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31.
A process is presented to facilitate the sustainable management and development of tourist destinations. Based on a specific reforming of the Limits of Acceptable Change planning system and combined with the Tourism Carrying Capacity concept into a common framework, specific steps are described to integrate environmental, social and economic information of a tourist destination into indicators, which are afterwards compared with reference conditions. The Leopold matrix is applied to identify and classify restrictions of development and provide the basis for negotiations between managers, stakeholders and local communities. Through a feedback process of continuous monitoring and adjustment, the aim is to focus developmental activities on restricting factors until all indicators upgrade to reference. A case study at a Greek coastal municipality (Ilida western Greece) is applied to demonstrate the process. Activity zones are identified and 18 indicators are selected. Results suggest high potential for tourism development of the area. However, low scores are assigned to 8/18 indicators, reflecting restrictions, requiring priority under a sustainable development plan. The proposed process offers managers and stakeholders the ability to easily visualize/identify restrictions and assign developmental priorities within a step-by-step upgrading process, toward the sustainable management and development of tourist destinations.  相似文献   
32.
Sludge resulting from industrial waste water treatment at the industrial area of Patras, Greece, was spiked with cadmium, chromium and lead and entrenched in 4 experimental trenches. Soil from the unsaturated zone and sludge from the trenches were sampled at successive time points over a period of 14 months to monitor the movement of metals. Results showed that 94% of cadmium and 80% of lead but only 32% of chromium migrated from the sludge just 14 months after the entrenchment.

At the end of this time the buried sludge could be considered stabilised, as indicated by the total nitrogen content. Cd content in underlying soil layers at 3 m depth showed an increase in the first 7 months followed by a decrease, afterwards. Soil Pb concentration at 3 and 6 m depth was significantly high, in relation to it's initial concentration 14 months after the entrenchment. Pb and Cd in the soil samples were negatively correlated. It is suggested that lead displaces cadmium in the sediments.  相似文献   
33.
Municipal wastewater treatment results to the production of large quantities of sewage sludge, which requires proper and environmentally accepted management before final disposal. In European Union, sludge management remains an open and challenging issue for the Member States as the relative European legislation is fragmentary and quite old, while the published data concerning sludge treatment and disposal in different European countries are often incomplete and inhomogeneous. The main objective of the current study was to outline the current situation and discuss future perspectives for sludge treatment and disposal in EU countries. According to the results, specific sludge production is differentiated significantly between European countries, ranging from 0.1 kg per population equivalent (p.e.) and year (Malta) to 30.8 kg per p.e. and year (Austria). More stringent legislations comparing to European Directive 86/278/EC have been adopted for sludge disposal in soil by several European countries, setting lower limit values for heavy metals as well as limit values for pathogens and organic micropollutants. A great variety of sludge treatment technologies are used in EU countries, while differences are observed between Member States. Anaerobic and aerobic digestion seems to be the most popular stabilization methods, applying in 24 and 20 countries, respectively. Mechanical sludge dewatering is preferred comparing to the use of drying beds, while thermal drying is mainly applied in EU-15 countries (old Member States) and especially in Germany, Italy, France and UK. Regarding sludge final disposal, sludge reuse (including direct agricultural application and composting) seems to be the predominant choice for sludge management in EU-15 (53% of produced sludge), following by incineration (21% of produced sludge). On the other hand, the most common disposal method in EU-12 countries (new Member States that joined EU after 2004) is still landfilling. Due to the obligations set by Directive 91/271/EC, a temporary increase of sludge amounts that are disposed in landfills is expected during the following years in EU-12 countries. Beside the above, sludge reuse in land and sludge incineration seem to be the main practices further adopted in EU-27 (all Member States) up to 2020. The reinforcement of these disposal practices will probably result to adoption of advanced sludge treatment technologies in order to achieve higher pathogens removal, odors control and removal of toxic compounds and ensure human health and environmental protection.  相似文献   
34.
This research investigates the reception of the visual representations of a wind farm (WF) development by local stakeholders. Using non-verbal Qmethodology, residents of Lesvos’ island, Greece, sort images according to how these images represented their opinion about the proposed Aegean Link WF project. We found three opinion types. The “Risk Averter” type is focused on the various risks of constructing and operating the Aegean Link wind development. The “Green Developer” type believes that the renewable energy project will benefit both their local community and the environment. The “Realist” type defers to expert knowledge to make decisions about project outcomes and is sceptical of media bias. While the former two types seem to form their visual opinions based on whether they are in favour or against (respectively) of the WF development, the Realist opinion is rather guided by carefully considering whether the visual stimuli are representative of the project’s actual characteristics.  相似文献   
35.
Nitrate pollution from agriculture is an important environmental externality, caused by the excessive use of fertilizers. The internalization of this problem, via a tax on mineral nitrogen, could lead to a second best solution, reducing nitrate emissions. Several authors suggest that a reduction in agricultural support could produce similar results. In this paper, we examine the effects of different levels of a uniformly implemented nitrogen tax in France under two policy scenarios, corresponding to post Agenda 2000 and 2003 Luxembourg reforms of European Union’s Common Agricultural Policy, in order to reveal the synergies and conflicts between the tax and the policy scenarios in terms of nitrate emissions abatement. The analysis is performed at different geographical scales, from the national to the regional and is based on a bioeconomic approach that involves the coupling of the economic model AROPAj with the crop model STICS. Results show that the efficiency of the N-tax varies according to the geographical scale of the analysis and the type of farming. Furthermore, we prove that a uniform implementation may lead to perverse effects that should always be taken into account when introducing second-best instruments.  相似文献   
36.
Air quality impacts of volatile organic compound (VOC) and nitrogen oxide (NOx) emissions from major sources over the northwestern United States are simulated. The comprehensive nested modeling system comprises three models: Community Multiscale Air Quality (CMAQ), Weather Research and Forecasting (WRF), and Sparse Matrix Operator Kernel Emissions (SMOKE). In addition, the decoupled direct method in three dimensions (DDM-3D) is used to determine the sensitivities of pollutant concentrations to changes in precursor emissions during a severe smog episode in July of 2006. The average simulated 8-hr daily maximum O3 concentration is 48.9 ppb, with 1-hr O3 maxima up to 106 ppb (40 km southeast of Seattle). The average simulated PM2.5 (particulate matter with an aerodynamic diameter <2.5 μm) concentration at the measurement sites is 9.06 μg m?3, which is in good agreement with the observed concentration (8.06 μg m?3). In urban areas (i.e., Seattle, Vancouver, etc.), the model predicts that, on average, a reduction of NOx emissions is simulated to lead to an increase in average 8-hr daily maximum O3 concentrations, and will be most prominent in Seattle (where the greatest sensitivity is??0.2 ppb per % change of mobile sources). On the other hand, decreasing NOx emissions is simulated to decrease the 8-hr maximum O3 concentrations in remote and forested areas. Decreased NOx emissions are simulated to slightly increase PM2.5 in major urban areas. In urban areas, a decrease in VOC emissions will result in a decrease of 8-hr maximum O3 concentrations. The impact of decreased VOC emissions from biogenic, mobile, nonroad, and area sources on average 8-hr daily maximum O3 concentrations is up to 0.05 ppb decrease per % of emission change, each. Decreased emissions of VOCs decrease average PM2.5 concentrations in the entire modeling domain. In major cities, PM2.5 concentrations are more sensitive to emissions of VOCs from biogenic sources than other sources of VOCs. These results can be used to interpret the effectiveness of VOC or NOx controls over pollutant concentrations, especially for localities that may exceed National Ambient Air Quality Standards (NAAQS).

Implications: The effect of NOx and VOC controls on ozone and PM2.5 concentrations in the northwestern United States is examined using the decoupled direct method in three dimensions (DDM-3D) in a state-of-the-art three-dimensional chemical transport model (CMAQ). NOx controls are predicted to increase PM2.5 and ozone in major urban areas and decrease ozone in more remote and forested areas. VOC reductions are helpful in reducing ozone and PM2.5 concentrations in urban areas. Biogenic VOC sources have the largest impact on O3 and PM2.5 concentrations.  相似文献   
37.
Here, we describe for the first time the synthesis of [35S] PFOS and [35S] PFBS with sulfur-35 enriched sulfur dioxide as the radiolabelled reagent, resulting in 2.5 and 2.3 mCi of product, respectively. Basic information concerning the physicochemical properties of perfluorooctanesulfonate (PFOS), perfluorobutanesulfonate (PFBS) and perfluorooctanoic acid (PFOA) are still limited. Hence, we utilized these radiolabelled perfluoroalkanesulfonates (PFSAs), as well as carbon-14 labelled perfluorooctanoic acid ([14C] PFOA) to determine some basic characteristics of physiological and experimental significance.The solubility of PFOS in buffered aqueous solutions at pH 7.4 was found to be severely reduced in the presence of potassium and sodium ions, which, however, did not reduce the solubility of PFOA or PFBS. PFOS was found to adhere to a small extent to polypropylene and polystyrene, whereas no such adhesion of PFOA or PFBS was detected. The extents of adhesion of PFOS and PFOA to glass were found to be 20% and 10%, respectively. For the first time, the partition coefficients for PFOS, PFBS and PFOA between n-octanol and water were determined experimentally, to be −0.7, −0.3, and 1.4, respectively, reflecting the difference in the amphiphilic natures of these molecules.  相似文献   
38.
Cai QY  Mo CH  Wu QT  Zeng QY  Katsoyiannis A 《Chemosphere》2007,68(9):1751-1762
This study presents the occurrence of 43 semi-volatile organic compounds (SVOCs) listed as priority pollutants by both China and the United States Environmental Protection Agency, in sewage sludges collected from eleven wastewater treatment plants (WWTPs) of mainland and Hong Kong, China. Thirty-six SVOCs were detected by gas chromatography coupled with mass spectrometer (GC-MS) and at least 14 in each sample. The most abundant compounds were phthalic acid esters (PAEs) and polycyclic aromatic hydrocarbons (PAHs) with total concentrations ranging from 10 to 114mgkg(-1) dry weight (d.w.) (with a mean of 30mgkg(-1) d.w.) and from 1.4 to 33mgkg(-1)d.w. (with a mean of 16mgkg(-1) d.w.), respectively, followed by chlorobenzenes, nitroaromatics, haloethers and halogenated hydrocarbons which occurred generally at concentrations lower than 10mgkg(-1) d.w. Large variations were observed between the concentrations of individual compounds as well as their total concentrations in sludge samples from different WWTPs. The highest values of sum concentration of 16 PAHs and of 6 PAEs were found in sewage sludge from Beijing. The mean total concentration of each class of SVOCs in sewage sludge from mainland was remarkably higher than that from Hong Kong. The concentrations of di(2-ethylhexyl) phthalate in 91% sludge samples met the limit (100mgkg(-1)d.w.) proposed by the Europe Union for land application, whereas the PAH concentrations of 64% sludge samples exceeded the maximum permissible concentration (6.0mgkg(-1)d.w.). The occurrence of SVOCs in this study are compared with other studies and their sources are discussed.  相似文献   
39.
ABSTRACT: The spatial distribution and the temporal and spatial variation of the annual, seasonal, and monthly precipitation in two mountainous watersheds in southwestern British Columbia, Canada, have been analyzed using a detailed database for 1971–1990 in the Capilano and Seymour watersheds. The analysis showed that the precipitation increases up to the mid-position of the watersheds, and then either levels off or decreases. Precipitation on mountain slopes and in the valley at the same distance from the beginning of the slope is similar, and the barrier height is identified as the dominant parameter which influences the precipitation distribution. The temporal variation of the precipitation is the smallest at the mid-position of the watersheds. This variability is the least in the fall and winter and largest in the summer. Correlation between the precipitation accumulations at various stations is large, ranging from 0.80 for the wet period of October-March to 0.65 for the dry period of April-September for distances less than 32 km. Comparison with other studies and the analyses of precipitation and runoff data from coastal British Columbia showed that the results of this study are perhaps general and thus transferable to similar areas in the coastal Pacific Northwest.  相似文献   
40.
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