Measuring the linkage between strategies on sustainability and institutional forces: an empirical study of Spanish universities

Policy documents are commonly identified as key outcomes that guide initiatives directed by senior university leaders towards sustainability through plans and policies. Many studies have called for a more integration of sustainability into universities. Nevertheless, the interest in sustainability issues has been more recent in the specific case of Spain. This study analyses the strategic plans developed by Spanish universities in the last decade with two different aims: first, we examine the extent to which Spanish universities are incorporating strategies on sustainability. The second goal evaluates whether the presence of strategies on sustainability in Spanish universities could be associated with coercive and mimetic pressures. Findings indicate the low presence of strategies on sustainability in Spanish universities. Moreover, the results seem to suggest that the presence of strategies on sustainability in Spanish universities could be linked with coercive and mimetic pressures emanating from the State performance funding for universities. The results indicate that universities usually incorporate practices and strategies on sustainability as a response of the pressure exerted by institutional forces, such as the funding systems of higher education institutions.     

On causes of illegal waste dumping in Slovakia

This paper examines the determinants of illegal waste dumping at the county level in Slovakia (in 77 of 79 counties), using a truncated regression model. It analyzes a unique data-set composed of illegal dumping data provided by the TrashOut platform and sociodemographic data from the national statistical authority.

This study shows that a higher level of expected overall waste production results in a higher rate of illegally dumped waste and a higher number of illegal dumping sites. More precisely, income has a positive impact on the rate of illegal waste dumping, poverty influences the rate of illegal dumping negatively and a higher level of education does not result in more responsible waste management. On the contrary, higher education has a positive influence on the rate of dumping. A negative relationship between costs of illegal waste disposal and dumping rate, as well as a positive relationship between costs of legal waste disposal and dumping rate has been revealed.     

Landfill leachate enhances fermentative hydrogen production from glucose and sugarcane processing derivatives

Fermentation can use renewable raw materials as substrate, which makes it a sustainable method to obtain H₂. This study evaluates H₂ production by a mixed culture from substrates such as glucose and derivatives from sugarcane processing (sucrose, molasses, and vinasse) combined with landfill leachate. The leachate alone was not a suitable substrate for biohydrogen production. However, leachate blended with glucose, sucrose, molasses, or vinasse increased the H₂ production rate by 2.0-, 2.8-, 4.6-, and 0.5-fold, respectively, as compared with the substrates without the leachate. Determination of metals (Cu, Cd, Pb, Hg, Ni, and Fe) at the beginning and at the end of the fermentative assays showed how they were consumed during the fermentation and demonstrated improved H₂ production. During fermentation, Cu, Fe, and Cd were the most consumed leachate metals. The best substrate combination to produce H₂ was molasses and leachate, which gave high volumetric productivity—469 ml H₂/l h. However, addition of the leachate to the substrates stimulated lactic acid formation pathways, which lowered the H₂ yield. The use of leachate combined with sugarcane processing derivatives as substrates could add value to the leachate and reduce its polluting power, generating a clean energy source from renewable raw materials.     

The Influence of Artificial Photodegradation on Properties of Poly(3-hydroxybutyrate-<Emphasis Type="Italic">co</Emphasis>-3-hydroxyvalerate)(PHBV)/Graphite Nanosheets (GNS) Nanocomposites

The potential use of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/graphite nanosheets (GNS) as a biodegradable nanocomposite has been explored. PHBV/GNS nanocomposites films were prepared by solution casting at various concentrations of GNS—0.25, 0.50 and 1.00 wt% GNS. The films were exposed to artificial ultraviolet radiation (UV) during 52 h. The effect of GNS on PHBV photodegradation was investigated and compared to neat PHBV film. The artificial photodegradation induced changes in physical (weight loss), chemical carbonyl index by Fourier transform infrared spectroscopy, thermal degree of crystallinity and melting temperature by differential scanning calorimetry and morphological scanning electron microscopy characteristics. Based on the results obtained from aforementioned analyzes it was verified that GNS inhibits the oxidative degradation of PHBV matrix.     

Utilization of Waste Lignin and Hydrolysate From Chromium Tanned Waste in Blends of Hot-Melt Extruded PVA-Starch

The demand for biodegradable plastic material is increasing worldwide. However, the cost remains high in comparison with common forms of plastic. Requirements comprise low cost, good UV-stability and mechanical properties, as well as solubility and water uptake lead to the preparation of multi-component polymer blends based on polyvinyl alcohol and starch in combination with waste products that are hard to utilize—waste lignin and hydrolysate extracted from chromium tanned waste. Surprisingly the addition of such waste products into PVA gives rise to blends with better biodegradability than commercial PVA in an aquatic aerobic environment with non-adapted activated sludge. These blends also exhibited greater solubility in the water and UV stability than commercial PVA. Tests on the processing properties of the blends (melt flow index, tensile strength and elongation at break of the films) as well as their mechanical properties showed that materials based on these blends might be applied in agriculture (for example as the systems for controlled-release pesticide or fertilizer) and, somewhat, in the packaging sector.     

One-Component Spray Polyurethane Foam from Liquefied Pinewood Polyols: Pursuing Eco-Friendly Materials

The use of petroleum-derived products should be avoided regarding the principles of green and sustainable chemistry. The work reported herein, is aimed at the liquefaction of pine shavings for the production of an environmentally-friendly polyol suitable to be used in the formulations of sprayable polyurethane foams. The biopolyols were obtained in high yield and were used to replace those derived from fossil sources, to produce more “greener” polyurethane foams and therefore, less dependent on petroleum sources, since the polyol component was substituted by products resulting from biomass liquefaction. The partial and fully exchange of the polyols was accomplished, and the results compared with a reference foam. The foams were afterward, chemical, physical, morphological, and mechanically characterized. The complete replacement of polyether polyol and polyol polyester has presented some similar characteristics as that used as a reference, validating that the path chosen for the development of more sustainable materials is on the right track for the contribution to a cleaner world.     

Static and Dynamic Behavior of Fibrous Polymeric Composite Materials at Different Environmental Conditions

The study of static and dynamic behavior of environmentally conditioned fibre reinforced polymeric (FRP) composites is necessary and crucial to examine the durability, reliability and sustainability of these noble materials. FRP composites are being used all around the globe and substituting the conventional materials, starting from mini toys to large aerospace components. Present review has introduced to accumulate and understand the disseminate literature in concentrating the significance of understanding the static and dynamic behavior of FRPs with changing environmental conditionings (hygrothermal, low and high temperature, salt solution, freeze thaw, UV light) and with the interaction of different nano-fillers. Their stability and integrity in diverse service environments may be reformed by their reactions against different nature of loadings i.e. static or dynamic and the components such as fibre, matrix and fibre/matrix interfaces in those environments. The static and dynamic states of loading may come with a possible weaker region to encounter the durability and integrity of the composites. To understand the exact failure modes that correlates the position of environmentally conditioned interfaces and dynamic state of loadings, thus confusing the estimation of its overall performance and mechanical behavior. Interface reliability and durability is vital since in-service environments the degradation in the interfacial region leads to complete composite failure. Therefore, the study of combined effects of various in-service environmental conditions and the role of static and dynamic behavior on the interface will be a crucial part related to the multiaxial dynamic states of failures occurring in FRP’s.     

Recent Changes in Stream Flashiness and Flooding,and Effects of Flood Management in North Carolina and Virginia

The southeastern United States has undergone anthropogenic changes in landscape structure, with the potential to increase (e.g., urbanization) and decrease (e.g., reservoir construction) stream flashiness and flooding. Assessment of the outcome of such change can provide insight into the efficacy of current strategies and policies to manage water resources. We (1) examined trends in precipitation, floods, and stream flashiness and (2) assessed the relative influence of land cover and flow‐regulating features (e.g., best management practices and artificial water bodies) on stream flashiness from 1991 to 2013. We found mean annual precipitation decreased, which coincided with decreasing trends in floods. In contrast, stream flashiness, overall, showed an increasing trend during the period of study. However, upon closer examination, 20 watersheds showed stable stream flashiness, whereas 5 increased and 6 decreased in flashiness. Urban watersheds were among those that increased or decreased in flashiness. Watersheds that increased in stream flashiness gained more urban cover, lost more forested cover and had fewer best management practices installed than urban watersheds that decreased in stream flashiness. We found best management practices are more effective than artificial water bodies in regulating flashy floods. Flashiness index is a valuable and straightforward metric to characterize changes in streamflow and help to assess the efficacy of management interventions.