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551.
Mariagrazia D’Emilio Rosa Caggiano Rosa Coppola Maria Macchiato Maria Ragosta 《Environmental monitoring and assessment》2010,169(1-4):619-630
The development of in situ, cheep, noninvasive, and fast strategies for soil monitoring is a crucial task for environmental research. In this paper, we present the results of three field surveys carried out in an industrial area of Southern Italy: S. Nicola di Melfi. The monitoring procedure is based on soil magnetic susceptibility measurements carried out by means of experimental protocols that our research group developed during the last years. This field surveys is supported by both geological characterization of the area and analytical determinations of metal concentrations in soils. Magnetic studies were carried out not only in situ but also in laboratory. Results show that, taking into account the influence due to the geomorphologic difference, soil magnetic susceptibility is an optimal indicator of the anthropogenic impact. So, our monitoring strategy discloses that the combined use of magnetic susceptibility measurements and soil geomorphology information may be used as a useful tool for the temporal monitoring of pollution evolution and for a fast screening of polluted zones. 相似文献
552.
Pasture selection by livestock is an essential topic for rangeland management, especially in trace element-contaminated soils.
We have studied the composition (nutrients and trace elements) of a grass-based diet from soils affected by a mine spill at
different growth stages (October 2008 to May 2009). A diet based on other plants (mainly Compositae species) was also studied (May 2009) for comparison. Faeces and mane hair of horses feeding on these pastures were also analysed.
Micronutrient (Cu, Fe, Mn and Zn) and potentially toxic trace element (As, Cd, Pb, Tl) concentrations were below the maximum
tolerable levels (MTL) for horses, except for Fe (at early growth of pastures) and Cd (in the diet based on ‘other’ plants).
Values of potential ingestion of Fe by horses were higher than 10 mg kg body weight − 1 day − 1. Cadmium concentrations in some pasture samples (those composed of Compositae species) were higher than 3 mg kg − 1. Potential toxicity of such Cd levels in pastures is uncertain, since a high disparity of criteria about MTL by cattle exists
(between 0.5 and 10 mg kg − 1 diet). Nutrient concentrations were adequate for horses, which could counteract possible harmful effects derived from trace
element ingestion. The analyses of excreta and mane hair point to the low risk of toxicity derived from the consumption of
these contaminated pastures. However, the ingestion of regenerating pastures (autumnal samples) should be avoided due to the
greater risk of ingestion of contaminated soil attached to the plant material. Management of these pastures by grazing requires
periodic monitoring. Special attention should be given to Fe and particularly Cd (non-essential element) which accumulates
in animal organs, where it could provoke uncertain long-term effects. 相似文献
553.
Cachada A Pereira ME Ferreira da Silva E Duarte AC 《Environmental monitoring and assessment》2012,184(1):15-32
Urban and industrial development has caused a major impact on environmental soil quality. This work assesses the extent and
severity of contamination in a small urban area subjected to an industrial impact and identifies the major anthropogenic inputs.
Twenty-six soil samples were collected from agricultural and urban sites, and concentrations of potentially toxic elements
(As, Cd, Cu, Cr, Fe, Mn, Ni, Pb and Zn), PAHs and PCBs, were determined. In spite of the low median concentrations observed,
some sites represent a potential hazard for human health and ecosystems. Concentrations of contaminants were higher than those
found in a nearby city, indicating that the study area is affected by the surrounding industry. The use of multivariate statistical
analyses allowed for the identification of the main factors controlling the variability of potentially toxic elements and
organic pollutants in the soils. The presence of Cr, Fe, Mn and Ni was associated with geogenic inputs, and Cu, Pb, Zn, As,
PAHs and PCBs were associated with anthropogenic inputs. Industry and traffic were the most important anthropogenic sources.
Soil characteristics were identified as important factors controlling the spatial variability of elements, both from recognised
natural and anthropogenic origin. Differences between land uses were observed, which may be attributed to both management
practices and proximity to sources. 相似文献
554.
Gomes LN Oliveira SM Giani A von Sperling E 《Environmental monitoring and assessment》2012,184(8):4635-4645
The water reservoir of Vargem das Flores, Brazil, has been subject to eutrophication problems. The occurrence of cyanobacterial blooms in this water body has raised concerns regarding the presence of toxic metabolites. In order to understand the factors that promote the proliferation and distribution of cyanobacteria in the reservoir, physicochemical parameters, species composition, and toxicity of the reservoir water column were analyzed at monthly intervals over a 3-year period (2004-2007) using a range of analytical techniques. The results showed that cyanobacteria were absent in the dry period, returning after the onset of stratification. A succession pattern was observed within this group. The Aphanocapsa genus was dominant in the last rainy period of the study (October 2006 to March 2007). However toxicity was only detected when the genera Microcystis and Sphaerocavum were present (October 2005). The principal components analysis showed negative correlation between cyanobacteria and orthophosphate. The change of dominant cyanobacteria along the 3 years of study and the final prevalence of nontoxic genera in the reservoir is an evidence of water quality improvement in response to the management techniques implemented in the reservoir basin. 相似文献
555.
Beniamino Gioli Maria F. Carfora Vincenzo Magliulo Maria C. Metallo Attilio A. Poli Piero Toscano Franco Miglietta 《Environmental monitoring and assessment》2014,186(4):2053-2066
Aircraft measurements were used to estimate the CO2 emission rates of the city of Rome, assessed against high-resolution inventorial data. Three experimental flights were made, composed of vertical soundings to measure Planetary Boundary Layer (PBL) properties, and circular horizontal transects at various altitudes around the city area. City level emissions and associated uncertainties were computed by means of mass budgeting techniques, obtaining a positive net CO2 flux of 14.7?±?4.5, 2.5?±?1.2, and 10.3?±?1.2 μmol m?2 s?1 for the three flights. Inventorial CO2 fluxes at the time of flights were computed by means of spatial and temporal disaggregation of the gross emission inventory, at 10.9?±?2.5, 9.6?±?1.3, and 17.4?±?9.6 μmol m?2 s?1. The largest differences between the two dataset are associated with a greater variability of wind speed and direction in the boundary layer during measurements. Uncertainty partitioned into components related to horizontal boundary flows and top surface flow, revealed that the latter dominates total uncertainty in the presence of a wide variability of CO2 concentration in the free troposphere (up to 7 ppm), while it is a minor term with uniform tropospheric concentrations in the study area (within 2 ppm). Overall, we demonstrate how small aircraft may provide city level emission measurements that may integrate and validate emission inventories. Optimal atmospheric conditions and measurement strategies for the deployment of aircraft experimental flights are finally discussed. 相似文献
556.
Mariana de F Matos Clarice Maria Rispoli Botta Ana Lúcia Fonseca 《Environmental monitoring and assessment》2014,186(11):7999-8006
The Funil Reservoir (Rio de Janeiro State, Brazil) is an environment degraded by constant discharge of nutrients and pollution coming from the most industrialized region of the country. As a consequence of eutrophication, there are continuous cyanobacteria blooms, which cause acute and chronic toxicity to zooplankton. In this context, Phase I of Toxicity Identification Evaluation (TIE) was performed on Daphnia similis using water and interstitial water from the reservoir, with the aim of identifying classes of compounds responsible for toxicity. The results indicated that water toxicity was due to cyanobacteria resulting from blooms in the reservoir and surfactants. Metals, especially copper, contributed to sediment toxicity. This research is the first attempt to describe the nature of toxicity in this reservoir using this method. 相似文献
557.
Otto Hänninen Stefano Zauli-Sajani Roberta De Maria Paolo Lauriola Matti Jantunen 《Environmental Modeling and Assessment》2009,14(4):419-429
Particulate matter air pollution is estimated to cause in the order of 350,000 excess deaths in the European Union calling for policy development and evaluation tools. In the current work, a model for PM10 exposures of children is developed using microenvironment time activities and infiltration of ambient pollution indoors, both evaluated against observations earlier and integrated with city-wide air quality models in the current work. The model is demonstrated using data from two cities in Italy. High-end short-term exposures are characterized by an episode-day situation in Turin, and annual mean exposures in downtown Bologna. The air quality model was unable to capture the highest levels during the episode, and therefore, the exposure model was adjusted using observed–modeled ratio from a monitoring station. Air quality model performance for the annual levels was significantly better. Annual exposure variability within the target population was 1.5-fold in the downtown area Bologna and tenfold during the episode day in Turin. 相似文献
558.
Galante-Oliveira S Oliveira I Santos JA Pereira Mde L Pacheco M Barroso CM 《Journal of environmental monitoring : JEM》2010,12(5):1055-1063
Nucella lapillus (L.) is a marine gastropod mollusc widely used as a bioindicator of TBT pollution in the North Atlantic coastlines. The species reproductive cycle and the male penis length seasonal/spatial variation were studied at a single site at Aveiro seashore (NW Portugal) between December 2005 and June 2007. The main objective of this work is to assess if the "Relative Penis Size Index" (RPSI)--an important imposex assessment index--varies seasonally and spatially in the same sampling site and how this can affect results obtained in imposex monitoring programmes. Animals able to reproduce were found every month but a seasonal pattern in N. lapillus reproductive cycle was evident. Female gametogenic maturation varied seasonally and a decrease in capsule gland volume and condition factor occurred in late summer/early autumn. The gametogenesis in males did not show a significant seasonal variation as in females but the condition factor, penis length, amount of sperm and prostate volume also diminished in late summer/early autumn. On the other hand, males that were close to egg capsules clusters had larger penises than those far away from clusters. The temporal and spatial male penis length variation introduces a bias on imposex assessment results when using RPSI and the magnitude of the error involved is evaluated for different TBT pollution levels scenarios. We consider that RPSI provides interesting and complementary information that should not be excluded from monitoring programmes, but temporal or spatial comparisons of imposex should be based on other more reliable imposex indices like the VDSI. 相似文献
559.
Storelli MM Barone G Giacominelli-Stuffler R Marcotrigiano GO 《Environmental monitoring and assessment》2012,184(9):5797-5805
Concentrations of polychlorinated biphenyls (PCBs) including dioxin-like PCBs (non-ortho, PCB 77, PCB 126, and PCB 169 and mono-ortho, PCB 105, PCB 118, and PCB 156) were measured in different organs and tissues (melon, blubber, liver, kidney, lung, heart, and muscle tissue) of striped dolphins (Stenella coeruleoalba) from the Eastern Mediterranean Sea (Adriatic Sea). The mean highest levels were in blubber and melon, followed by liver, kidney, lung, heart, and muscle tissue. PCB profiles were similar in all tissues and organs being dominated by the higher chlorinated homologues (hexa-CBs, 55.8-62.1%; penta-CBs, 15.4-20.0%; and hepta-CB PCB 180, 12.7-16.5%). Major PCBs in all tissues were congeners 138 and 153 collectively accounting for 50.6-58.3% of the total PCB concentrations, followed by PCB 101, 105, 118, and 180 constituting from 27.0% to 31.0%. PCB levels were higher in adult males than in adult females. The estimated 2,3,7,8-TCDD toxic equivalents of non- and mono-ortho PCBs were much higher than the threshold level above which adverse effects have been observed in other marine mammals species, suggesting that striped dolphins in this region are at risk for toxic effects. 相似文献
560.
Maria Aparecida Macêdo Silva Gilmara Fernandes Eça Danielle Felix Santos Alonso Góes Guimarães Michelle Coêlho Lima Marcelo Friederichs Landim de Souza 《Environmental monitoring and assessment》2013,185(7):5387-5399
Sampling was conducted monthly during a transition period between the dry and rainy seasons in order to evaluate the effectiveness of a municipal sewage treatment plant (STP) in eutrophication control. STP effluent and fluvial input data were also estimated. In the dry period, high concentrations of nutrients, chlorophyll a (up to 360 μg?L?1), and anoxia in bottom waters were observed in the upper portion of the estuary. Nitrate was scarce during the dry months, although high concentrations were observed at the river sources and the upper estuary. The N:P and Si:P molar ratios were usually below 16:1, and the Si:N ratio was higher than 1:1. The fluvial inputs were a greater source of nutrients to the estuary than the STP, but nutrient loading by these effluents were also important in contributing to the eutrophication of the upper estuarine zone, especially in the dry season when symptoms were more intense. 相似文献