Ozone concentrations in the Central Wasatch Mountains of Utah

In the Salt Lake Valley, a June through August SUM60 value (sum of hourly average ozone concentrations > or =60 parts per billion by volume [ppbv]) of 25,000 ppbv-hr was exceeded in 9 yr between 1978 and 1998. Ozone concentrations in the nearby Central Wasatch Mountains were monitored to determine the potential for vegetation injury. The SUM60 value of 19,000 ppbv-hr in these mountains and peak hourly concentrations >100 ppbv suggests that ozone-sensitive species may be injured. Ozone concentrations in the mountains were greatest during periods of strong upslope winds from the Salt Lake Valley. Both SUM60 values and hourly average concentrations in the Central Wasatch Mountains were strongly correlated with those in the Salt Lake Valley, suggesting that data from valley stations could be used to estimate ozone in the mountains.     

HYDROLOGICAL UNDERSTANDING AND SOCIETAL ACTION1

ABSTRACT: Hydrology is both an applied practical science and a pure geophysical science. The goal of hydrology, as a geophysical science, is to achieve theories capable of explaining with satisfactory accuracy the phenomena of interest. Through the rapidly accelerating power and versatility of digital computing technology, theory development and application are immensely facilitated via increasingly sophisticated predictive modeling schemes, which are now the principal operating tools both for applied management hydrology and for basic geophysical hydrology. While this approach treats phenomena as classes or generalizations, social and behavioral scientists have long argued that human beings base their actions on percepts, i.e., on the concrete specifics of their experience. Thus, the commonly held ideal of basing policy, decisions, and public actions on the best possible science encounters a conflict in belief systems. A possible resolution of this dilemma lies in the use of observational components, which in concept-centered science serve as data to test or calibrate models. These components also serve as a great repository of natural experience that is closely attuned to the perceptual reality that propels societal action. Landscapes and sediments provide indices of real processes, whose occurrence can be expected by continuity to extend to present and future activity. More attention to research on such indices is warranted as a means of triggering perception-based action by responsible decision-makers. Grounded in reality, and tempered by their intrinsic fallibility, the scientifically powerful conceptual schemes (models) will then serve as guides to further action. The full societal benefit of hydrological science requires a balanced approach in which subdisciplines focused on environmental indices are afforded equal attention to those focused on conceptual idealization.     

Modelling the costs of fox predation and preventive measures on sheep farms in Britain

Economic analysis is a useful tool to aid decisions on what to do about wildlife impacts, such as those of vertebrate predators on livestock farmers. The case-study of lamb predation by foxes in Britain is used to develop a theoretical economic model, with the aim of determining a financially optimal solution to minimise the total costs of livestock predation at the farm-level. Total costs include output losses and expenditure on preventive and control measures, in this case indoor housing and lethal fox control. The model is tested empirically with data from a questionnaire survey of sheep farmers and field data on fox population densities in Britain. Regression analyses are used to determine the relationships between lamb losses and expenditure on indoor housing, fox population density and other non-management characteristics. The effect of fox abundance on the cost of fox control is also assessed. Marginal analysis is used to determine the total cost-minimising solution from the farmer's point-of-view, in terms of how many ewes should be housed indoors and for how long, as well as how many foxes should be killed in addition to any lethal control already carried out. Optimal solutions vary according to farm characteristics, including flock size and the regional location of farms. In all cases, to minimise the costs of predation, as many ewes as possible should be housed. However, it is not worthwhile housing them for more than a day after lambing. Efficient fox predation management does not necessarily mean that lamb losses should be reduced to zero, and additional fox control is not worthwhile on the majority of farms. The analysis provides a framework for future evaluations of wildlife impacts and cost-effective management of these problems.     

A NEW FLASHINESS INDEX: CHARACTERISTICS AND APPLICATIONS TO MIDWESTERN RIVERS AND STREAMS1

ABSTRACT: The term flashiness reflects the frequency and rapidity of short term changes in streamflow, especially during runoff events. Flashiness is an important component of a stream's hydrologic regime. A variety of land use and land management changes may lead to increased or decreased flashiness, often to the detriment of aquatic life. This paper presents a newly developed flashiness index, which is based on mean daily flows. The index is calculated by dividing the pathlength of flow oscillations for a time interval (i.e., the sum of the absolute values of day‐to‐day changes in mean daily flow) by total discharge during that time interval. This index has low interannual variability, relative to most flow regime indicators, and thus greater power to detect trends. Index values were calculated for 515 Midwestern streams for the 27‐year period from 1975 through 2001. Statistically significant increases were present in 22 percent of the streams, primarily in the eastern portion of the study area, while decreases were present in 9 percent, primarily in the western portion. Index values tend to decrease with increasing watershed area and with increasing unit area ground water inputs. Area compensated index values often shift at ecoregion boundaries. Potential index applications include evaluation of programs to restore more natural flow regimes.     

Methane emissions of rice increased by elevated carbon dioxide and temperature

Methane (CH4) effluxes by paddy-culture rice (Oryza sativa L.) contribute about 16% of the total anthropogenic emissions. Since radiative forcing of CH4 at current atmospheric concentrations is 21 times greater on a per mole basis than that of carbon dioxide (CO2), it is imperative that the impact of global change on rice CH4 emissions be evaluated. Rice (cv. IR72) was planted in sunlit, closed-circulation, controlled-environment chambers in which CH4 efflux densities were measured daily. The CO2 concentration was maintained at either 330 or 660 micromol mol(-1). Air temperatures were controlled to daily maxima and minima of 32/23, 35/26, and 38/29 degrees C at each CO2 treatment. Emissions of CH4 each day were determined during a 4-h period after venting and resealing the chambers at 0800 h. Diurnal CH4 effluxes on 77, 98, and 119 d after planting (DAP) were obtained similarly at 4-h intervals. Emissions over four-plant hills and over flooded bare soil were measured at 53, 63, and 100 DAP. Emissions were negligible before 40 DAP. Thereafter, emissions were observed first in high-CO2, high-temperature treatments and reached a sustained maximum efflux density of about 7 mg m(-2) h(-1) (0.17 g m(-2) d(-1)) near the end of the growing season. Total seasonal CH4 emission was fourfold greater for high-CO2, high-temperature treatments than for the low-CO2, low-temperature treatment, probably due to more root sloughing or exudates, since about sixfold more acetate was found in the soil at 71 DAP. Both rising CO2 and increasing temperatures could lead to a positive feedback on global warming by increasing the emissions of CH4 from rice.     

Agricultural dust production in standard and conservation tillage systems in the San Joaquin Valley

The negative health effects of repeated dust exposure have been well documented. In California's San Joaquin Valley, agricultural operations may contribute substantially to airborne particulates. We evaluated four management systems to assess impacts on dust production and soil properties for a cotton (Gossypium hirsutum L.)-tomato (Lycopersicon esculentum Mill.) rotation: standard tillage with (STCC) and without (STNO) cover crop, and conservation tillage with (CTCC) and without (CTNO) cover crop. Gravimetric analysis of total dust (TD, <100-mum aerodynamic diameter) and respirable dust (RD, 4-mum aerodynamic diameter) samples collected in the plume generated by field implements showed that dust concentrations for CTNO treatments were about one-third of their STNO counterparts for both cumulative TD and RD measured throughout the two-year rotation, primarily due to fewer in-field operations. The TD and RD production for STNO and STCC was comparable, whereas the CTCC system produced about twice as much TD and RD as CTNO. Energy dispersive spectroscopy (EDS) analyses showed absolute increases of 8 and 39% organic fragments in STCC and CTCC over STNO and CTNO, respectively, while organic fragments in the TD increased by 6% in both cover crop treatments. Soil C content was positively correlated with clay content and increased by an average of 0.12 and 0.07% in the cover crop and non-cover crop treatments, respectively, although soil C for each treatment showed a distinct response to a field texture gradient. While dust emissions show an immediate decrease due to fewer field operations for the conservation tillage treatments, long-term sampling is necessary to determine the effects that increased aggregation through organic matter additions may have on dust production.     

湖鲟(Acipenser fulvescens)早期生命阶段对2,3,7,8-四氯二苯并-p-二恶英和3,3'4,4'5-五氯联苯的敏感性研究

自20世纪中叶以来,五大湖区的水生食物网就已受到多氯联苯化合物(PCBs)的污染。对于长寿命鱼类,如湖鲟(Acipenser fulvescens),由于缺乏该物种的相对敏感性信息,一直无法确定其PCB暴露的风险。本文的研究目标就是评估湖鲟早期生命阶段对3,3''4,4''5-五氯联苯(PCB-126)或2,3,7,8-四氯二苯并-p-二恶英(TCDD)暴露的敏感性。死亡率、生长、形态和组织病理学、游泳能力和活动水平都被用作评估终点。心包和卵黄囊水肿、管状心脏、卵黄囊出血和体长较小是TCDD和PCB-126暴露中最常见的病理症状,早在受精4 d后就开始出现,其中许多的病理都以一种剂量依赖的方式发生。湖鲟体内PCB-126和TCDD的半致死剂量分别为5.4 ng/g egg(95%置信区间,3.9-7.4 ng/g egg)和0.61 ng/g egg (0.47-0.82 ng/g egg)。由此产生的PCB-126的相对强度因子(0.11)远大于世界卫生组织对鱼的估计值(毒性当量因子=0.005),这表明目前的风险评估可能低估了PCB对湖鲟的毒性。在受精60 d后,从半致死剂量中幸存的湖鲟的游泳活性和耐力均有所下降。阈值和半数效应毒性值表明,与在北美发现的另一种鲟鱼属Scaphirhynchu相比,湖鲟对PCB和TCDD更为敏感。事实上,在大湖区和其他地方的湖鲟种群都容易受到PCB/ TCDD诱导,使胚胎发育受到影响,游泳能力下降。
精选自Tillitt, D. E., Buckler, J. A., Nicks, D. K., Candrl, J. S., Claunch, R. A., Gale, R. W., Puglis, H. J., Little, E. E., Linbo, T. L. and Baker, M. (2017), Sensitivity of lake sturgeon (Acipenser fulvescens) early life stages to 2,3,7,8-tetrachlorodibenzo-P-dioxin and 3,3′,4,4′,5-pentachlorobiphenyl. Environmental Toxicology and Chemistry, 36: 988–998. doi: 10.1002/etc.3614
详情请见http://onlinelibrary.wiley.com/doi/10.1002/etc.3614/full
     

Development and validation of the volatile correction model for PM10 – An empirical method for adjusting TEOM measurements for their loss of volatile particulate matter

EU Directives stipulate that PM₁₀ should be measured using the gravimetric reference method as laid out in EN12341 [CEN, 1998. Air Quality – Determination of the PM₁₀ Fraction of Suspended Particulate Matter – Reference Method and Field Test Procedure to Demonstrate Reference Equivalence of Measurement Methods. European Committee for Standardisation], or an equivalent method as demonstrated using EC guidance [EC, 2005. Demonstration of Equivalence of Ambient Air Monitoring Methods. European Commission Working Group on Guidance for the Demonstration of Equivalence]. There is however a conflict between the requirement to measure PM₁₀ using the gravimetric reference method and the need for rapid public reporting, and many member states, including the UK, rely on non-gravimetric techniques to measure PM₁₀. In the UK the majority of PM₁₀ measurements are made using the Tapered Element Oscillating Microbalance (TEOM), which does not meet the equivalence criteria [Harrison, D., 2006. UK Equivalence Programme for Monitoring of Particulate Matter. Defra, London]. The implied need to upgrade or replace TEOMs with an equivalent automated measurement technique has significant cost implications. The model described in this paper was based on analysis of daily mean measurements of PM₁₀ by the Filter Dynamics Measurement System (FDMS) and the TEOM at UK sites. It uses the FDMS measurement of the volatile component of PM₁₀ (referred to here as FDMS purge) to correct for differences in the sensitivity to volatile PM₁₀ between the TEOM and the EU gravimetric reference method. The model equation for the correction of TEOM PM₁₀ measurements is: TEOM_VCM = TEOM ? 1.87 FDMS purge due to the regional homogeneity of volatile PM, the FDMS purge concentration may be measured at a site distant to the TEOM, allowing the possibility of using a single FDMS instrument to correct PM₁₀ measurements made by several TEOMs in a defined geographical area. The model was assessed against the criteria for the EC Working Group's Guidance for the Demonstration of Equivalence of Ambient Air Monitoring Methods [EC, 2005. Demonstration of Equivalence of Ambient Air Monitoring Methods. European Commission Working Group on Guidance for the Demonstration of Equivalence]. The model satisfies the equivalence criteria using remote FDMS purge measurements for distances up to 200 km (in 22 out of 23 data sets). These data provide strong evidence that the model is a viable tool for correcting measurements from TEOM instruments on the national and local government networks.     

Natural Jordanian zeolite: removal of heavy metal ions from water samples using column and batch methods

The adsorption behavior of natural Jordanian zeolites with respect to Cd(2 + ), Cu(2 + ), Pb(2 + ), and Zn(2 + ) was studied in order to consider its application to purity metal finishing drinking and waste water samples under different conditions such as zeolite particle size, ionic strength and initial metal ion concentration. In the present work, a new method was developed to remove the heavy metal by using a glass column as the one that used in column chromatography and to make a comparative between the batch experiment and column experiment by using natural Jordanian zeolite as adsorbent and some heavy metals as adsorbate. The column method was used using different metal ions concentrations ranged from 5 to 20 mg/L with average particle size of zeolite ranged between 90 and 350 mum, and ionic strength ranged from 0.01 to 0.05. Atomic absorption spectrometry was used for analysis of these heavy metal ions, the results obtained in this study indicated that zeolitic tuff is an efficient ion exchanger for removing heavy metals, in particular the fine particle sizes of zeolite at pH 6, whereas, no clear effect of low ionic strength values is noticed on the removal process. Equilibrium modeling of the removal showed that the adsorption of Cd(2 + ), Cu(2 + ), Pb(2 + ), and Zn(2 + ) were fitted to Langmuir, Freundlich and Dubinin-Kaganer-Radushkevich (DKR). The sorption energy E determined in the DKR equation (9.129, 10.000, 10.541, and 11.180 kJ/mol for Zn(2 + ), Cu(2 + ), Cd(2 + ) and Pb(2 + ) respectively) which revealed the nature of the ion-exchange mechanism.