全文获取类型
收费全文 | 13625篇 |
免费 | 166篇 |
国内免费 | 258篇 |
专业分类
安全科学 | 401篇 |
废物处理 | 356篇 |
环保管理 | 1989篇 |
综合类 | 3584篇 |
基础理论 | 3199篇 |
环境理论 | 6篇 |
污染及防治 | 3415篇 |
评价与监测 | 606篇 |
社会与环境 | 395篇 |
灾害及防治 | 98篇 |
出版年
2018年 | 137篇 |
2017年 | 151篇 |
2016年 | 204篇 |
2015年 | 184篇 |
2014年 | 233篇 |
2013年 | 1007篇 |
2012年 | 339篇 |
2011年 | 483篇 |
2010年 | 336篇 |
2009年 | 432篇 |
2008年 | 484篇 |
2007年 | 514篇 |
2006年 | 456篇 |
2005年 | 344篇 |
2004年 | 369篇 |
2003年 | 402篇 |
2002年 | 346篇 |
2001年 | 496篇 |
2000年 | 343篇 |
1999年 | 241篇 |
1998年 | 164篇 |
1997年 | 159篇 |
1996年 | 190篇 |
1995年 | 188篇 |
1994年 | 209篇 |
1993年 | 187篇 |
1992年 | 186篇 |
1991年 | 185篇 |
1990年 | 209篇 |
1989年 | 194篇 |
1988年 | 167篇 |
1987年 | 164篇 |
1986年 | 148篇 |
1985年 | 166篇 |
1984年 | 147篇 |
1983年 | 162篇 |
1982年 | 161篇 |
1981年 | 163篇 |
1980年 | 149篇 |
1979年 | 145篇 |
1978年 | 142篇 |
1977年 | 129篇 |
1976年 | 136篇 |
1975年 | 114篇 |
1974年 | 142篇 |
1973年 | 125篇 |
1972年 | 125篇 |
1971年 | 105篇 |
1970年 | 106篇 |
1967年 | 116篇 |
排序方式: 共有10000条查询结果,搜索用时 843 毫秒
821.
Silvia M. Calderón Noreen D. Poor Scott W. Campbell 《Journal of the Air & Waste Management Association (1995)》2013,63(9):1278-1286
Abstract The research objective was to adapt the ultraviolet (UV)photolysis method to determine dissolved organic nitrogen (DON) in aqueous extracts of aerosol samples. DON was assumed to be the difference in total concentration of inorganic nitrogen forms before and after sample irradiation. Using a 22 factorial design the authors found that the optimal conversion of urea, amino acids (alanine, aspartic acid, glycine, and serine), and methylamine for a reactor temperature of 44 °C occurred at pH 2.0 with a 24-hr irradiance period at concentrations < µM of organic nitrogen. Different decomposition mechanisms were evident: the photolysis of amino acids and methylamine released mainly ammonium (NH4 +), but urea released a near equimolar ratio of NH4 + and nitrate (NO3 ?). The method was applied to measure DON in the extracts of aerosol samples from Tampa, FL, over a 32-day sampling period. Average dissolved inorganic (DIN) and DON concentrations in the particulate matter fraction PM10 were 78.1 ± 29.2 nmol-Nm?3and 8.3 ± 4.9 nmol-Nm?3, respectively. The ratio between DON and total dissolved nitrogen ([TDN] = DIN + DON) was 10.1 ± 5.7%, and the majority of the DON (79.1 ± 18.2%) was found in the fine particulate matter (PM2.5) fraction. The average concentrations of DIN and DON in the PM2.5 fraction were 54.4 ± 25.6 nmol-Nm?3 and 6.5 ± 4.4 nmol-Nm?3, respectively. 相似文献
822.
823.
Cheryl L. Dahlin Connie A. Williamson W. Keith Collins David C. Dahlin 《Environmental Forensics》2013,14(2):191-201
The applicability of sequential extraction as a means to determine species of heavy-metals was examined by a study on soil samples from two Superfund sites: the National Lead Company site in Pedricktown, NJ, and the Roebling Steel, Inc., site in Florence, NJ. Data from a standard sequential extraction procedure were compared to those from a comprehensive study that combined optical- and scanning-electron microscopy, X-ray diffraction, and chemical analyses. The study shows that larger particles of contaminants, encapsulated contaminants, and/or man-made materials such as slags, coke, metals, and plastics are subject to incasement, non-selectivity, and redistribution in the sequential extraction process. The results indicate that standard sequential extraction procedures that were developed for characterizing species of contaminants in river sediments may be unsuitable for stand-alone determinative evaluations of contaminant species in industrial-site materials. However, if employed as part of a comprehensive, site-specific characterization study, sequential extraction could be a very useful tool. 相似文献
824.
常温低基质厌氧氨氧化反应器启动及其稳定性 总被引:5,自引:0,他引:5
以上向流生物滤池为反应器,以实验室内氧化沟回流污泥为接种污泥,采用先培育好氧生物膜,后转为厌氧环境培育厌氧氨氧化生物膜的方式,成功实现了常温低基质浓度下厌氧氨氧化反应器的启动。控制反应器进水pH为7.50~7.80,NH4+-N为30~40 mg/L,NO2--N为35~50 mg/L,温度为20~25℃。224 d以后,反应器启动成功。在稳定运行阶段,出水亚硝氮和氨氮的平均浓度分别为1.4 mg/L和4.6 mg/L,平均去除率分别为95.3%和90.1%,去除比例为1~1.8∶1,主要集中在1.4~1.5∶1,亚硝氮和氨氮去除的容积负荷分别为104.2 mg/(L.d)和146.0 mg/(L.d)。 相似文献
825.
826.
R.D. Moore J.W. Trubilowicz J.M Buttle 《Journal of the American Water Resources Association》2012,48(1):32-42
Moore, R.D. (Dan), J.W. Trubilowicz, and J.M. Buttle, 2011. Prediction of Streamflow Regime and Annual Runoff for Ungauged Basins Using a Distributed Monthly Water Balance Model. Journal of the American Water Resources Association (JAWRA) 48(1): 32‐42. DOI: 10.1111/j.1752‐1688.2011.00595.x Abstract: Prediction of streamflow in ungauged basins is a global challenge, but is particularly an issue in physiographically complex regions like British Columbia (BC), Canada. The objective of this study was to assess the accuracy of a simple water balance model that can be run using existing spatial datasets. The model was developed by modifying an existing monthly water balance model to account for interception loss from forest canopy, glacier melt, and evaporation from lakes. The model was run using monthly climate normals from the ClimateBC application, which have a horizontal resolution of 400 m. Each ClimateBC grid cell was classified as forest, open land, glacier or water surface based on provincial scale digital maps of biogeoclimatic zones, glaciers, and water. The output was monthly mean runoff from each grid cell. These values were integrated within the catchment boundaries for streams gauged by the Water Survey of Canada. Annual runoff was predicted with modest accuracy: after updating the predicted runoff by interpolating errors from neighboring gauged streams, the mean absolute error was 25.4% of the gauged value, and 52% of the streams had errors less than 20%. However, the model appears to be quite robust in distinguishing between pluvial, hybrid, and melt‐dominated hydroclimatic regimes, and therefore has promise as a tool for catchment classification. 相似文献
827.
Wesley W. Stone Robert J. Gilliom 《Journal of the American Water Resources Association》2012,48(5):970-986
Stone, Wesley W. and Robert J. Gilliom, 2012. Watershed Regressions for Pesticides (WARP) Models for Predicting Atrazine Concentrations in Corn Belt Streams. Journal of the American Water Resources Association (JAWRA) 48(5): 970‐986. DOI: 10.1111/j.1752‐1688.2012.00661.x Abstract: Watershed Regressions for Pesticides (WARP) models, previously developed for atrazine at the national scale, are improved for application to the United States (U.S.) Corn Belt region by developing region‐specific models that include watershed characteristics that are influential in predicting atrazine concentration statistics within the Corn Belt. WARP models for the Corn Belt (WARP‐CB) were developed for annual maximum moving‐average (14‐, 21‐, 30‐, 60‐, and 90‐day durations) and annual 95th‐percentile atrazine concentrations in streams of the Corn Belt region. The WARP‐CB models accounted for 53 to 62% of the variability in the various concentration statistics among the model‐development sites. Model predictions were within a factor of 5 of the observed concentration statistic for over 90% of the model‐development sites. The WARP‐CB residuals and uncertainty are lower than those of the National WARP model for the same sites. Although atrazine‐use intensity is the most important explanatory variable in the National WARP models, it is not a significant variable in the WARP‐CB models. The WARP‐CB models provide improved predictions for Corn Belt streams draining watersheds with atrazine‐use intensities of 17 kg/km2 of watershed area or greater. 相似文献
828.
Ted R. Angradi David W. Bolgrien Matt A. Starry Brian H. Hill 《Journal of the American Water Resources Association》2012,48(5):1054-1070
Angradi, Ted R., David W. Bolgrien, Matt A. Starry, and Brian H. Hill, 2012. Modeled Summer Background Concentration of Nutrients and Suspended Sediment in the Mid‐Continent (USA) Great Rivers. Journal of the American Water Resources Association (JAWRA) 48(5): 1054‐1070. DOI: 10.1111/j.1752‐1688.2012.00669.x Abstract: We used regression models to predict summer background concentration of total nitrogen (N), total phosphorus (P), and total suspended solids (TSS), in the mid‐continent great rivers: the Upper Mississippi, the Lower Missouri, and the Ohio. From multiple linear regressions of water quality indicators with land use and other stressor variables, we determined the concentration of the indicators when the predictor variables were all set to zero — the y‐intercept. Except for total P on the Upper Mississippi River, we could predict background concentration using regression models. Predicted background concentration of total N was about the same on the Upper Mississippi and Lower Missouri Rivers (430 μg l?1), which was lower than percentile‐based values, but was similar to concentrations derived from the response of sestonic chlorophyll a to great river total N concentration. Background concentration of total P on the Lower Missouri (65 μg l?1) was also lower than published and percentile‐based concentrations. Background TSS concentration was higher on the Lower Missouri (40 mg l?1) than the other rivers. Background TSS concentration on the Upper Mississippi (16 mg l?1) was below a threshold (30 mg l?1) designed to protect aquatic vegetation. Our model‐predicted concentrations for the great rivers are an attempt to estimate background concentrations for water quality indicators independent from thresholds based on percentiles or derived from stressor‐response relationships. 相似文献
829.
A comprehensive study of the degradation of monuron, one of the phenylurea herbicides, was conducted by UV-Vis/WO3 process. It was found that hydroxyl radicals played a major role in the decay of monuron while other radicals (e.g. superoxide) and hole might also contribute to the decomposition of monuron. The oxidation path likely plays a major role in the generation of hydroxyl radicals. The effects of initial pH level, initial concentration of monuron, and inorganic oxidants on the performance of UV-Vis/WO3 process were also investigated and optimized. Comparison between monuron decay pathways by UV-Vis/WO3 and UV/TiO2 was conducted. The decay mechanisms, including N-terminus demethylation, dechlorination and direct hydroxylation on benzene ring, were observed to be involved in the oxidation of monuron in these two processes. Sixteen intermediates were identified during the photodegradation of monuron and degradation pathways were proposed accordingly. 相似文献
830.
A novel electrolytic groundwater remediation process, which used the H2 continuously generated at cathode to achieve in situ catalytic hydrodechlorination, was developed for the treatment of 2,4-dichlorophenol (2,4-DCP) in groundwater. Catalytic hydrodechlorination using Pd supported on bamboo charcoal and external H2 showed that 2,4-DCP was completely dechlorinated to phenol within 30 min at pH ? 5.5. In a divided electrolytic system, the catalytic hydrodechlorination of 2,4-DCP in cathodic compartment by H2 generated at the cathode under 20 and 50 mA reached 100% at 120 and 60 min, respectively. Two column experiments with influent pHs of 5.5 (unconditioned) and 2 were conducted to evaluate the feasibility of this process. The 2,4-DCP removal efficiencies were about 63% and nearly 100% at influent pHs of 5.5 and 2, respectively. Phenol was solely produced by 2,4-DCP hydrodechlorination, and was subsequently degraded at the anode. A low pH could enhance the hydrodechlorination, but was not necessarily required. This study provides the preliminary results of a novel effective electrolytic process for the remediation of groundwater contaminated by chlorinated aromatics. 相似文献