Ozone artifacts and carbonyl measurements using Tenax GR, Tenax TA, Carbopack B, and Carbopack X adsorbents

Four popular thermally desorbable adsorbents used for air sampling (Tenax TA, Tenax GR, Carbopack B, and Carbopack X) are examined for the potential to form artifacts with ozone (O3) at environmental concentrations. The performance of these adsorbents for the ketone and aldehyde species identified as O3-adsorbent artifacts was also characterized, including recovery, linearity, and method detection limits (MDLs). Using gas chromatography/mass spectrometry, 13 different artifacts were identified and confirmed for both Tenax TA and Tenax GR, 9 for Carbopack B, but none for Carbopack X. Several O3 artifacts not reported previously were identified, including: pentanal, 3-hexanone, 2-hexanone, hexanal, 3-heptanone, and heptanal with Tenax TA; pentanal, 3-hexanone, 2-hexanone, hexanal, and 3-heptanone on Tenax GR; and 1-octene and 1-nonene with Carbopack B. Levels of straight-chain aldehyde artifacts rapidly diminished after a few cycles of adsorbent conditioning/O3 exposure, and concentrations could be predicted using a first-order model. Phenyl-substituted carbonyl artifacts (benzaldehyde and acetophenone) persisted on Tenax TA and GR even after 10 O3 exposure-conditioning cycles. O3 breakthrough through the adsorbent bed was most rapid in adsorbents that yielded the highest levels of artifacts. Overall, artifact composition and concentration are shown to depend on O3 concentration and dose, conditioning method, and adsorbent type and age. Calibrations showed good linearity, and most compounds had reasonable recoveries, for example, 90 +/- 15% for Tenax TA, 97 +/- 23% for Tenax GR, 101 +/- 24% for Carbopack B, and 79 +/- 25% (91 +/- 9% for n-aldehydes) for Carbopack X. Benzeneacetaldehyde recovery was notably poorer (22-63% across the four adsorbents). MDLs for several compounds were relatively high, up to 5 ng. By accounting for both artifact formation and method performance, this work helps to identify which carbonyl compounds can be measured using thermally desorbable adsorbents and which may be prone to bias because of the formation of O3-adsorbent artifacts.     

宁夏生态移民社区生活空间融合与重构的影响因素及机理——以宁夏闽宁镇为例

生态移民的空间位移引致了迁入区多因素的相互作用及长期演化,成为多学科深入探究的重要问题之一。以闽宁镇生态移民社区为例,采用主成分分析法和地理探测器分析法,对生态移民社区生活空间融合的影响因素和机理进行了研究,结果发现：（1）生态移民社区生活空间融合与重构受多种因素影响,生活基础设施、经济收入增长、移民社区环境、邻里关系、政府政策、民族生活六个主成分对生态移民社区生活空间融合的影响可以起到解释作用。（2）影响生态移民社区生活空间的因子解释力由强到弱依次排序为：X₁生活基础设施>X₂经济收入增长>X₃邻里关系>X₄政府政策>X₅民族生活>X₆移民社区环境;交互探测结果表明社区各要素因子交互后因子解释力呈双线性增强,即任意两个因子交互作用对于生态移民社区生活空间融合的影响强度都大于单个因子的独自作用强度。（3）各影响因素之间的互动影响,共同促进生态移民社区固有的生活方式、文化习惯、社会交往关系的演化,进而形成了生活空间的融合与重构。     

不同草地资源水平牧户对气候变化的感知与偏差途径

人群感知是气候变化适应行为形成的重要信息基础,基于对中国北方草地草甸草原、典型草原、荒漠草原、草原化荒漠、沙地、农牧交错带等地区1292个牧户的问卷访谈,分2轮调查研究了不同草地类型地区牧民对气候变化的感知,与气候实值比较分析,并研究了牧民气候变化感知的偏差途径,结果表明:1980~2009年间研究区温度变化倾向率为0.63℃/10a(P0.05);温度较强的趋势性与牧民对其感知的分歧存在偏差,降水无明显变化与不同地区牧民感知明确的趋势性判断存在偏差;受草场变化等环境信息的传导是气候变化感知偏差形成的重要原因,其中,降水感知与环境感知之间具有较强的关系,存在明显的传导过程,而温度感知的传导性不明显;通过Probit模型分析显示,气候变化传导感知与否主要与牧户距离行政中心距离、户主年龄、教育背景、载畜水平、草畜资源等因素有关.     

Environmental Reporting by the Fortune 50 Firms

/ The extent and use of industry-reported environmental data are increasing, warranting an in-depth analysis of this information. This paper reviews the environmental reporting guidelines issued by several business and nonprofit organizations and evaluates the environmental reports published by the Fortune 50 companies, half of which publish reports. After describing the history of environmental reporting and the content of the guidelines, a comparative evaluation is made to indicate the types of companies producing reports, the topics reported, the intended audiences, the scope and depth of the material reported, and the effectiveness of the reports as communication devices. These reports are mechanisms to enhance a firm's image, public relations, and marketing and are aimed largely at concerned individuals, affected communities, and investors. Significant differences in the content and the depth of reports are seen as firms report on topics that are perceived by the public as high risks. The most complete reports are published by industries with poor or controversial public images, e.g., the chemical and timber industries. Still, no report provided information that was sufficient for comprehensive or comparative analyses of environmental performance. Recommendations are provided to increase the quality and effectiveness of environmental reporting.KEY WORDS: Communication; Environmental management; Performance reporting; Reporting; Stakeholder     

A bioassessment approach for mid-continent great rivers: the Upper Mississippi, Missouri, and Ohio (USA)

The objectives of the Environmental Monitoring and Assessment Program for Great River Ecosystems (EMAP-GRE) are to (1) develop and demonstrate, in collaboration with states, an assessment program yielding spatially unbiased estimates of the condition of mid-continent great rivers; (2) evaluate environmental indicators for assessing great rivers; and (3) assess the current condition of selected great river resources. The purpose of this paper is to describe EMAP-GRE using examples based on data collected in 2004-2006 with emphasis on an approach to determining reference conditions. EMAP-GRE includes the Upper Mississippi River, the Missouri River, and the Ohio River. Indicators include biotic assemblages (fish, macroinvertebrates, plankton, algae), water chemistry, and aquatic and riparian physical habitat. Reference strata (river reaches for which a single reference expectation is appropriate) were determined by ordination of the fish assemblage and examination of spatial variation in environmental variables. Least disturbed condition of fish assemblages for reference strata was determined by empirical modeling in which we related fish assemblage metrics to a multimetric stressor gradient. We inferred least disturbed condition from the y-intercept, the predicted condition when stress was least. Thresholds for dividing the resource into management-relevant condition classes for biotic indicators were derived using predicted least disturbed condition to set the upper bound on the least disturbed condition class. Also discussed are the outputs of EMAP-GRE, including the assessment document, multimetric indices of condition, and unbiased data supporting state and tribal Clean Water Act reporting, adaptive management, and river restoration.     

Sorption of trihalomethanes in foods

Trihalomethanes (THMs, namely, CHCl₃, CHCl₂Br, CHClBr₂ and CHBr₃) are disinfection by-products that are present in drinking water. These toxic chemicals are also present in meat, dairy products, vegetables, baked goods, beverages and other foods, although information regarding their concentrations and origin is very limited. This study investigates sorption of THMs occurring during rinsing and cooking of foods and the significance of food as an exposure source.Initial estimates of THM uptake were measured in experiments representing rinsing with tap water at 25 C using nine types of food, and for cooking in tap water at 90 C for fourteen other foods. A subset of foods was then selected for further study over a range of THM concentrations (23.7–118.7 μg/l), temperatures (25 C and 90 C), food concentrations (0.2–1.4, food weight: water weight), and contact times (5–240 min). Data were analyzed using regression and exponential models, and diffusion models were used to help explain the trends of THM uptake.Among vegetables, sorbed THM concentrations at 25 C were 213 to 774 ng/g for CHCl₃, 53 to 609 ng/g for CHCl₂Br, and 150–845 ng/g for CHClBr₂. Meats at 90 C tended to have higher concentrations, e.g., 870–2634 ng/g for CHCl₃. Sorbed concentrations increased with contact time and THM concentration, and decreased with food concentration in rinsing tests (using spinach, iceberg-head lettuce and cauliflower) and cooking tests (using tomato, potato, beef and miso–tofu soup). For most foods, THM uptake was diffusion limited and several hours were needed to approach steady-state levels. Swelling, hydrolysis and other physical and chemical changes in the food can significantly affect sorption. Screening level estimates for CHCl₃ exposures, based on experimental results and typical food consumption patterns, show that uptake via foods can dominate that due to direct tap water consumption, suggesting the importance of sorption and the need for further evaluation of THM intake due to foods.     

日本环境会计体系分析及对我国启示

环境会计发展的理念与实践是以实现经济、社会、环境的可持续发展为前提,通过实施环境会计制度,可以使企业准确掌握经营活动的资源消耗、环境负荷,促进其提供环境友好产品及服务,推进经济朝着低碳、绿色、可持续模式发展。日本经过十几年的发展,目前已形成较为完善的环境会计体系。本文通过介绍和分析日本环境会计体系产生的背景、发展变化与作用,探讨我国环境会计体系构筑问题。     

Levels and composition of volatile organic compounds on commuting routes in Detroit, Michigan

Vehicle emissions can constitute a major share of ambient concentrations of many volatile organic compounds (VOCs) and other air pollutants in urban areas. Especially high concentrations may occur at curbsides, vehicle cabins, and other microenvironments. Such levels are not reflected by monitoring at fixed sites. This study reports on measurements of VOCs made from buses and cars in Detroit, MI. A total of 74 adsorbent tube samples were collected on 40 trips and analyzed by GC-MS for 77 target compounds. Three bus routes, selected to include residential, commercial and heavily industrialized areas, were sampled simultaneously on four sequential weeks during morning and afternoon rush hour periods. Nineteen compounds were regularly detected and quantified, the most prevalent of which included hexane/2-methyl pentane (15.6±5.8 μg m⁻³), toluene (10.2±7.9 μg m⁻³), m,p-xylene (6.8±4.7 μg m⁻³), benzene (4.5±3.0 μg m⁻³), 1,2,4-trimethylbenzene (4.0±2.6 μg m⁻³), o-xylene (2.2±1.6 μg m⁻³), and ethylbenzene (2.1±1.5 μg m⁻³). VOC levels in bus interiors and outdoor levels along the roadway were similar. Despite the presence of large industrial sources, route-to-route variation was small, but temporal variation was large and statistically significant. VOC compositions and trends indicate the dominance of vehicle sources over the many industrial sources in Detroit with the possible exceptions of styrene and several chlorinated VOCs. In-bus levels exceeded concentrations at fixed site monitors by a factor of 2–4. VOC concentrations in Detroit traffic are generally comparable to levels measured elsewhere in the US and Canada, but considerably lower than measured in Asia and Europe.     

青岛理工大学安全工程专业课程体系设置模式

介绍了我国安全工程专业发展概况、存在的问题及青岛理工大学安全工程专业现状.重点介绍了青岛理工大学安全工程专业课程体系设置情况,提出了2006年安全工程专业课程体系设置调整的构想.