Assessment of organochlorine pesticide pollution in Upper Awash Ethiopian state farm soils using selective pressurised liquid extraction

Upper Awash Agro Industry Enterprises (UAAIE) is one of the major state farms in Ethiopia with known large-scale pesticide use. Although organochlorine pesticides (OCPs) have been applied for about three decades, no studies have been carried out on levels of residue in the region. In this work a fast selective pressurised liquid extraction (SPLE) methodology has successfully been applied for screening of 13 OCPs in 12 soil samples from different fields in UAAIE, which further strengthen this methodology. Quantitative and qualitative analyses were done using a dual column gas chromatography-electron capture detection system (GC-ECD) and a GC equipped with a mass spectrometer (MS), respectively. The main contaminants identified comprised of previously used persistent organic pollutants (POPs) and currently used insecticides. Low concentrations or non-detectable levels of certain OCPs (aldrin, dieldrin, endrin, and heptachlor) indicate a positive phasing out of these persistent organic pollutants (POPs). Similarly HCHs were found in few soils and at low concentrations. Endosulfans and DDTs were detected in substantial amounts in the soils with Sigmaendosulfans up to 56000 and SigmaDDTs up to 230 ng g(-1) dry weight, which is a threat to the surrounding and downstream ecosystems, especially considering that the investigated OCPs constituted 29000 l of the 63000 l of pesticide applied annually on the fields. Additional concerns must be raised concerning synergistic effects of all pesticides added.     

Hydrogeochemical comparison and effects of overlapping redox zones on groundwater arsenic near the Western (Bhagirathi sub-basin, India) and Eastern (Meghna sub-basin, Bangladesh) margins of the Bengal Basin

Although arsenic (As) contamination of groundwater in the Bengal Basin has received wide attention over the past decade, comparative studies of hydrogeochemistry in geologically different sub-basins within the basin have been lacking. Groundwater samples were collected from sub-basins in the western margin (River Bhagirathi sub-basin, Nadia, India; 90 samples) and eastern margin (River Meghna sub-basin; Brahmanbaria, Bangladesh; 35 samples) of the Bengal Basin. Groundwater in the western site (Nadia) has mostly Ca-HCO(3) water while that in the eastern site (Brahmanbaria) is much more variable consisting of at least six different facies. The two sites show differences in major and minor solute trends indicating varying pathways of hydrogeochemical evolution However, both sites have similar reducing, postoxic environments (p(e): +5 to -2) with high concentrations of dissolved organic carbon, indicating dominantly metal-reducing processes and similarity in As mobilization mechanism. The trends of various redox-sensitive solutes (e.g. As, CH(4), Fe, Mn, NO(3)(-), NH(4)(+), SO(4)(2-)) indicate overlapping redox zones, leading to partial redox equilibrium conditions where As, once liberated from source minerals, would tend to remain in solution because of the complex interplay among the electron acceptors.     

Temporal variability of groundwater chemistry in shallow and deep aquifers of Araihazar, Bangladesh

Samples were collected every 2-4 weeks from a set of 37 monitoring wells over a period of 2-3 years in Araihazar, Bangladesh, to evaluate the temporal variability of groundwater composition for As and other constituents. The monitoring wells are grouped in 6 nests and span the 5-91 m depth range. Concentrations of As, Ca, Fe, K, Mg, Mn, Na, P, and S were measured by high-resolution ICPMS with a precision of 5% or better; concentrations of Cl were measured by ion chromatography. In shallow wells <30 m deep, As and P concentrations generally varied by <30%, whereas concentrations of the major ions (Na, K, Mg, Ca and Cl) and the redox-sensitive elements (Fe, Mn, and S) varied over time by up to +/-90%. In wells tapping the deeper aquifers >30 m often below clay layers concentrations of groundwater As were much lower and varied by <10%. The concentrations of major cations also varied by <10% in these deep aquifers. In contrast, the concentration of redox-sensitive constituents Fe, S, and Mn in deep aquifers varied by up to 97% over time. Thus, strong decoupling between variations in As and Fe concentrations is evident in groundwaters from shallow and deep aquifers. Comparison of the time series data with groundwater ages determined by (3)H/(3)He and (14)C dating shows that large seasonal or inter-annual variations in major cation and chloride concentrations are restricted to shallow aquifers and groundwater recharged <5 years ago. There is no corresponding change in As concentrations despite having significant variations of redox sensitive constituents in these very young waters. This is attributed to chemical buffering due to rapid equilibrium between solute and solid As. At two sites where the As content of groundwater in existing shallow wells averages 102 microg/L (range: <5 to 648 microg/L; n=118) and 272 microg/L (range: 10 to 485 microg/L; n=65), respectively, a systematic long-term decline in As concentrations lends support to the notion that flushing may slowly deplete an aquifer of As. Shallow aquifer water with >5 years (3)H/(3)He age show a constant As:P molar ratio of 9.6 over time, suggesting common mechanisms of mobilization.     

Total and Leachable Heavy Metals in Muddy and Sandy Sediments of Egyptian Coast Along Mediterranean Sea

The assessment of marine pollution due to metals was made for surficial sediments sampled from 20 sites along Mediterranean coast of Egypt. The samples were dried, acid digested and analyzed for leachable and total heavy metal contents (Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn) by flame atomic absorption spectrophotometer (air–acetylene) with deuterium background correction. Evaluation of the heavy metals pollution status was carried out using enrichment factors (EFs), the effect range-low (ERL) and the effect range-median (ERM). The study showed high concentrations of Cd, Co, Pb, Ni and moderate concentrations of Cr, Cu and Mn were contaminated in the sediments of studied sites. The results of Spearman correlation, factor and cluster analysis of the heavy metals analyzed in the collected sediment were discussed. The main source of contamination is the offshore oil field and industrial wastes, which arise due to the ineffective and inefficient operation equipments, illegal discharge and lack of supervision and prosecution of offenders.     

Trace metal contamination in commercial fish and crustaceans collected from coastal area of Bangladesh and health risk assessment

Environmental Science and Pollution Research - Trace metals contamination in commercial fish and crustaceans have become a great problem in Bangladesh. This study was conducted to determine seven...     

Waste high impact polystyrene (HIPS) microfiltration membranes for water treatment: A thorough experimental study

In our previous work, the prepared high-impact polystyrene (HIPS) membranes, synthesized using four concentrations (20, 25, 30, and 35 wt%) of waste HIPS, were proved to be promising for water purification by microfiltration process (MF). However, the fabricated membranes' mechanical properties and microfiltration process parameters were not investigated. Consequently, in this study, various parameters affecting the previously fabricated membranes' performance in the filtration process, such as membrane mechanical properties, feeding pressure, fouling behavior, and polymer concentration, were thoroughly investigated. With increasing polystyrene concentrations, the ultimate tensile strength of the fabricated membranes increased. When the concentration was increased from 20 to 25 wt percent, the elongation at break rose, but as the concentration was increased further, the membrane became brittle. Permeate flux and rejection both declined as polymer content was raised. Accordingly, the highest flux and humic acid (HA) rejection were shown by 20 wt% (14.18 L/m²h (LMH) and 98.95%, respectively). The antifouling properties declined when the polymer concentration was raised, and 20 wt% had the lowest total fouling resistance. Furthermore, the permeate flux was reduced while increasing the HA initial concentration.     

Exploring the therapeutic potential of omega-3 fatty acids in depression

Environmental Science and Pollution Research - Omega-3 fatty acids have been acknowledged for their number of holdings on an individual’s health. Not only in physical valuation but also in...     

Perception of household in regards to water pollution: an empirical evidence from Pakistan

Environmental Science and Pollution Research - Water pollution is one of the main threats to public health in Pakistan. The watchdogs for drinking water quality are toothless, hence...     

The influence mechanism of dissolved organic matter on the adsorption of Cd (II) by calcite

Environmental Science and Pollution Research - Dissolved organic matter (DOM) has been widely existed in the soil, which has great influence on the adsorption of heavy metals by minerals. In this...     

Recycling municipal,agricultural and industrial waste into energy,fertilizers, food and construction materials,and economic feasibility: a review

The global amount of solid waste has dramatically increased as a result of rapid population growth, accelerated urbanization, agricultural demand, and industrial development. The world's population is expected to reach 8.5 billion by 2030, while solid waste production will reach 2.59 billion tons. This will deteriorate the already strained environment and climate situation. Consequently, there is an urgent need for methods to recycle solid waste. Here, we review recent technologies to treat solid waste, and we assess the economic feasibility of transforming waste into energy. We focus on municipal, agricultural, and industrial waste. We found that methane captured from landfilled-municipal solid waste in Delhi could supply 8–18 million houses with electricity and generate 7140 gigawatt-hour, with a prospected potential of 31,346 and 77,748 gigawatt-hour by 2030 and 2060, respectively. Valorization of agricultural solid waste and food waste by anaerobic digestion systems could replace 61.46% of natural gas and 38.54% of coal use in the United Kingdom, and could reduce land use of 1.8 million hectares if provided as animal feeds. We also estimated a levelized cost of landfill solid and anaerobic digestion waste-to-energy technologies of $0.04/kilowatt-hour and $0.07/kilowatt-hour, with a payback time of 0.73–1.86 years and 1.17–2.37 years, respectively. Nonetheless, current landfill waste treatment methods are still inefficient, in particular for treating food waste containing over 60% water.