracy of this approach. O3 fluxes were characterised by a comparatively large random uncertainty, which during daytime typically amounted to 60%. EC O3 fluxes were compared against O3 flux measurements made concurrently with the flux-gradient (FG) method. The two methods generally agreed well, except for a period between sunrise and early afternoon, when the FG method was suspected of being affected by the presence of photochemical sources/sinks. O3 flux magnitudes and deposition velocities determined with the EC method compared nicely with the available literature from grassland studies. We conclude that our understanding of the causes and consequences of various sources of flux loss (associated with any EC system) has sufficiently matured so that also less-than-ideal instrumentation may be used in EC flux applications, albeit at the cost of relatively large empirical corrections.  相似文献   
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Most species of the rove beetle genus Stenus employ the spreading alkaloid stenusine as an escape mechanism on water surfaces. In the case of danger, they emit stenusine from their pygidial glands, and it propels them over the water very quickly. Stenusine is a chiral molecule with four stereoisomers: (2′R,3R)-, (2′S,3R)-, (2′S,3S)-, and (2′R,3S)-stenusine. The percentile ratio of these four isomers is only known for the most common species of the genus: Stenus comma. With the intention of determining the stereoisomer ratios of five additional species from the two subgenera, Stenus and Hypostenus, we used GC/mass spectrometry measurements with a chiral phase. The results showed that the ratio differs among the genus. These findings can be a basis for chemotaxonomy. It is also possible that the biological function of stenusine, e.g., as antibiotic or fungicide, varies with changing stereoisomer composition.
Inka LusebrinkEmail:
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The possible liberation of highly toxic and mutagenic phosphine from putrefying media raises the question of its significance as a problem of hygiene. Free phosphine was established by gas chromatography as a universal trace component in gas emitted from the anaerobic biosphere. Sources of phosphine include landfills, compost processing, sewage sludge, animal slurry and river sediments. We detected maximum concentrations in the order of 20 ppb(v/v).  相似文献   
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Atmospheric mixing ratios of chlorinated C1 and C2 hydrocarbons (CHCs) were measured at the mountain Wank (Garmisch-Partenkirchen, Bavarian Alps) in autumn 1992. The data lead to the assumption that at least part of the observed CC14 originates from a source different to the other CHCs measured (C2HCL3, C2C14, CHCl3 and CH3CCl3). The nature of this source is discussed.  相似文献   
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