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941.
Ali-Khodja H Belaala A Demmane-Debbih W Habbas B Boumagoura N 《Environmental monitoring and assessment》2008,138(1-3):219-231
Total suspended particulate matter and deposition fluxes of particles were investigated in the town of Didouche Mourad which
is located 13 km north of Constantine. Samples of air particulate matter were collected at one site located in the heart of
the town and situated 3 km north of a cement plant. Samples were collected from 2 November 2002 to 28 April 2003 every 3 days
using a high volume air sampler. Sampling intervals were 24 h in all cases. During the same period, samples of dust fallout
were collected at the same site. Samples were collected at 30-day intervals. Lead, chromium, manganese, nickel, copper, cobalt
and cadmium deposition fluxes were measured and both the soluble and insoluble fractions were determined. Furthermore, the
information gathered by this study was correlated with the corresponding hourly weather data provided by a weather station
installed at the study station. The possible sources for dust and trace metals were analyzed by comparing average contributions
of wind aspects to the concentrations and depositions of mass and chemical species with the average frequencies of wind direction.
The mean concentration was 300 μg/m3. The average dust deposition rate through the period of study was 221 mg/(m2.day). Results indicate that anthropogenic sources contribute greatly to trace elements. An exposure assessment to the heavy
metals taking into account the inhalation route and soil dust ingestion was carried out and allowed direct comparison of trace
metal intakes via these routes. 相似文献
942.
May TW Fairchild JF Petty JD Walther MJ Lucero J Delvaux M Manring J Armbruster M 《Environmental monitoring and assessment》2008,137(1-3):213-232
The Solomon River Basin is located in north-central Kansas in an area underlain by marine geologic shales. Selenium is an
indigenous constituent of these shales and is readily leached into the surrounding groundwater. Portions of the Basin are
irrigated primarily through the pumping of selenium-contaminated groundwater from wells onto fields in agricultural production.
Water, sediment, macroinvertebrates, and fish were collected from various sites in the Basin in 1998 and analyzed for selenium.
Selenium concentrations were analyzed spatially and temporally and compared to reported selenium toxic effect thresholds for
specific ecosystem components: water, sediments, food-chain organisms, and wholebody fish. A selenium aquatic hazard assessment
for the Basin was determined based on protocol established by Lemly. Throughout the Basin, water, macroinvertebrate, and whole
fish samples exceeded levels suspected of causing reproductive impairment in fish. Population structures of several fish species
implied that successful reproduction was occurring; however, the influence of immigration of fish from low-selenium habitats
could not be discounted. Site-specific fish reproduction studies are needed to determine the true impact of selenium on fishery
resources in the Basin.
The U.S. Government’s right to retain a non-exclusive, royalty free license in and to any copyright is acknowledged. 相似文献
943.
Langston WJ O'Hara S Pope ND Davey M Shortridge E Imamura M Harino H Kim A Vane CH 《Environmental monitoring and assessment》2012,184(1):289-311
Biomonitoring of contaminants (metals, organotins, polyaromatic hydrocarbons (PAHs), PCBs) was undertaken in Milford Haven
Waterway (MHW) and a reference site in the Tywi Estuary (St Ishmael/Ferryside) during 2007–2008. Bioindicator species encompassed
various uptake routes—Fucus vesiculosus (dissolved contaminants); Littorina littorea (grazer); Mytilus edulis and Cerastoderma edule (suspension feeders); and Hediste (=Nereis) diversicolor (sediments). Differences in feeding and habitat preference have subtle implications for bioaccumulation trends though, with
few exceptions, contaminant burdens in MHW were higher than the Tywi reference site, reflecting inputs. Elevated metal concentrations
were observed at some MHW sites, whilst As and Se (molluscs and seaweed) were consistently at the higher end of the UK range.
However, for most metals, distributions in MH biota were not exceptional. Several metal-species combinations indicated increases
in bioavailability upstream, which may reflect the influence of geogenic/land-based sources—perhaps enhanced by lower salinity.
TBT levels in MH mussels were below OSPAR toxicity thresholds and in the Tywi were close to zero. Phenyltins were not accumulated
appreciably in M. edulis, whereas some H. diversicolor populations appear subjected to localized (historical) sources. PAHs in H. diversicolor were distributed evenly across most of MHW, although acenaphthene, fluoranthene, pyrene, benzo(a)anthracene and chrysene were highest at one site near the mouth; naphthalenes in H. diversicolor were enriched in the mid-upper Haven (a pattern seen in M. edulis for most PAHs). Whilst PAH (and PCB) concentrations in MH mussels were mostly above reference and OSPAR backgrounds, they
are unlikely to exceed ecotoxicological thresholds. Bivalve Condition indices (CI) were highest at the Tywi reference site
and at the seaward end of MH, decreasing upstream—giving rise to several significant (negative) relationships between CI and
body burdens. Despite the possible influence of salinity gradient as a complicating factor, multivariate analysis indicated
that a combination of contaminants could influence the pattern in condition (and the biomarkers metallothionein and TOSC).
Integrating bioaccumulation data with biological and biochemical endpoints is seen as a useful way to discriminate environmental
quality of moderately contaminated areas such as MHW and to prioritise cause and effect investigations. 相似文献
944.
Chlorinated paraffins (CPs) are straight chain hydrocarbons that are produced as complex mixtures and are used as flame retardants
and paint additives. These mixtures are extremely difficult to characterize using conventional chromatographic methods, as
conventional gas chromatography results in unresolved complex chromatograms that preclude the identification and quantification
of individual congeners or any reasonable assessment of the average carbon chain length. Carbon chain length is an important
parameter for assessing physical properties and the toxicity of these materials. We have modified and improved a previously
published gas chromatography–flame ionization detector method that uses Pd catalyst held in the gas chromatograph injector
to simultaneously dechlorinate the CPs and separate the resulting alkanes. In addition, we have adapted this method to gas
chromatography–mass spectrometry. Dehalogenation of other compounds was also studied with this system to investigate potential
application to other complex halogenated mixtures. 相似文献
945.
Sarath K. Guttikunda Ramani V. Kopakka Prasad Dasari Alan W. Gertler 《Environmental monitoring and assessment》2013,185(7):5585-5593
Air quality in Hyderabad, India, often exceeds the national ambient air quality standards, especially for particulate matter (PM), which, in 2010, averaged 82.2?±?24.6, 96.2?±?12.1, and 64.3?±?21.2 μg/m3 of PM10, at commercial, industrial, and residential monitoring stations, respectively, exceeding the national ambient standard of 60 μg/m3. In 2005, following an ordinance passed by the Supreme Court of India, a source apportionment study was conducted to quantify source contributions to PM pollution in Hyderabad, using the chemical mass balance (version 8.2) receptor model for 180 ambient samples collected at three stations for PM10 and PM2.5 size fractions for three seasons. The receptor modeling results indicated that the PM10 pollution is dominated by the direct vehicular exhaust and road dust (more than 60 %). PM2.5 with higher propensity to enter the human respiratory tracks, has mixed sources of vehicle exhaust, industrial coal combustion, garbage burning, and secondary PM. In order to improve the air quality in the city, these findings demonstrate the need to control emissions from all known sources and particularly focus on the low-hanging fruits like road dust and waste burning, while the technological and institutional advancements in the transport and industrial sectors are bound to enhance efficiencies. Andhra Pradesh Pollution Control Board utilized these results to prepare an air pollution control action plan for the city. 相似文献
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950.
Vibrio species isolated from four different sampling stations in the west coast of Peninsular Malaysia were screened for their antimicrobial resistance and plasmid profiles. A total of 138 isolates belonging to 15 different species were identified. Vibrio campbellii, V. parahaemolyticus, V. harveyi, and V. tubiashii were found to predominance species at all stations. High incidence of erythromycin, ampicillin, and mecillinam resistance was observed among the Vibrio isolates. In contrast, resistance against aztreonam, cefepime, streptomycin, sulfamethoxazole, and sulfonamides was low. All the Vibrio isolates in this study were found to be susceptible to imipenem, norfloxacin, ofloxacin, chloramphenicol, trimethoprim/sulfamethoxazole, and oxytetracycline. Ninety-five percent of the Vibrio isolates were resistant to one or more different classes of antibiotic, and 20 different resistance antibiograms were identified. Thirty-two distinct plasmid profiles with molecular weight ranging from 2.2 to 24.8 kb were detected among the resistance isolates. This study showed that multidrug-resistant Vibrio spp. were common in the aquatic environments of west coast of Peninsular Malaysia. 相似文献