Book reviews

Dr. Earl J. “Jay” Baker is an Associate Professor in the Department of Geography and Director of the Environmental Hazards Center at Florida State University. He has conducted extensive research on hurricane evacuation problems and also has studied growth management, policy evaluation, and storm recovery issues in hurricane-prone areas. He is a member of the National Research Council’s Committee on Natural Disasters and a director of the National Hurricane Conference.     

A MODEL FOR PLANNING AND LOCATION OF ON-SITE WASTE DISPOSAL SYSTEMS1

Abstract: A model that incorportaes performace data about data about several wastewater management systems is discussed. From these data the excepted behavior of an individual wastewater system or group of systems can be product of the performace probabilities of its individual components. The modeel can be used on a regional scale facilitating land use planning by allowing accurate estimates of performance for a prospective wastewater management system. At this scale it can allow the impact evaluation of new wastewater technology on land use in a region.     

A COLORIMETRIC METHOD FOR THE DETERMINATION OF TRACE COPPER CONCENTRATIONS IN WATER1

Trace quantities of copper (II) ion can be found in natural water as waste products from industrial, mining, and agricultural operations. Because low concentrations of copper can be toxic to plant life, many workers have devised methods of analysis for this metal in water. These methods require expensive equipment and skilled technicians. The described study illustrates a simple method in which copper (II) ion is concentrated by a batch ion exchange technique and estimated colorimetrically after formation of the blue triethylenetetramine complex. Using the visible absorption peak of the complex at 600 nm it was possible to obtain accurate estimations of original copper concentrations in the range 0.5-3 ppm. Using the complex absorption peak at 260 nm in the ultra-violet region of the spectrum increased the sensitivity by a factor of twenty. Because of the dependence of the complex formation reaction on solution acidity it is possible to optimize conditions for the detection of copper (II) in the presence of other metal ions. This type of method, which could be extended to the analysis of other metal ions, could be performed by a relatively unskilled technician under field conditions.     

Sorption of volatile organic compounds on typical carpet fibers

Measurements of adsorption isotherms for three volatile organic compounds (VOCs) (toluene, 1,2-dichlorobenzene and 1,1,1-trichloroethane) on polyacrylonitrile carpet fibers over the temperature range 25-45 degrees C were carried out in a thermogravimetric analyzer (TGA). Linear isotherms were observed in all cases with values of the Henry coefficient ranging from 0.063 to 0.941 mm. The results of additional experiments carried out in a simple test chamber containing a single source of VOC showed that the carpet fibers acted as a significant sink causing a prolonged elevation of VOC concentration in the air within the chamber. An unsteady-state model is presented, which adequately described the adsorption and desorption phenomena occurring in the test chamber and yielded realistic values of the adsorption and desorption rate constants. There was good agreement between the equilibrium and kinetic constants obtained in the TGA and test chamber experiments.     

Eu3+ uptake by calcite: preliminary results from coprecipitation experiments and observations with surface-sensitive techniques

A lack of information in databases for contamination risk assessment about the transport behaviour of the trivalent f-orbital elements in groundwater systems where calcite is at equilibrium motivated this study of Eu(3+) uptake. The free drift technique was used to examine the effects of Eu(3+) concentration, presence of Na(+) or K(+) and temperature, as well as calcite nucleation and precipitation kinetics, on the partitioning of calcite. Changes in surface composition and morphology resulting from exposure of single crystals of Iceland spar to Eu(3+)-bearing solutions were observed with X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM). First results confirm that calcite has high affinity for Eu(3+). Rates of nucleation and precipitation strongly affect the extent of uptake but the presence of Na(+) and K(+) has no effect, suggesting formation of solid solution as CaCO(3)-EuOHCO(3). Surface-sensitive techniques prove that Eu(3+) is adsorbed to calcite even when the surface is dissolving and adsorption is not accompanied by precipitation of a separate Eu(3+)-solid phase. Adsorbed Eu modifies calcite's dissolution behaviour, roughening terraces and rounding step edges, and producing surface morphology where some surface sites appear blocked. Results imply that Eu(3+) concentrations in natural calcites are limited by Eu(3+) availability rather than by a lack of ability to fit into calcite's atomic structure. This behaviour can probably be expected for other trivalent rare Earth elements (REE), actinides and fission products whose behaviour is similar to that of Eu(3+). These elements are likely to be incorporated within the calcite bulk in systems where it is precipitating and the demonstrated strong partitioning ensures some uptake even where calcite is at or under saturation.     

UTILIZATION OF A GEOGRAPHIC INFORMATION SYSTEM TO IDENTIFY THE PRIMARY AQUIFER PROVIDING GROUND WATER TO INDWIDUAL WELLS IN EASTERN ARKANSAS1

ABSTRACT: A Geographic Information System (GIS) was used to develop an automated procedure for identifying the primary aquifers supplying ground water to individual wells in eastern Arkansas. As mandated by state law, water-use data are reported by ground-water withdrawers annually to the Arkansas Soil and Water Conservation Commission, and stored in the Arkansas Site-Specific Water-Use Data System provided and supported by the U.S. Geological Survey. Although most withdrawers are able to provide the amount of water withdrawn and the depth of their wells, very few are able to provide the name of the aquifer from which they withdraw water. GIS software was used to develop an automated procedure for identifying the primary aquifers supplying ground water to individual wells in eastern Arkansas. The software was used to generate a spatial representation of the bottom boundary for the Mississippi River Valley alluvial aquifer (the shallowest aquifer) in eastern Arkansas from well log-data collected by the U.S. Geological Survey. The software was then used to determine the depth of the aquifer bottom at reported well locations to ascertain whether the Mississippi River Valley alluvial aquifer or a deeper aquifer was the primary aquifer providing water to each well. The alluvial aquifer was identified as the primary aquifer for about 23,500 wells.     

The identification and classification of reactions to sexual harassment

Distinct forms of reactions to sexual harassment were identified in the current study, and a classification scheme was developed based upon those reactions. One hundred forty two male and 100 female upper-division undergraduate management students and 44 working women read 18 randomly ordered scenarios, each of which depicted a woman being exposed to a different form of sexual harassment by a man. For each incident, the subjects were asked to write down what they themselves would do if they were in the woman's place. The resulting 5148 open-ended responses were systematically sorted into 10 classes of reaction types. In addition to assessing the reliability and validity of the classification scheme, the relative frequency of employment of the various classes was examined. Comparisons of the reactions of men and women students and comparisons of the reactions of working women and women students yielded few significant differences.     

The possibility of in situ heavy metal decontamination of polluted soils using crops of metal-accumulating plants

The decontamination of soils and wastes polluted with heavy metals presents one of the most intractable problems for soil clean-up. Present technology relies upon metal extraction or immobilization processes, both of which are expensive and which remove all biological activity in the soil during decontamination. They may only be appropriate for small areas of valuable redevelopment land. In this paper the use of metal-accumulating plants is explored for the removal of metals from superficially-contaminated soils such as those resulting from the long-term application to land of metal-contaminated sewage sludges. Green remediation employs plants native to metalliferous soils with a capacity to bioaccumulate metals such as zinc and nickel to concentrations greater than 2% in the aerial plant dry matter (hyperaccumulators). Growing such plants under intensive crop conditions and harvesting the dry matter is proposed as a possible method of metal removal and for ‘polishing’ contaminated agricultural soils down to metal concentrations below statutory limits. Not only are the biological activity and physical structure of soils maintained but the technique is potentially cheap, visually unobtrusive and offers the possibility of biorecovery of metals. The limitations of the process are reviewed and the future requirements for the development of efficient phytoremediators are outlined.     

Current approaches to the revegetation and reclamation of metalliferous mine wastes

Abandoned metalliferous mine wastes can result in severe pollution and have aesthetic impacts on the local environment. Use of a vegetation cover gives a cost-effective and environmentally sustainable method of stabilising and reclaiming wastes such as mine-spoils and tailings. Many characteristics of metalliferous wastes are often inimical to successful vegetation establishment, most notably phytotoxic levels of residual heavy metals, low nutrient status and poor physical structure of the substratum. Current approaches to revegetation and reclamation involve both ameliorative and adaptive strategies to allow plant establishment and encourage subsequent vegetation development. Different techniques of revegetation are available for temperate and arid, subtropical regions depending on the characteristics of the waste. These include direct seeding with commercially available plants, use of cover and barrier systems and the enhancement of natural revegetation processes.