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161.
Scaratti Gidiane De Noni Júnior Agenor José Humberto Jorge de Fatima Peralta Muniz Moreira Regina 《Environmental science and pollution research international》2020,27(18):22144-22154
Environmental Science and Pollution Research - 1,4-Dioxane is a synthetic cyclic ether traditionally used as a chlorinated solvent stabilizer. It is a small molecule and recalcitrant compound that... 相似文献
162.
Ferrazzo Suéllen Tonatto Tímbola Rafael de Souza Bragagnolo Lucimara Prestes Elvis Korf Eduardo Pavan Prietto Pedro Domingos Marques Ulsen Carina 《Environmental science and pollution research international》2020,27(30):37718-37732
Environmental Science and Pollution Research - Exposure of geomaterials to acidic leachates may compromise their structure and functionality due to changes in physicochemical, mineralogical, and... 相似文献
163.
de Castro Lima José Augusto Monteiro Labanowski Jérôme Bastos Marília Camotti Zanella Renato Prestes Osmar Damian de Vargas Jocelina Paranhos Rosa Mondamert Leslie Granado Eugenie Tiecher Tales Zafar Mohsin Troian Alexandre Le Guet Thibaut dos Santos Danilo Rheinheimer 《Environmental science and pollution research international》2020,27(10):10581-10598
Environmental Science and Pollution Research - The total cultivated area in Brazil reached to 62 million ha in 2018, with the predominance of genetically modified soybean and corn (36 and 17... 相似文献
164.
Preparation of 2-mercaptobenzothiazole-derivatized mesoporous silica and removal of Hg(ii) from aqueous solution 总被引:2,自引:0,他引:2
Pérez-Quintanilla D Del Hierro I Fajardo M Sierra I 《Journal of environmental monitoring : JEM》2006,8(1):214-222
Mesoporous silicas (SBA-15 and MCM-41) have been functionalized by two different methods. Using the heterogeneous route the silylating agent, 3-chloropropyltriethoxysilane, was initially immobilized onto the mesoporous silica surface to give the chlorinated mesoporous silica Cl-SBA-15 or Cl-MCM-41. In a second reaction a multifunctionalized N,S donor compound (2-mercaptobenzothiazol) was incorporated to obtain the functionalized silicas denoted as MBT-SBA-15-Het and MBT-MCM-41-Het. Using the homogeneous route, the functionalization was achieved via the one step reaction of the mesoporous silica with an organic ligand containing the chelating functions, to give the modified mesoporous silicas denoted as MBT-SBA-15-Hom or MBT-MCM-41-Hom. The functionalized mesoporous silicas were employed as adsorbents for the regeneration of aqueous solutions at pH 6 contaminated with Hg(ii) at room temperature. Results obtained indicate that mercury adsorption was higher in the mesoporus silicas prepared by the homogeneous method, and the maximum adsorption value (0.24 +/- 0.02 mmol Hg(ii) g(-1)) was obtained for MBT-SBA-15-Hom. The chemically stability in acid medium of the functionalized silicas, possibility its regeneration washing with concentrate HCl, resulting in the reuse of the adsorbent material for several cycles. 相似文献
165.
Thomassen Y Koch W Dunkhorst W Ellingsen DG Skaugset NP Jordbekken L Arne Drabløs P Weinbruch S 《Journal of environmental monitoring : JEM》2006,8(1):127-133
The number concentration and size distribution of ultrafine particles in a S?derberg and a prebake potroom of an aluminium primary smelter have been measured using a scanning mobility particle spectrometer. The particle morphology was studied by transmission electron microscopy (TEM). The study shows the existence of elevated number concentrations of ultrafine particles in both potrooms. The main source of these particles is likely to be the process of anode changing. The ultrafine particles were measured directly at the source but could also be identified as episodes of high number concentrations in the general background air. Unlike the larger particles belonging to the 50-100 nm mode, the nanoparticle mode could not be detected in the TEM indicating that they may not be stable under the applied sampling conditions and/or the high vacuum in the instrument. 相似文献
166.
Bioaerosol sampling by a personal rotating cup sampler CIP 10-M 总被引:1,自引:0,他引:1
Görner P Fabriès JF Duquenne P Witschger O Wrobel R 《Journal of environmental monitoring : JEM》2006,8(1):43-48
High concentrations of bioaerosols containing bacterial, fungal and biotoxinic matter are encountered in many workplaces, e.g. solid waste treatment plants, waste water treatment plants and sewage networks. A personal bioaerosol sampler, the CIP 10-M (M-microbiologic), has been developed to measure worker exposure to airborne biological agents. This sampler is battery operated; it is light and easy to wear and offers full work shift autonomy. It can sample much higher concentrations than biological impactors and limits the mechanical stress on the microorganisms. Biological particles are collected in 2 ml of liquid medium inside a rotating cup fitted with radial vanes to maintain an air flow rate of 10 l min(-1) at a rotational speed of approximately 7,000 rpm. The rotating cup is made of sterilisable material. The sampled particles follow a helicoidal trajectory as they are pushed to the surface of the liquid by centrifugal force, which creates a thin vertical liquid layer. Sterile water or another collecting liquid can be used. Three particle size selectors allow health-related aerosol fractions to be sampled according to international conventions. The sampled microbiological particles can be easily recovered for counting, incubation or further biochemical analysis, e.g., for airborne endotoxins. Its physical sampling efficiency was laboratory tested and field trials were carried out in industrial waste management conditions. The results indicate satisfactory collection efficiency, whilst experimental application has demonstrated the usefulness of the CIP 10-M personal sampler for individual bioaerosol exposure monitoring. 相似文献
167.
From 1988 to 2003, the St. Lawrence Action Plan, a Canada – Quebec cooperation agreement on the St. Lawrence River, helped to mobilize a still-growing number of stakeholders in the conservation and protection of this great river and generated tangible results in a number of areas of intervention. The successes enjoyed in the area of industrial, agricultural and urban clean-up, in protecting plant and animal species and their habitats, and in acquiring new knowledge on the state and trends of the ecosystem reflect the sustained efforts of government and non-government partners over the course of those 15 years. The committed involvement of local communities provides assurance of the sustainable development of this vast ecosystem.The Canadian Crown reserves the right to retain a non-exclusive, royalty free licence in and to any copyright. 相似文献
168.
Romário J. da Silv Lizeth Carolina Mojica-Sánchez Filipe D.S. Gorz Graciela C. Pedro Bruna G. Maciel Gabriela P. Ratkovski Hérica D. da Roch Kamila T.O. do Nascimento Juan C. Medina-Llamas Alicia E. Chávez-Guajardo José J. Alcaraz-Espinoz Celso P. de Melo 《环境科学学报(英文版)》2021,33(2):62-73
We report the preparation of poly(3,4-ethylene dioxythiophene) (PEDOT)-modified polyvinylidene fluoride electrospun fibers and their use as a novel adsorbent material for the removal of the anionic dye Methyl Orange (MO) from aqueous media. This novel adsorbent material can be used to selectively remove MO on a wide pH range (3.0–10.0), with a maximum capacity of 143.8 mg/g at pH 3.0. When used in a recirculating filtration system, the maximum absorption capacity was reached in a shorter time (20 min) than that observed for batch mode experiments (360 min). Based on the analyses of the kinetics and adsorption isotherm data, one can conclude that the predominant mechanism of interaction between the membrane and the dissolved dye molecules is electrostatic. Besides, considering the estimated values for the Gibbs energy, and entropy and enthalpy changes, it was established that the adsorption process is spontaneous and occurs in an endothermic manner. The good mechanical and environmental stability of these membranes allowed their use in at least 20 consecutive adsorption/desorption cycles, without significant loss of their characteristics. We suggest that the physical-chemical characteristics of PEDOT make these hybrid mats a promising adsorbent material for use in water remediation protocols and effluent treatment systems. 相似文献
169.
Chile ratified the Montreal Protocol in 1990 which sets out an agenda for the reduction and then elimination of ozone depleting substances (ODS); however, by 1998 the country had not yet defined a strategy to encourage greater compliance, so that in the same year the National Environmental Commission decided to examine the policy options available. This paper examines the process followed to develop this strategy. As a first step it was necessary to look at how far the implicit policy of "business as usual" could be stretched without jeopardizing Chile's compliance obligations. A second step included quantifying compliance costs and their impact on different policy instruments and so policy choice. Finally, the attitudes of decision-makers or participants were identified, by interviews with officials of the different public agents involved, in order to weigh their views about policy. A strategy was proposed, based on this information, which the Chilean regulator has used, although not in its entirety. The methodology developed could well be useful for developing-country Protocol signatories building their own appropriate compliance strategy. 相似文献
170.