Comparative study of hotplate wet digestion methods for the determination of mercury in biosolids

The re-use of biosolids is becoming increasingly popular for land applications. However, biosolids may contain elevated levels of metals and metalloids (including mercury) relative to background environmental concentrations. Consequently, reliable mercury analysis is important to allow classification of biosolids and to determine appropriate options for beneficial uses. This paper reports on a comparative study of 12 hotplate wet digestion methods for their suitability for the determination of mercury in biosolids. The methods were applied to mercury biosolids samples from four localities of two different sewage treatment plants in the State of Victoria, Australia. Samples were also spiked with methylmercury chloride and mercury sulphide to evaluate the Hg recovery in each hotplate digestion method. Aqua regia (HCl:HNO(3)=3:1), reverse aqua regia (HCl:HNO(3)=1:3), nitric, hydrochloric, sulphuric acid and their combinations with or without hydrogen peroxide were studied as wet digestion solutions. The method providing the best mercury recoveries was optimized. Under optimal conditions the corresponding analytical procedure consisted of 1h pre-digestion of 0.4 g biosolids sample with 10 ml reverse aqua regia with temperature increasing to 110 degrees C and 3h digestion at this temperature. In the last 10 min of the digestion step, 2 ml hydrogen peroxide were added to ensure complete decomposition of all mercury containing compounds. After filtering and dilution with deionised water (1:10), the concentration of mercury was determined by cold vapour atomic absorption spectrometry. It is expected, that the wet acid digestion method developed in this study will be also applicable to biosolids from other sewage treatment plants and to other types of solid mercury samples with elevated levels of organic matter.     

Effects of filtration and pH perturbation on freshwater organic matter fluorescence

Fluorescence of organic matter from six contrasting freshwaters was analysed after filtration (1.2 microm and 0.2 microm filter sizes) and pH perturbation (+/-2 pH units from ambient conditions). Two fluorophores were compared in detail: tryptophan-like fluorescence, whose filtration and pH characteristics are relatively poorly understood, and humic-like fluorescence, which is better characterised. Although there was some variability in both fluorophores, the tryptophan-like fluorescence showed the most significant decrease in fluorescence intensity between raw and 1.2 microm filter samples, and a much smaller decrease between 1.2 and 0.2 microm, demonstrating a significant source associated with particulate material as well as a significant <0.2 microm fraction. In contrast, humic-like fluorescence shows little change with filtration, suggesting that the majority of this fluorescence is associated with truly dissolved material. The pH perturbation experiments demonstrate that tryptophan-like fluorescence is less impacted by pH than with filter fraction. For humic-like fluorescence, pH effects are weak and are not as consistent as those reported in the literature for extracted humic substances. pH perturbation of the freshwaters shows a wide range of sample specific pH responses, significantly more variable than that observed in experiments using extracted humic substances and tryptophan standards, demonstrating the natural variability of freshwater dissolved organic matter.     

Attraction of two lacewing species to volatiles produced by host plants and aphid prey

It is well documented that host-related odors enable many species of parasitoids and predatory insects to locate their prey and prey habitats. This study reports the first characterization of prey and prey host odor reception in two species of lacewings, Chrysoperla carnea (Say) and Chrysopa oculata L. 2-Phenylethanol, one of the volatiles emitted from their preys host plants (alfalfa and corn) evoked a significant EAG response from antennae of C. carnea. Traps baited with this compound attracted high numbers of adult C. carnea, which were predominantly females. One of the sex pheromone components (1R,4aS,7S,7aR)-nepetalactol of an aphid species, Acyrthosiphon pisum (Harris) attracted only C. oculata adults. Single sensillum recordings showed that the olfactory neurons of C. carnea responded to both 2-phenylethanol and aphid sex pheromone components, but those of C. oculata only responded to the latter.     

Estimating K(oc) for persistent organic pollutants: limitations of correlations with K(ow)

The n-octanol/water partition coefficient (K(ow)) is commonly used to predict the soil or aquatic particle water partition coefficient normalized to organic carbon (K(oc)). Many correlations are available covering several chemical classes and ranges of hydrophobicity. This work indicates the K(ow) may not be a strong predictor for persistent organic pollutants (POPs) which are defined here as chemicals with logK(ow) > 5.0. In addition, the correlation developed in this work for POPs will still result in a predicted value which is of by a factor of 15. Accordingly, care must be taken when applying K(oc) estimations using K(ow) for POPs until more suitable correlations are developed.     

The Environmental Appraisal of National Park Management Plans in England and Wales

The Countryside Agency has recommended that national park authorities (NPAs) undertake an environmental appraisal of their national park management plans. A study of the appraisal practices of the NPAs of England and Wales has shown that, despite this guidance, the practice of environmental appraisal is uncommon but that a culture of applying sustainability appraisal is evolving. It is argued that the most likely explanation for this situation is the increasing influence of the concept of sustainable development on the workings of the national park management system. This broad policy development has manifested itself in a variety of ways, including the production of government guidance relating to sustainability appraisal and changes in best practice, each of which have influenced appraisal procedures in national parks. The wider implications of, and drivers behind, the evolution of appraisal procedure towards sustainability appraisal are thus identified and then discussed.     

Soils, water quality, and watershed size: interactions in the Maumee and Sandusky river basins of northwestern Ohio

Soil variability in watersheds accounts for the problem of partitioning downstream water quality data and evaluating sources of non-point pollution. This review of previous water quality studies was conducted to examine more closely the influence of soil properties on pollutant export. The approach used in this paper was to start with data from the two largest watersheds (Maumee and Sandusky) and then compare them on a unit area export basis with data from intermediate-size and smaller watersheds. General relationships between pollutant levels at the river mouth and upstream soil conditions are vague and seemingly contradictory at the large-watershed scale. With smaller watersheds, it can be determined that soil texture, slope, and internal drainage are controlling factors for pollutant export. Although Paulding (very-fine, illitic, nonacid, mesic Typic Epiaquept) and Roselms (very-fine, illitic, mesic Aeric Epiaqualf) soils occupy only 5% of the Maumee basin, they generate more than 10 times as much sediment per unit area as the tile-drained Hoytville (fine, illitic, mesic Mollic Epiaqualf) soils that occupy 16% of the Maumee basin. Tile drainage of very poorly drained soils that are formed from either glacial till or silty to sandy lake deposits reduces runoff and increases downward movement of soluble nutrients into tile drains. The assumption that sloping moraine areas are the primary source of pollutants should be reexamined based on this review.     

Reliable QSAR for estimating Koc for persistent organic pollutants: correlation with molecular connectivity indices

Several recent studies have shown that n-octanol/water partition coefficients may not be a good predictor for estimating soil sorption coefficients of persistent organic pollutants (POPs), defined here as chemicals with log Kow greater than 5. Thus, an alternative QSAR model was developed that seems to provide reliable estimates for the soil sorption coefficients of persistent organic pollutants. This model is based on a set of calculated molecular connectivity indices and evaluated soil sorption data for 18 POPs. The chemical's size and shape, quantified by 1chi, 3chiC and 4chiC(v) indices, have a dominant effect on the soil sorption process of POPs. The developed QSAR model was rationalized in terms of potential hydrophobic interactions between persistent organic pollutants and soil organic matrix. Its high predictive power has been verified by an extensive internal and external validation procedure.     

Participatory indicator development: what can ecologists and local communities learn from each other?

Given the growing popularity of indicators among policy-makers to measure progress toward conservation and sustainability goals, there is an urgent need to develop indicators that can be used accurately by both specialists and nonspecialists, drawing from the knowledge possessed by each group. This paper uses a case study from the Kalahari, Botswana to show how participatory and ecological methods can be combined to develop robust indicators that are accessible to a range of users to monitor and enhance the sustainability of land management. First, potential environmental sustainability indicators were elicited from pastoralists in three study sites. This knowledge was then evaluated by pastoralists, before being tested empirically using ecological and soil-based techniques. Despite the wealth of local knowledge about indicators, this knowledge was thinly spread. The knowledge was more holistic than published indicator lists for monitoring rangelands, encompassing vegetation, soil, livestock, wild animal, and socioeconomic indicators. Pastoralist preferences for vegetation and livestock indicators match recent shifts in ecological theory suggesting that livestock populations reach equilibrium with key forage resources in semiarid environments. Although most indicators suggested by pastoralists were validated through empirical work (e.g., decreased grass cover and soil organic matter content, and increased abundance of Acacia mellifera and thatching grass), they were not always sufficiently accurate or reliable for objective degradation assessment, showing that local knowledge cannot be accepted unquestioningly. We suggest that, by combining participatory and ecological approaches, it is possible to derive more accurate and relevant indicators than either approach could achieve alone.     

A health risk assessment for fluoride in Central Europe

Like many elements, fluorine (which generally occurs in nature as fluoride) is beneficial to human health in trace amounts, but can be toxic in excess. The links between low intakes of fluoride and dental protection are well known; however, fluoride is a powerful calcium-seeking element and can interfere with the calcified structure of bones and teeth in the human body at higher concentrations causing dental or skeletal fluorosis. One of the main exposure routes is via drinking water and the World Health Organisation currently sets water quality guidelines for the element. In Central Europe, groundwater resources that exceed the guideline value of 1.5 mg l⁻¹ are widespread and effects on health of high fluoride in water have been reported. The aim of the current project was to develop a geographic information system (GIS) to aid the identification of areas where high-fluoride waters and fluorosis may be a problem; hence, where water treatment technologies should be targeted. The development of the GIS was based upon the collation and digitisation of existing information relevant to fluoride risk in Ukraine, Moldova, Hungary and Slovakia assembled for the first time in a readily accessible form. In addition, geochemistry and health studies to examine in more detail the relationships between high-fluoride drinking waters and health effects in the population were carried out in Moldova and Ukraine demonstrating dental fluorosis prevalence rates of 60–90% in adolescents consuming water containing 2–7 mg l⁻¹ fluoride.