Morphology of single inhalable particle inside public transit biodiesel fueled bus

In an urban-transit bus,fueled by biodiesel in Toledo,Ohio,single inhalable particle samples in October 2008 were collected and detected by scanning electron microscopy and energy dispersive X-ray spectrometry(SEM/EDS).Particle size analysis found bimodal distribution at 0.2 and 0.5 μm.The particle morphology was characterized by 14 different shape clusters:square,pentagon,hexagon,heptagon,octagon,nonagon,decagon,agglomerate,sphere,triangle,oblong,strip,line or stick,and unknown,by quantitative order.The square particles were common in the samples.Round and triangle particles are more,and pentagon,hexagon,heptagon,octagon,nonagon,decagon,strip,line or sticks are less.Agglomerate particles were found in abundance.The surface of most particles was coarse with a fractal edge that can provide a suitable chemical reaction bed in the polluted atmospheric environment.The three sorts of surface patterns of squares were smooth,semi-smooth,and coarse.The three sorts of square surface patterns represented the morphological characteristics of single inhalable particles in the air inside the bus in Toledo.The size and shape distribution results were compared to those obtained for a bus using ultra low sulfur diesel.     

High bat (Chiroptera) diversity in the Early Eocene of India

The geographic origin of bats is still unknown, and fossils of earliest bats are rare and poorly diversified, with, maybe, the exception of Europe. The earliest bats are recorded from the Early Eocene of North America, Europe, North Africa and Australia where they seem to appear suddenly and simultaneously. Until now, the oldest record in Asia was from the Middle Eocene. In this paper, we report the discovery of the oldest bat fauna of Asia dating from the Early Eocene of the Cambay Formation at Vastan Lignite Mine in Western India. The fossil taxa are described on the basis of well-preserved fragments of dentaries and lower teeth. The fauna is highly diversified and is represented by seven species belonging to seven genera and at least four families. Two genera and five species are new. Three species exhibit very primitive dental characters, whereas four others indicate more advanced states. Unexpectedly, this fauna presents strong affinities with the European faunas from the French Paris Basin and the German Messel locality. This could result from the limited fossil record of bats in Asia, but could also suggest new palaeobiogeographic scenarios involving the relative position of India during the Early Eocene.     

Stakeholders' views towards flood risk management in the Paz River catchment area of Guatemala and El Salvador

The river Paz is a transboundary river that flows through Guatemala and El Salvador. Its frequent floods endanger the lives and livelihoods of downstream communities. Attempts have previously been made to develop flood management programmes for this watershed. However, these approaches were generally made by high-level governmental institutions with few if any contributions from floodplain communities and other stakeholders. Recognising that public consultation is a key aspect in flood management programmes, we intend in this work to extract different stakeholders' views regarding current and future flooding and flood management programmes in the Paz River basin. This is achieved using Future Scenarios Workshops with a projected time horizon of 30 years. The exercise was expected to identify consensual short- and medium–long-term flood management strategies for the Paz River basin that draws on input from inhabitants of flood-prone areas and other stakeholders.     

Three-phase partitioning for the separation of proteins,enzymes, biopolymers,oils and pigments: a review

Environmental Chemistry Letters - Modern biomass and organic waste are becoming major, carbon-neutral sources of fine chemicals, biomolecules and fuels to replace fossil fuel products. As a...     

Comparative performance study of different configurations of organic Rankine cycle using low-grade waste heat for power generation

This paper aims at analyzing the feasibility of a waste heat recovery power generation plant based on parametric optimization and performance analysis using different organic Rankine cycle configurations and heat source temperature conditions with working fluid R-12, R-123, R-134a, and R-717. A parametric optimization of turbine inlet temperature(TIT) was performed to obtain the irreversibility rate, system efficiency, availability ratio, turbine work output, system mass flow rate, second-law efficiency, and turbine outlet quality, along the saturated vapor line and also on superheating at an inlet pressure of 2.50 MP in basic as well as regenerative organic Rankine cycle. The calculated results reveal that selection of a basic organic Rankine cycle using R-123 as working fluid gives the maximum system efficiency, turbine work output, second-law efficiency, availability ratio with minimum system irreversibility rate and system mass flow rate up to a TIT of 150°C and appears to be a choice system for generation of power by utilizing the flue gas waste heat of thermal power plants and above 150°C the regenerative superheat organic Rankine cycle configuration using R 123 as working fluid gives the same results.     

Personal exposure measurement of students to various microenvironments inside and outside the college campus

This study characterizes the exposure of a typical Indian Institute of Technology Kanpur student to particulate matter and gaseous co-pollutants like carbon monoxide, volatile organic compounds, and nitrogen dioxide in various microenvironments, within and outside the college campus. Chemical analysis of filter, used for the particulate matter measurement, was also carried out to determine the concentration of various elements such as Ca, Cd, Cr, Cu, Fe, Mg, Pb, Zn, and anions like F^?, Cl^?, NO₃ ^?, and SO₄ ^2?. Furthermore, time activity diary along with temperature data was maintained for the precise evaluation and analysis of results for various microenvironments. The results showed PM₁₀ and PM_2.5 concentrations to be higher at some outdoor microenvironments, particularly near the Ganga riverbank. From the chemical analysis, concentrations of chloride and fluoride were found higher in indoor microenvironments as compared to outdoors. Also, nitrate concentrations were quite higher within the laboratory premises. Concentrations of Ca, Fe, and Mg were significant outdoors, whereas Na, Ca, Fe, and K were prominent indoors. The study highlights the real-time personal exposure of a student cohort to various toxic pollutants typically found within their breathing levels and their potential sources both indoors and outdoors.     

Development of an Ozone Forecasting Model for Non-Attainment Areas in the State of Ohio

Ground level ozone is responsible for the formation ofsmog, and for a variety of adverse effects on bothhuman and plant life. High concentrations of groundlevel ozone occur during the summer months. This paperdescribes the development of a model to forecast themaximum daily concentration of ozone as a function ofthe maximum surface temperature, for ozonenon-attainment regions in Ohio. The model wasdeveloped by statistical analysis of existing data.Site-specific models were developed initially. Theverification and evaluation of the performancecriteria of the model at each site were explored bycomparing the model with an independent datasetcollected from that site. A generalized statewidemodel was developed from the site-specific models. Theperformance criteria of this model were verified andevaluated by employing the same independent datasetsemployed for the site-specific models. An exceedencemodel to predict the occurrence of ozone exceedencesover 100 ppb has also been presented.     

Ecological Restoration of Coal Mine‐Degraded Lands in Dry Tropical Climate: What Has Been Done and What Needs to Be Done?

In developed countries, ecological restoration is a widely accepted practice to restore the productivity of degraded coal mine spoils and prevent mine‐degraded sites from acting as sources of pollution. During the past decade, ecologists realized the global need for ecological restoration, and the benefit of restoration is now assessed on the basis of ecosystem services that the restored lands can provide. In this article, the knowledge gap between crude reclamation and ecological restoration is examined, the steps crucial to ecological restoration in tropical conditions are identified, and simple guidelines are given for easy understanding. Restoration issues, such as modification of the forestry restoration approach, reestablishment of biodiversity, removal and reuse of topsoil during progressive and final stages of ecological restoration, drainage, promotion of a plant‐succession‐based approach, use of a grass–legume mixture as an initial colonizer, stabilization of steep slopes, and soil blanketing, are discussed. Those attributes of a degraded ecosystem that are responsible for the success of any restoration project are critically examined, and the opportunities provided by ecological restoration are explored.     

Cell cycle stage specific application of municipal landfill leachates to assess the genotoxicity in root meristem cells of barley (Hordeum vulgare)

Municipal solid wastes (MSW) are unavoidable sources of environmental pollution. Improper disposal of municipal waste results in the leaching of toxic metals and organic chemicals, which can contaminate the surface and ground water leading to serious health hazard. In this study, the toxic effects of the leachate prepared from municipal solid waste samples were examined in root meristem cells of barley (Hordeum vulgare L.) at various stages of cell cycle, i.e., G₁, S, and G₂. Seeds of barley were exposed to 2.5, 5, and 10 % of leachates in soil and aqueous media in 48 h at different cell cycle stages. The physicochemical data of the present study revealed that municipal solid waste leachate contains high amount of heavy metals, which significantly affected growth and physiological activities of barley. Significant inhibition in hypocotyl length, germination, and mitotic index were observed at all concentration of leachate treatment. Induction of chromosomal aberrations (CA’s) and micronuclei (MN) formation were also observed with different concentrations of leachate treatment at 7, 17, and 27 h of presoaking durations, which falls in G₁, S, and G₂ phase of the cell cycle, respectively. Also, exposure of leachate at S phase of the cell cycle had significant effects in barley through chromosomal aberration and micronuclei formation.