Formation of chlorinated hydrocarbons from the reaction of chlorine atoms and activated carbon

The reactions of chlorine atoms and activated carbon have been studied over the temperature range of 200-400 degrees C using an isothermal flow reactor in conjunction with 337 nm laser photolysis of Cl2. These studies have shown that carbon tetrachloride is the major product, with chloroform, methylene chloride, and methyl chloride being formed in progressively decreasing yields. Trace quantities of methane, ethane, and dichloroethylenes were also observed. Mechanisms of carbon fragmentation by successive addition of chlorine atoms are proposed. The formation of small chlorinated hydrocarbons by the direct reaction of chlorine with carbon may be a key link in both the de novo and precursor pathways of formation of PCDD/F.     

Mercury and organochlorine content of Dipper Cinclus cinclus eggs in south-west Ireland: trends during 1990-1999

A sample of 124 deserted/infertile dipper (Cinclus cinclus) eggs was collected in south-west Ireland during six seasons (1990-1994 and 1999) and analysed for mercury and organochlorines. Mercury was detected in three of the 6 years but no trend was observed. DDT occurred above the limit of detection in only two eggs, one each in 1993 and 1994. In contrast, two derivatives of DDT (DDE and TDE) were found much more commonly. DDE occurred in over 87% of eggs, while TDE contamination was less widespread and reached a maximum of 60% in 1993, with none detected in 1991 or 1999. There was no trend in occurrence of DDE or TDE across years. PCB contamination was present consistently over the 10-year period, with little change in the proportion of contaminated eggs collected over time. In all years, the lowest recorded occurrence of total PCBs was 69% expressed on a formulation basis as Arochlor 1254. PCB congeners 138, 153 and 180 dominated. The congener pattern was similar across years with the exception of 1990 when congener 118 dominated. A distinct trend of high values of contaminants was observed in 1990 and 1993. In 1990, PCB 118 was the dominant contaminant, while in 1993, HEOD, DDE, PCB 138 and PCB 153 were primary contributors to the observed result. Other contaminants (HCB, PCB 101, gamma-HCH, PCB 170 and PCB 180) showed little obvious patterns between years and occurred at relatively low levels. No pattern was observed in contaminants when eggs were grouped according to river or altitude. These data provide a baseline for organochlorine contamination levels in Irish freshwater ecosystems against which future trends can be assessed.     

Vanadium uptake by higher plants: Some recent developments

The occurrence of vanadium in the biosphere, and the possible roles this element may play in the metabolism of living organisms, especially higher plants, are discussed. The aqueous chemistry of the element is reviewed, and the chemical properties of the element are related to those of soils and plants. Evidence is present for a biotransformation of vanadium from vanadate (VO ₃ ^– ) to vanadyl (VO²⁺) during uptake by plants, based on tissue analysis and ESR spectra. The significance of this process on the potential impact of vanadium in the biosphere is discussed.     

UNCERTAINTY ANALYSIS OF RUNOFF ESTIMATES FROM A RUNOFF CONTOUR MAP1

ABSTRACT: The U.S. Environmental Protection Agency (EPA) in cooperation with the U.S. Geological Survey (USGS) conducted an analysis to quantify the uncertainty associated with interpolating runoff to specific sites using a runoff contour map. We interpolated runoff to 93 gaged watersheds from a runoff contour map using (1) hand interpolation to the watershed outlet, (2) a computer interpolation to the watershed outlet, and (3) hand interpolation to the watershed centroid. We compared the interpolated values to the actual gaged values and found that there was a bias in the average interpolated value for runoff estimated at basin outlets, with interpolated values being less than the actual. We found no significant difference between the hand interpolation method and the computer interpolation method except that the computer method tended to have higher variability due to factors inherent to the software used. There were no strong spatial correlations or regional patterns in the runoff interpolations, which indicates that there are no regional biases introduced in the development of the contour map. We determined that we could estimate runoff, on the average, within approximately 8.9 cm (3.5 in; 15 percent) of the measured value using the three methods. The results of this work indicate that runoff contour maps can he used in regional studies to estimate runoff to ungaged systems with quantifiable uncertainty.     

A METHOD FOR OBTAINING SLOPE INFORMATION FOR HYDROLOGIC MODELS1

: A method is described for obtaining surface slope information for analysis with other land resource and water quality data in hydrologic models of nonpoint sources of water pollution. The method described requires a point sampling scheme, topographic maps, and a coordinate digitizer. Sample point elevation, slope direction, and slope magnitude are calculated from locations of the sample point and the nearest upper and lower contour lines. Details of the data collection methodology and associated problems are discussed.     

Ecotoxicological assessment of diffuse pollution using biomonitoring tool for sustainable land use in Thailand

As a developing country, Thailand has a significant issue with diffuse pollution of the soil ecosystem due to an indiscriminate use of agrichemicals and poorly regulated disposal of a wide variety of hazardous wastes. Practical risk assessment tools based on locally-occurring species are needed to assess the effects of diffuse pollutants on the soil ecosystem in Thailand because reliance on soil criteria developed for overseas conditions may provide inadequate protection. Native soil organisms in Thailand may be more or less sensitive to contaminants compared to overseas test species. This article described a biological indicator approach for ecological risk assessment of diffuse pollution in the soil ecosystem of Thailand from pesticide application with the aim of developing standardized protocols using native species and locally generated data to better evaluate the ecological risks of non-point source soil pollution. It was found that ecotoxicological assessment provided a better understanding of the ecological impacts that diffuse pollution induced on Thai environmental conditions. Thai soil biota species were more sensitive to soil contaminants than similar species overseas. Soil series also had an influence on the ecotoxicology of contaminants to soil biota. Collembolan, Cyphoderus sp., was demonstrated as a useful alternative test species to Folsomia Candida (international test species) for terrestrial ecotoxicological testing of Thai soils. In addition, the soil biota activities such as soil respiration and earthworm avoidance including soil biodiversity and the litter bag decomposition technique are also good tools to assess the effects of diffuse pollution by pesticides on the soil ecosystem of Thailand.     

Perceptions and experiences of random breath testing in Queensland and the self-reported deterrent impact on drunk driving

OBJECTIVE: The present study explored the impact of random breath testing (RBT) on the attitudes, perceptions, and self-reported behavior of motorists in the Australian state of Queensland. Particular attention was given to how exposure to RBT impacted motorists' perceived risk of apprehension and self-reported behavior, relative to other variables of interest such as alcohol consumption. METHODS: The study involved a telephone survey of 780 motorists drawn from throughout the state of Queensland. Participants were volunteers recruited from a random sample of all listed telephone numbers in the state, adjusted according to district population figures. The survey questionnaire collected information relating to the participants' socio-demographic characteristics, drinking and drunk driving behaviors, attitudes toward drunk driving and RBT, and experiences and perceptions of RBT. RESULTS: The analysis indicated that a large proportion of the sample had both observed RBT and been breath tested within the last six months and believed the practice served an important role in improving road safety. However, a considerable percentage also reported drunk driving at least once in the last six months without being detected, with further analysis indicating that the threat of apprehension associated with RBT did not appear to greatly influence their offending behavior. Rather, a higher frequency of alcohol consumption, combined with more favorable attitudes to drunk driving and lower levels of support for RBT, appeared to be associated with offending behavior. CONCLUSIONS: While the results confirm the high levels of exposure to RBT achieved in Queensland, the direct impact of recent exposure on drunk driving behavior appears less important than other factors such as alcohol consumption and attitudes to drunk driving and RBT. Further research is required to better understand how recent and lifetime exposure to RBT impacts on motorists' perceived risk of apprehension and subsequent drunk driving behavior.     

SNAKES USED IN ETHNOMEDICINE IN NORTHEAST BRAZIL

This paper documents zootherapeutic practices in Northeast Brazil. It is primarily based on field surveys carried out in fishing villages located in the States of Maranhão and Paraíba, where dwellers provided information on snake species used as medicine, body parts used to prepare the remedies, and the illnesses to which the remedies were prescribed. The species used as medicinal drug and their respective families were: Crotalus durissus (rattlesnake), Bothrops leucurus (‘lance head’, a venomous snake), and Lachesis muta (bushmaster) of the family Crotalidae; and Boa constrictor (boa constrictor), Epicrates cenchria (‘salamanta’), and Eunectes murinus (anaconda) of the family (Boidae). These zootherapeutical resources were used for the cure of 14 illnesses. The most commonly cited species were Crotalus durissus (n=26) e Boa constrictor (n=6), Apparently, the medicinal use of snakes does not pose a threat for their population in the studied sites.     

基于关联向量机回归的水质预测模型

提出了一种基于关联向量机回归的水质时间序列预测模型,并以该模型对氢离子浓度指数(p H值)、溶解氧(DO)、高锰酸盐指数(CODMn)和氨氮(NH3-N)4种重要水质指标进行预测.首先采用国家环保部发布的四川攀枝花龙洞水质自动监测数据进行实验,对该模型的有效性进行了验证;然后将关联向量机回归预测模型与支持向量机回归预测模型进行比较.为了比较不同核函数的预测效果,实验中预测模型的核函数分别采用了线性函数和高斯函数.实验结果表明,关联向量机回归模型的预测效果不亚于支持向量机回归模型;且在给出预测值时,还能同时给出预测结果的可信程度.     

On inferring population trends of mobile waterbirds from aerial transect surveys in variable environments

Environmental and Ecological Statistics - Monitoring waterbird populations in Australia is challenging for reasons of counting logistics, and because population aggregation and dispersion can shift...