首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   5072篇
  免费   871篇
  国内免费   1421篇
安全科学   770篇
废物处理   141篇
环保管理   482篇
综合类   3739篇
基础理论   793篇
环境理论   2篇
污染及防治   513篇
评价与监测   330篇
社会与环境   319篇
灾害及防治   275篇
  2024年   34篇
  2023年   129篇
  2022年   347篇
  2021年   354篇
  2020年   443篇
  2019年   291篇
  2018年   317篇
  2017年   296篇
  2016年   280篇
  2015年   335篇
  2014年   318篇
  2013年   414篇
  2012年   476篇
  2011年   458篇
  2010年   444篇
  2009年   369篇
  2008年   363篇
  2007年   434篇
  2006年   357篇
  2005年   240篇
  2004年   197篇
  2003年   114篇
  2002年   104篇
  2001年   83篇
  2000年   62篇
  1999年   44篇
  1998年   8篇
  1997年   6篇
  1996年   7篇
  1995年   12篇
  1994年   9篇
  1993年   3篇
  1992年   3篇
  1991年   3篇
  1990年   2篇
  1989年   4篇
  1983年   1篇
  1971年   1篇
  1967年   1篇
  1964年   1篇
排序方式: 共有7364条查询结果,搜索用时 15 毫秒
31.
A first derivative spectrophotometric method has been developedfor the determination of parathion and p-nitrophenol in vegetabletissues. Ethanol was used as solvent for extracting the compoundsfrom the tissues and subsequently the samples were evaluated against a vegetable tissue blank, directly by derivative spectrophotometry. The simultaneous determination of these compounds can be carried out using the zero-crossing approach for parathion at 253.0 nm and for p-nitrophenol at 273.1 nm. In the samples each analyte was determined in the presence of one another in the ranges between 4.9 to 3883.5 g g-1 forparathion and 4.9 to 3285.3 g g-1 for p-nitrophenol.The detection limits (3) were found to be 1.5 and 1.4 g g-1 for parathion and p-nitrophenol, respectively. The relative standard deviations were in all instances less than1.8%. The proposed method was applied to the determination ofthe analytes in spiked leafs of corn. The results show a goodrecovery and they are in agreement with those obtained bypolarography.  相似文献   
32.
The aim of this study was to analyse the relationship between the distribution of hay-fever patients in the city of Córdoba, south-western Iberian Peninsula, and the specific atmospheric biological content originating from local sources. Four different districts were established in the metropolitan area of the city, according to vegetational and urbanistic characteristics. Air samples were taken in each area using portable Hirst-type samplers (Lanzoni VPPS 1000) and the spectrum of biological content was defined. Patients attending the Allergy Unit at Córdoba Teaching Hospital in 2000 with allergic rhinitis and/or asthma, and displaying a positive reaction to aeroallergen extracts, were distributed within the areas as a function of their district of residence. Aerobiological results revealed differences in pollen content between areas, in terms of both quantity and number of pollen types recorded. These differences were largely due to proximity to rural areas, prevalence of pollen from typically urban species and the possible effect of urban architecture as a barrier to the dispersal/ concentration of particles and other pollutants. Patients were not uniformly distributed within the city. The majority lived in districts in which pollen from rural species was mixed with pollen from ornamentals. Patients living in typically urban districts displayed a higher prevalence of allergy to pollen from ornamentals. It is concluded that a high degree of exposure to the same environment may influence the development of sensitisation to the particular pollen load associated with that area.  相似文献   
33.
The optimisation of a simple multielement extraction method employing an experimental design approach is described. The method uses centrifugation to pass one extractant solution at varying pH through a contaminated soil sample. The nature and concentration of the acid, rate of centrifugation and time, number of sequential leachates and the ratio of extractant volume: sample weight have been studied in order to obtain the optimum conditions for extraction. A fractional factorial experimental design was performed, and the results were used to identify significance which was then evaluated by carrying out a central composite experimental approach. Once optimum conditions had been obtained, sequential leaches were analysed by ICP-AES and chemometrics were employed to identify the composition of each component. Comparisons have been made with previous studies and tentative assignments, based on well defined separated fractions and percentage compositions for individual elements, used to identify the different physico-chemical components in the sample.  相似文献   
34.
Passive diffusion samplers were employed in San Miguel(Buenos Aires Metropolitan Area) for a preliminary airpollution monitoring. The highest loads were observedin downtown, compared with an urban background site.Total suspended particulate matter (TSPM) varied from0.257 to 0.033 mg cm-2 month-1; dust was examinedfor particle nature and size distribution. A similartrend was observed for nitrogen dioxide (NO2) andTSPM spatial distribution, suggesting that traffic isthe major pollution source. Sulphur dioxide (SO2)values were low and rather homogeneous. Levels for theinvestigated pollutants are below EPA's guide linevalues. Geographic (flat area, near to Rio de LaPlata) and climatologic factors (rainfalls andvariable wind directions) contribute to disperse pollutants.  相似文献   
35.
罗耀宗 《上海环境科学》1992,11(1):49-50,48
对含柠檬酸盐电镀废水的几种处理方法的比较表明,氯化钡添加法能较好地使柠檬酸盐沉淀,操作简便,处理效果理想,其柠檬酸根离子的去除率达98%以上。  相似文献   
36.
金属铁还原降解2,4-二硝基甲苯的实验研究   总被引:1,自引:0,他引:1  
研究了金属铁对2,4-二硝基甲苯(2,4-DNT)的还原降解情况.实验结果表明,2,4-DNT的还原降解与溶液初始pH值、初始浓度和溶解氧等因素有关.氯离子能消除金属铁的钝化现象.金属铁表面附载的铜对2,4-DNT的还原降解具有催化作用.  相似文献   
37.
膨润土吸附-絮凝法处理污水中的重金属离子   总被引:8,自引:0,他引:8       下载免费PDF全文
研究了天然膨润土对Pb ̄(2+)、Cd ̄(2+)、Cr ̄(3+)的吸附和膨润土的絮凝沉降条件,将吸附与絮凝过程结合起来形成处理污水的新工艺,加入0.04%膨润土和0.006%的PAC可使低浓度污水中Pb ̄(2+)脱除93.1%。  相似文献   
38.
讨论了铜在淡水藻(Scenedesmus subspicatus86.81SAG)细胞壁和细胞内分布规律,以及乙二胺四乙酸(EDTA)和水体腐殖酸(FA)存在下对铜分布的影响,研究结果表明,EDTA和FA的存在显著降低了细胞表面铜的吸附量,但是不影响细胞内铜的浓度,对测定数据进行分析。可以认为溶液相铜与EDTA或FA形成的铜络合物是生物无效形态,不参与铜在藻细胞壁上特定位点或生物配体的竞争结合反应。  相似文献   
39.
生态工业园区是一种以追求更高物质利用率和能量转化效率,更少废物排放甚零排放为目标的企业地域分布形式,环境保护意义和生态绿色概念的工业园区.为了能够获得最大的生态效益,就要从源头开始提高招商引资的质量,制定一个绿色招商的指标体系,设置绿色门槛,把好环保关,为园区的可持续发展奠定良好的基础.  相似文献   
40.
萜烷作为溢油指物(或指标)的研究   总被引:3,自引:0,他引:3  
用毛细管GC-MS对溢油中的萜烷进行分析,结果表明,在一年多的风化过程中,作为溢油指示物(或指标)的萜烷及其比值参数,受风化影响很小。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号