Maternal and cord blood levels of Aldrin and Dieldrin in Delhi population

Aldrin and dieldrin, structurally similar organochlorine pesticides belong to cyclodiene family and were widely used for agriculture and public health program in India. Although the manufacturing, use and import of aldrin and dieldrin have been banned in India since 2003, these pesticides are still persistent in environment and may be associated with adverse neurological and reproductive effects. The aim of this study is to assess the recent exposure level of aldrin and dieldrin and their placental transfer to fetus in normal healthy full-term pregnant women belonging to north Indian population undergoing normal delivery at Obstetrics and Gynecology department of UCMS and GTB hospital, Delhi. Quantitative analysis of aldrin and dieldrin residues in maternal and cord blood samples were carried out by gas chromatography system equipped with electron capture detector. The results of our study clearly revealed that maternal and cord blood levels of aldrin and dieldrin of pregnant women are age and dietary habit dependent. The aldrin level in maternal blood and dieldrin level in cord blood are higher in women in the age group 25–30 years than in women in age group of 19–24 years. Similarly, aldrin level in maternal blood is significantly higher in women with non-vegetarian dietary habit than in women with vegetarian dietary habit. No significant association is found for maternal and cord blood level. The results of the present study clearly demonstrate prenatal uptake of aldrin and dieldrin and provide recent information on the subsequent transplacental transfer.     

Natural product biomarkers as indicators of sources and transport of sedimentary organic matter in a subtropical river

The sources and transformations of sedimentary organic matter along the Harney River, a representative subtropical river of the Florida Everglades, were assessed using a natural product biomarker approach. Sediment samples were collected from the headwaters to the Continental Shelf, with characteristic vegetation dominated by freshwater marsh species, mangrove (middle to lower estuary), and seagrass as the marine end-member. A peat sample was collected inland. All sample extracts were analyzed by GC–MS as underivatized and as silylated compounds. With these total extract analyses, major compound classes can be defined: n-alkanols, n-alkanoic acids, methyl alkanoates, methyl - and ω-hydroxyalkanoates, triterpenoids, phytosterols and saccharides, with traces of hydrocarbons. In general, the peat sample extract has a different overall composition compared to the sediment extracts. The major differences include distinct carbon number maxima for the lipid series (e.g., C_max = 28 for n-alkanols) probably from sawgrass and periphyton biomass, and predominance of phytosterols (sitosterol and stigmasterol) from higher plant detritus. In contrast, river sediment extracts contain biomarkers predominantly from mangrove-derived organic matter, such as the triterpenoids taraxerol and myricadiol. Significant amounts of saccharides and ω-hydroxyalkanoates are also found. Generally, compound concentrations decrease downstream due to dilution, and alteration of organic compounds from plant waxes and coastal vegetation is obvious in both peat and sediment samples. This is confirmed by the significant low abundance of n-alkanes and n-alkenoic acids due to biodegradation, oxidation of -tocopherol to homophytanic acid γ-lactone, and presence of traces of dihydrolacunosic acid, a photochemical alteration product of taraxerol.     

Visible light sensitive activated carbon-metal oxide (TiO2, WO3, NiO,and SnO) nano-catalysts for photo-degradation of methylene blue: a comparative study

Four composites of metal oxide doped with activated carbon with a metal oxide weight of 20% were prepared using mechano-mixing method. The nano-catalysts were characterized by N₂-adsorption–desorption, X-ray diffraction analysis, transmission electron microscopy, Fourier-transform infrared spectroscopy, UV-diffuse reflectance, and photoluminescence spectroscopy. Photo-catalytic degradation of methylene blue dye under UV 254 nm and visible light was examined. In general, prepared catalysts are more active for degradation of dye under visible light than UV, reaching 96% within 180?min irradiation using the SnO catalyst. Photo-degradation of methylene blue followed pseudo first order reaction mechanism with a rate constant of 14.8?×?10^?3?min^?1, and the time required for removal of 50% of dye was 47?min.     

ESTIMATING WATER BUDGET IN A REGIONAL AQUIFER USING HSPF‐MODFLOW INTEGRATED MODEL1

ABSTRACT: Integrated water resources management is important, especially in watersheds where substantial interactions exist between the ground and surface water sources. This management warrants the need for reliable estimates of both an overall basin water budget and hydrologic fluctuations between ground water and surface water sources. The objectives of this study were to estimate the total water budget and to simulate the effects of the management of water in the Big Lost River Basin in Idaho. The study used the FIPR Hydrological Model (FHM), a hydrological model developed by the University of South Florida for the Florida Institute of Phosphate Research (FIPR). The FHM is an integrated model that simulates the full water budget of the surface and ground water systems. It has two public domain components: Hydrological Simulation Program ‐ FORTRAN (HSPF) and Modular Three‐Dimensional Finite‐Difference Ground Water Flow Model (MODFLOW). This study quantified the hydrologic fluxes between ground water and surface water and determined a comprehensive and accurate water budget for the Big Lost River. The study showed an annual amount of 10.44 m3/sec leaves the basin and never to return to the system. The study is useful in developing and calculating the annual water budget in the Big Lost River, and this process should be applicable to estimating water budgets in other basins.     

EVAPOTRANSPIRATION CONCEPTUALIZATION IN THE HSPF‐MODFLOW INTEGRATED MODELS1

In 1988, the Florida Institute of Phosphate Research (FIPR) funded project to develop an advanced hydrologic model for shallow water table systems. The FIPR hydrologic model (FHM) was developed to provide an improved predictive capability of the interactions of surface water and ground water using its component models, HSPF and MODFLOW. The Integrated Surface and Ground Water (ISGW) model was developed from an early version of FHM and the two models were developed relatively independently in the late 1990s. Hydrologic processes including precipitation, interception, evapotranspiration, runoff, recharge, streamflow, and base flow are explicitly accounted for in both models. Considerable review of FHM and ISGW and their applications occurred through a series of projects. One model evolved, known as the Integrated Hydrological Model IHM. This model more appropriately describes hydrologic processes, including evapotranspiration fluxes within small distributed land‐based discretization. There is a significant departure of many IHM algorithms from FHM and ISGW, especially for soil water and evapotranspiration (ET). In this paper, the ET concepts in FHM, ISGW, and IHM will be presented. The paper also identifies the advantages and data costs of the improved methods. In FHM and IHM, ground water ET algorithms of the MODFLOW ET package replace those of HSPF (ISGW used a different model for ground water ET). However, IHM builds on an improved understanding and characterization of ET partitioning between surface storages, vadose zone storage, and saturated ground water storage. The IHM considers evaporative flux from surface sources, proximity of the water table to land surface, relative moisture condition of the unsaturated zone, thickness of the capillary zone, thickness of the root zone, and relative plant cover density. The improvements provide a smooth transition to satisfy ET demand between the vadose zone and deeper saturated ground water. While the IHM approach provides a more sound representation of the actual soil profile than FHM, and has shown promise at reproducing soil moisture and water table fluctuations as well as field measured ET rates, more rigorous testing is necessary to understand the robustness and/or limitations of this methodology.     

Studies on the maturation-accelerating pheromone of the desert locustSchistocerca gregaria (Orthoptera: Acrididae)

Summary The accelerating effect of mature males of the desert locust,Schistocerca gregaria, on the maturation of immature male and female conspecifics was confirmed. The onset of sexual activity was found to correlate with yellowing of the male insects. Using the colour as an indicator of maturation, the maturation-hastening effect of an hexane extract from mature males was also confirmed. Likewise, volatiles from mature males placed in the upper storey of a two-chamber bioassay system (no visual or tactile contact possible) and charcoal-trapped volatiles from the mature males also induced accelerated maturation in recipient males placed in the lower storey. GC and GC-MS analysis of volatiles collected from 4-week-old mature males showed the presence of anisole, benzaldehyde, veratrole, phenylacetonitrile and 4-vinylveratrole, roughly at the ratio 4.8:7.0:3.3:79.8:5.0. In addition, guaiacol, phenol, benzoylnitrile, benzyl alcohol and 2-benzoyloxyphenylacetonitrile were present in smaller amounts. These compounds were either absent or found only in trace amounts in the female volatiles. Earlier, we had shown that essentially the same blend collected from younger males (10–20 d old, not yet demonstrating signs of maturation) induced strong aggregation of both sexes of adult desert locusts, suggesting a parsimonious role for the pheromone system: as an adult aggregation signal and as a maturation accelerant in young adults.     

A Comparative Study On the Levels of Trace Metals in Some Mediterranean and Red Sea Fishes

Samples of Mugil cephalus, Liza ramada, Siganus luridus, Siganus rivulatus, Epinephelus alexandrinus, Epinephelus areolatus, Epinephelus fasciatus, Epinephelus chlorostigma, Cephalopholis argus and Cephalopholis sonnerati were collected from the Mediterranean and Red Seas and their muscle and bone analyzed by AAS for some trace metals (Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd, Pb). the results showed that these metals accumulate in the bones to a greater extent than in the muscle. the highest accumulated element is cobalt (4.7-20.8 times), while the lowest is lead (1.1-2.5 times). the accumulation is more pronounced in Red Sea species than in Mediterranean species. the elevated levels of lead in Mugil cephalus (2.6-3.0 mg kg^-1) and Epinephelus alexandrinus (3.0-3.9 mg kg^-1) were attributed to the intake in food in the polluted environment of Alexandria coastal water. the relationship between body size and concentration of trace metals using a standard linear regression technique gives a significant positive correlation for cobalt, manganese, iron and lead in the muscle, as well as for lead in the bones of Mugil species from the Red Sea, while the Mediterranean species showed little correlation.

There is a tendency for increased concentrations of the essential metals manganese, iron and copper with increasing trophic level of the fish, while the opposite is true for the toxic metals chromium and lead. Our results indicate that there is no risk from toxic metal concentrations in muscle of fish from the Mediterranean and Red Seas consumed by man even in contaminated areas.     

Treatment of oily refinery wastes using a dissolved air flotation process

Refinery wastewater from Moustorod oil refinery, Cairo, Egypt, was treated by chemical coagulation. This step was followed by rapid solid-liquid separation using flotation under pressure of 4 atm. A flotation tank was designed for this purpose. Gas liquid chromatography was used for determination and identification of hydrocarbon compounds in refinery wastewater. The treatment technique proved to be very promising for reducing the hydrocarbon compounds, as well as other pollutants, to a very low concentration. The results obtained showed that some of the hydrocarbon compounds were completely removed.     

Combustion,emission, and phase stability features of a diesel engine fueled by Jatropha/ethanol blends and n-butanol as co-solvent

ABSTRACT

The main challenge of utilizing ethanol in diesel engines in blending mode is the phase separation issue. Therefore, an attempt has been performed to enhance the stability feature of ethanol/Jatropha biodiesel (JME) blends by using n-butanol as co-solvent. The 10% by volume of n-butanol is added to the mixtures of 10% and 20% ethanol and 70% and 80% JME, which is denoted as JME10Bu10E and JME10Bu20E, respectively. The phase stability of the evaluated fuels is examined employing visual approach and Thermogravimetric analysis. These methods confirm that there is no phase separation for more than 2 months under ambient conditions. Then, the combustion and emission features are investigated utilizing a diesel engine run with different loads and constant speed. The findings demonstrate that the p_max. and HRR are increased by adding ethanol. The ignition delay is extended with the addition of ethanol while the combustion period is almost the same. The bsfc is decreased by adding ethanol compared to JME fuel. The CO, UHC, and NO_x formations are reduced markedly by 40%, 40%, and 40%, respectively, with adding ethanol. Finally, using n-butanol and JME as co-solvents with ethanol supports the growth of renewable energy in the CI engine.