Modeling attitudes and perceptions as predictors for changing safety margins during organizational change

This study describes the relations between different dimensions of leadership commitment, safety climate and attitudes toward change, and how these affect employee perceptions of safety during organizational change in a high risk environment. We collected data from a European national air navigation services provider during a volatile 3-year corporatization process that ended in the sudden collapse of a deliberate change implementation project. Surprisingly, despite visible signs of internal and external stress caused by the volatile and disruptive change process, we did not observe any change in the traditional safety metrics of incident and accident reporting during the study. The study is based on a large survey (n = 422) of individual attitudes and perceptions of safety climate, perception of leadership commitment to safety, attitudes to organizational change, and perception of safety. The data support the claim that perception of safety at least, in part, depends on individual perceptions of the leadership’s commitment to safety, and the safety climate in place at a given point in time. The model shows how employee perceptions of the leadership’s commitment to safety and safety climate are related to both attitudes toward change, and to perceived safety.     

Taking Action Against Ocean Acidification: A Review of Management and Policy Options

Ocean acidification has emerged over the last two decades as one of the largest threats to marine organisms and ecosystems. However, most research efforts on ocean acidification have so far neglected management and related policy issues to focus instead on understanding its ecological and biogeochemical implications. This shortfall is addressed here with a systematic, international and critical review of management and policy options. In particular, we investigate the assumption that fighting acidification is mainly, but not only, about reducing CO₂ emissions, and explore the leeway that this emerging problem may open in old environmental issues. We review nine types of management responses, initially grouped under four categories: preventing ocean acidification; strengthening ecosystem resilience; adapting human activities; and repairing damages. Connecting and comparing options leads to classifying them, in a qualitative way, according to their potential and feasibility. While reducing CO₂ emissions is confirmed as the key action that must be taken against acidification, some of the other options appear to have the potential to buy time, e.g. by relieving the pressure of other stressors, and help marine life face unavoidable acidification. Although the existing legal basis to take action shows few gaps, policy challenges are significant: tackling them will mean succeeding in various areas of environmental management where we failed to a large extent so far.     

Natural variability in soil and runoff from small headwater catchments at Storgama, Norway

To provide baseline data for climate manipulation experiments in 11 small (30-268 m2) headwater catchments at Storgama, Telemark County, Southern Norway, we assessed the natural variability in site characteristics and runoff quality. Annual average concentrations in runoff at the sites have coefficients of variation between 26-61%, with the smallest values for total organic carbon (TOC) and carbon to nitrogen (C/N) ratios and the largest for inorganic nitrogen (N). The catchments have between two and five times higher concentrations of inorganic N, TOC, and total phosphorus than the larger (0.6 km2) Storgama watershed nearby. Concentrations of TOC and TON in runoff tend to increase with soil C and N content and with the volume of soil in the catchment. For nitrate (NO3) and ammonium in runoff, the reverse is true. In wet years the proportion of bare rock is a major predictor for the annual average NO3 concentration in runoff.     

Structural elucidation of main ozonation products of the artificial sweeteners cyclamate and acesulfame

Purpose  

The two artificial sweeteners cyclamate (CYC) and acesulfame (ACE) have been detected in wastewater and drinking water treatment plants. As in both facilities ozonation might be applied, it is important to find out if undesired oxidation products (OPs) are formed.     

Uptake and translocation of organophosphates and other emerging contaminants in food and forage crops

Emerging contaminants in wastewater and sewage sludge spread on agricultural soil can be transferred to the human food web directly by uptake into food crops or indirectly following uptake into forage crops. This study determined uptake and translocation of the organophosphates tris(1-chloro-2-propyl) phosphate (TCPP) (log K _ow 2.59), triethyl-chloro-phosphate (TCEP) (log K _ow 1.44), tributyl phosphate (TBP) (log K _ow 4.0), the insect repellent N,N-diethyl toluamide (DEET) (log K _ow 2.18) and the plasticiser N-butyl benzenesulfonamide (NBBS) (log K _ow 2.31) in barley, wheat, oilseed rape, meadow fescue and four cultivars of carrot. All species were grown in pots of agricultural soil, freshly amended contaminants in the range of 0.6–1.0 mg/kg dry weight, in the greenhouse. The bioconcentration factors for root (RCF), leaf (LCF) and seed (SCF) were calculated as plant concentration in root, leaf or seed over measured initial soil concentration, both in dry weight. The chlorinated flame retardants (TCEP and TCPP) displayed the highest bioconcentration factors for leaf and seed but did not show the same pattern for all crop species tested. For TCEP, which has been phased out due to toxicity but is still found in sewage sludge and wastewater, LCF was 3.9 in meadow fescue and 42.3 in carrot. For TCPP, which has replaced TCEP in many products and also occurs in higher residual levels in sewage sludge and wastewater, LCF was high for meadow fescue and carrot (25.9 and 17.5, respectively). For the four cultivars of carrot tested, the RCF range for TCPP and TCEP was 10–20 and 1.7–4.6, respectively. TCPP was detected in all three types of seeds tested (SCF, 0.015–0.110). Despite that DEET and NBBS have log K _ow in same range as TCPP and TCEP, generally lower bioconcentration factors were measured. Based on the high translocation of TCPP and TCEP to leaves, especially TCPP, into meadow fescue (a forage crop for livestock animals), ongoing risk assessments should be conducted to investigate the potential effects of these compounds in the food web.     

Life cycle assessment for printed newspapers in Northwestern Mexico

This paper aims to present the relevant results of a Life Cycle Assessment (LCA) study conducted on printed matter under a sheet-fed offset printing process by a company located in northwestern Mexico. Different scenarios were simulated in order to support decisions related to the improvement of environmental performance along the production processes. The study design was based on the European Platform on Life Cycle Assessment (EPLCA), which is in line with the ISO 14040 and 14044:2006 standards on LCA. The scope of the study was cradle-to-gate, with emphasis on the production of printed matter. The method chosen for the impact assessment was Impact 2002+ with a combined midpoint–damage approach. The results of the study showed that the major contributors to adverse effects were, primarily electricity consumption followed by paper consumption during the printing operation, as well as consumption of ink to a small degree. As for the plate-making operation along with the generation of secondary products, the result was negative. This is essentially due to involvement of recyclable materials, thus contributing to the prevention of raw material extraction. The smallest impact was observed from processes involving cleaning products and LP gas. The main issues of concern stemming from the results are electricity consumption and printing – both activities dominate almost all the midpoint categories. Generation of secondary products also had a relative environmental impact along the supply chain. Cleaning agents and LP gas did not have a significant impact on the final results of the process.     

Increased carbon dioxide availability alters phytoplankton stoichiometry and affects carbon cycling and growth of a marine planktonic herbivore

Rising levels of CO₂ in the atmosphere have led to increased CO₂ concentrations in the oceans. This enhanced carbon availability to the marine primary producers has the potential to change their nutrient stoichiometry, and higher carbon-to-nutrient ratios are expected. As a result, the quality of the primary producers as food for herbivores may change. Here, we present experimental work showing the effect of feeding Rhodomonas salina grown under different pCO₂ (200, 400 and 800 μatm) on the copepod Acartia tonsa. The rate of development of copepodites decreased with increasing CO₂ availability to the algae. The surplus carbon in the algae was excreted by the copepods, with younger stages (copepodites) excreting most of their surplus carbon through respiration and adult copepods excreting surplus carbon mostly as DOC. We consider the possible consequences of different excretory pathways for the ecosystem. A continued increase in the CO₂ availability for primary production, together with changes in the nutrient loading of coastal ecosystems, may cause changes in the trophic links between primary producers and herbivores.     

Priority organic micropollutants in water sources in Flanders and the Netherlands and assessment of removal possibilities with nanofiltration

The occurrence of organic micropollutants in ground- and surface waters has become an important concern for the drinking water industry, mainly because of possible related health effects. Due to the polar nature of some of these pollutants, they are not completely removed by traditional water treatment barriers. This paper offers an overview of priority organic micropollutants and their occurrence in Flemish and Dutch water sources. Furthermore, rejection by nanofiltration is qualitatively predicted for the selected priority micropollutants. The qualitative prediction is based on the values of key solute and membrane parameters in nanofiltration. Predicted values are then compared with experimental values obtained from literature. Overall, the qualitative predictions are roughly in agreement with literature values. Prediction based on key parameters may thus prove to be a very quick and useful technique to assess the implementation of nanofiltration as a treatment step for organic micropollutants in drinking water plant design.