Alterations in serum electrolyte levels after dimethoate exposure and recovery in the freshwater air-breathing catfish,Heteropneustes fossilis (Bloch)

Dimethoate, a moderately toxic insecticide, has a wide range of agricultural and domestic applications. Like other organophosphates, dimethoate has anticholinesterase activity. Fish are non-target organisms, inadvertently exposed to pesticides and their metabolic products. The present study includes short-term (96 h) and long-term (36 d) effects of dimethoate exposure on some serum electrolytes Ca²⁺, Mg²⁺, and Pi in the freshwater air-breathing catfish Heteropneustes fossilis. The concentration of dimethoate for short-term exposure was 2.24 mg L^?1 (75% of 96 h LC₅₀) and for long-term exposure 0.75 mg L^?1 (25% of 96 h LC₅₀). The study includes the recovery pattern in serum electrolytes after placing the fish in pesticide-free water. Fish show hypocalcemia, hypermagnesemia, and hyperphosphatemia after short-term and long-term exposure to dimethoate. When placed in pesticide-free water, these electrolytes exhibit recovery towards normalization, indicating significant (p < 0.05) recovery.     

Cerium dioxide and composites for the removal of toxic metal ions

The presence of contaminants in potable water is a cause of worldwide concern. In particular, the presence of metals such as arsenic, lead, cadmium, mercury, chromium can affect human health. There is thus a need for advanced techniques of water decontamination. Adsorbents based on cerium dioxide (CeO₂), also named ‘ceria,’ have been used to remove contaminants such as arsenic, fluoride, lead and cadmium. Ceria and composites display high surface area, controlled porosity and morphology, and abundance of functional groups. They have already found usage in many applications including optical, semiconductor and catalysis. Exploiting their attractive features for water treatment would unravel their potential. We review the potential of ceria and its composites for the removal of toxic metal ions from aqueous medium. The article discusses toxic contaminants in water and their impact on human health; the synthesis and adsorptive behavior of ceria-based materials including the role of morphology and surface area on the adsorption capacity, best fit adsorption isotherms, kinetic models, possible mechanisms, regeneration of adsorbents; and future perspectives of using metal oxides such as ceria. The focus of the report is the generation of cost-effective oxides of rare-earth metal, cerium, in their standalone and composite forms for contaminant removal.     

Iron-based flow batteries to store renewable energies

The development of cost-effective and eco-friendly alternatives of energy storage systems is needed to solve the actual energy crisis. Although technologies such as flywheels, supercapacitors, pumped hydropower and compressed air are efficient, they have shortcomings because they require long planning horizons to be cost-effective. Renewable energy storage systems such as redox flow batteries are actually of high interest for grid-level energy storage, in particular iron-based flow batteries. Here we review all-iron redox flow battery alternatives for storing renewable energies. The role of components such as electrolyte, electrode and membranes in the overall functioning of all-iron redox flow batteries is discussed. The effect of iron–ligand chemistry on the performance of battery is highlighted. Additionally, a brief contextual background and fundamentals of redox flow batteries are provided. The design aspects, progress in research, mathematical modeling, cost estimations and future prospects of using all-iron energy systems are discussed in the context of future grid-level energy storage.     

Evaluation of genotoxic potential of industrial waste contaminated soil extracts of Amritsar, India

The rapid increase in population together with unplanned disposal of effluents from various industries has resulted in accumulation of various heavy metals like As, Cr, Cu, Hg, Ni, Pb and Zn in soil ecosystem which ultimately causes DNA damage in living systems. Considering this, the present study was designed to evaluate the content of various heavy metals (Cu, Cr, Co, Hg, Mn, Ni, Zn) and genotoxicity/mutagenicity of soil samples collected from the outskirts of two industries viz. zinc coating industry (SI) and copper sulphate manufacturing industry (SII) employing Allium root anaphase aberration assay (A/RAAA) and Ames assay. The physicochemical parameters like bulk density, water holding capacity, moisture content, pH, nitrates, phosphates and potassium were also estimated. It was observed that SI sample contained Ni (6.86 mg g-1), Zn (6.53 mg g-1), Co (5.05 mg g-1) and Cr (4.49 mg g-1), while SII contained Cu (32.86 mg g-1), Ni (9.66 mg g-1), Co (6.85 mg g-1) and Zn (5.41 mg g-1). In A/RAA assay, the percentage of cells with anaphase aberrations ranged from 3.63 to 10.67 and 0.38 to 4.83% for samples SI and SII, respectively. In Ames test, sample SII was found to be lethal to Salmonella tester strains at all concentrations used, while sample SI was found to be mutagenic in TA100 strains of Salmonella typhimurium. Sample SII was found to be strongly acidic with pH 3.46. The present study focuses on the increasing heavy metal pollution in Amritsar city due to industrial discharges over lands and also infers that both bioassays Ames and A/RAAA can serve as first alert indication of pollution.     

Typifying cities to streamline the selection of relevant environmental sustainability indicators for urban water supply and sewage handling systems: a recommendation

Measuring performance and setting targets and benchmarks for the future entail the adoption of metrics or indicators. Sustainability is a multi-pronged objective encompassing social, economic, health, cultural, governance and environmental aspects. Indicators can be grouped under these categories. The selection of environmental sustainability indicators for a water and wastewater utility in a city needs to be based on concerns specific to the utility in question. The authors, in this paper, have recommended the classification of cities into city types based on specific attributes and identification of relevant environmental sustainability indicators, from a pool of 13 indicators, for these different city types. Having selected the relevant indicators, utilities can use them as tools to improve their environmental performance. The purpose is to not facilitate inter-utility comparisons within or across city types. Every utility would compare its environmental performance at a given point in time with what it was in the past. Towards the end, the paper also applies the methodology to nine cities across four continents—Europe (Oslo, Trondheim and Turin), Asia (the National Capital Territory of Delhi, Beijing, Tel Aviv and Male), North America (Sacramento) and South America (São Paulo). In all, 13 environmental sustainability indicators have been identified. Two cities—Oslo and Trondheim (both from Norway) belong to the same city type, while the other seven are different from each other in this regard. The number of relevant indicators ranged from 4 for Trondheim to 11 for Tel Aviv. The methodology is not restricted to urban water supply and sewage handling systems. It can be extended to other infrastructure systems as well—waste management, transportation, etc.     

Micronuclei frequency in lymphocytes and antioxidants in the blood of traditional limited-resource farm workers exposed to pesticides

Chronic low-level exposure to synthetic pesticides is implicated in many health conditions that result from the induction of oxidative stress, including cytogenetic damage. The objective of this study was to assess the risk of genotoxicity using micronuclei (MN) formation in lymphocytes and to determine changes in blood antioxidants superoxide dismutase (SOD) in erythrocytes (E) and glutathione (GSH) in E and plasma (PL) in farm workers for six months during a growing season. Blood and urine samples were collected once a month for six months (June to November 2003) from farm workers (n = 15) and urban unexposed controls (n = 10). Lymphocytes from blood were separated by density gradient centrifugation using Histopaque and cultured using the standard technique. There was no significant difference in the cytokinesis blocked proliferation index (CBPI) of lymphocytes between the farm workers and the control group, but there was a 76% increase in average MN frequency in lymphocytes of the farm worker group (P 相似文献   

Induction of apoptosis in A431 cells via ROS generation and p53-mediated pathway by chloroform fraction of Argemone mexicana (Pepaveraceae)

Environmental Science and Pollution Research - Argemone mexicana(Pepaveraceae) is an important medicinal plant commonly known as ‘maxican prickly poppy’ and is traditionally used to...     

Performance studies of low GWP refrigerants as environmental alternatives for R134a in low-temperature applications

Environmental Science and Pollution Research - Climate change is an important environmental issue that is causing global temperatures to rise. The primary environmental targets are to reduce carbon...     

Synergy of Sentinel-2A and Near-proximal sensor data for deriving biochemical parameters of paddy at different growth stages

Environment, Development and Sustainability - The biochemical parameters (i.e. chlorophyll and nitrogen content) of crops are essential to evaluate the health status and to monitor crop growth. The...