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51.
Benoit Cushman-Roisin 《Environmental Fluid Mechanics》2008,8(5-6):543-549
Turbulent dispersion proceeds not only much faster but also in a qualitatively different manner than molecular diffusion. Yet, the majority of hydraulic, oceanic and atmospheric models rely on the concept of an eddy diffusivity. It is shown here that an alternative model can be developed to exhibit observed behavior. The new term in the diffusion equation, which is non-local, may be interpreted in terms of the probability density function (pdf) of the turbulent velocity. Different assumptions about this distribution lead to a family of models, one of which is the model proposed here and another, the classical Fickian model of diffusion. A connection is also made with models using fractional calculus. 相似文献
52.
Anne Pinton Julia Boubnova François Becmeur Pierre Kuhn Marie-Victoire Senat Julien Stirnemann Marianne Capelle Jonathan Rosenblatt Jérôme Massardier Pascal Vaast Gwenaelle Le Bouar Amélie Desrumaux Laure Connant Laetitia Begue Benoit Parmentier Franck Perrotin Alain Diguet Guillaume Benoist Charles Muszynski Aurélien Scalabre Norbert Winer Jean-Luc Michel Florence Casagrandre-Magne Jean-Marie Jouannic Denis Gallot Perrine Coste Mazeau Emmanuel Sapin Alexis Maatouk Anne-Hélène Saliou Loïc Sentilhes Florence Biquard Nicolas Mottet Romain Favre Alexandra Benachi Nicolas Sananès 《黑龙江环境通报》2020,40(8):949-957
53.
I Chu K M Ng F M Benoit D Moir 《Journal of environmental science and health. Part. B》1992,27(6):729-749
In the present study the biotransformation of phenanthrene in the rat and guinea pig was investigated. 14C-labelled phenanthrene was administered by gavage in corn oil to Sprague-Dawley rats (10 mg/kg b.w./day) and guinea pigs (10 mg/kg b.w./day). Urine and feces were separately collected for the determination of the radioactivity content, and pooled urine was used for the analysis of metabolites. Phenanthrene was metabolized by the rat and guinea pig to free hydroxylated phenanthrenes and their conjugates. The percentages of conjugates, expressed as the total urinary radioactivity, were 39% glucuronides, 24% sulfates and 18% cysteinylglycine for rats; and 39% glucuronides, 23% sulfates and 28% cysteinylglycine for guinea pigs. Enzymatic hydrolysis of glucuronides and sulfates resulted in the formation of free 1,2-, 3,4- and 9,10-dihydrodiols of phenanthrene and 1-, 2-, 3-, and 4-hydroxyphenanthrene in both species. 相似文献
54.
The phenylurea herbicide isoproturon, 3-(4-isopropylphenyl)-1,1-dimethylurea (IPU), is widely used to control pre- and post-emergence of grass and broad-leaved weeds in cereal crops. Its degradation in soils is a key process for assessing its leaching risk to groundwater resources. The degradation properties of various samples from surface and subsurface soil (down to 1m depth) of a heterogeneous agricultural field were studied using (14)C-IPU. Laboratory incubations were carried out at 22 and 10 degrees C and at water contents 90% and 50% of the estimated water holding capacity (eWHC) corresponding to water potentials between -56 kPa and -660 MPa. Degradation was found to be more sensitive to water content variations than to temperature variations in the ranges that we used. For surface layers, at 10 and 22 degrees C, the degradation half-life increased by a factor 10 and 15, respectively, when water content decreased from 90% to 50% eWHC. Under optimal degradation conditions (i.e. 22 degrees C and 90% eWHC), 3-(4-isopropylphenyl)-1-methylurea (MDIPU) was the main metabolite in surface samples. At subsurface depths, IPU half-lives were larger than 100 d, IPU was the main compound after 92 d of incubation and the main metabolite was an unidentified polar metabolite. These results suggest a metabolic pathway involving hydroxylations for subsurface materials. IPU degradation was largely affected by water availability in both surface and subsurface horizons. Clay content seemed to play a major role in degradation processes in subsurface soil by determining through sorption IPU availability in soil solution and/or by limiting water availability for microorganisms. 相似文献
55.
Particulate matter in urban rivers transports a significant fraction of pollutants, changes rapidly during storm events, and is difficult to characterize. In this study, the physical speciation of trace metals and organic C in an urban river and upstream headwaters site in Torrington, CT, were measured during a winter rain-on-snow event. In addition, a selective fractionation scheme, using membrane and tangential-flow ultrafiltration methods to separate suspended particulate matter into sand, silt, clay, and colloid fractions, was evaluated based on the appropriateness of the chosen size categories. During peak runoff at the urban river site, total-recoverable concentrations of the metals Cu and Pb increased 6- and 13-fold to 16.9 and 9.5 microg L(-1), respectively, compared with baseflow concentrations. Concentrations of Cu and Pb reached only 0.9 and 0.86 microg L(-1) at the headwaters site. For the measured storm event, the majority of metals were transported by the urban river in association with coarse silt (20-80 microm particle diam.) during peak runoff. During peak runoff at the urban site, organic C associated with the large colloid fraction (0.1-1.0 microm) increased from 5% (at baseflow) to 54% of the total C in transport, whereas dissolved organic C and that associated with smaller colloids decreased from 91.5% (at baseflow) to 41% of the total. Other elements that were monitored as part of the study were Na, K, Ca, Mg, Fe, Mn, Al, Cd, Cl-, NO3(-), and SO4(2-). The chosen fractionation scheme was useful to characterize pollutant transport during this event, but further testing should be undertaken to determine the most appropriate size range categories, and to ensure that the sizes measured are comparable to those used in other studies. 相似文献
56.
57.
Ehrich Dorothée Schmidt Niels M. Gauthier Gilles Alisauskas Ray Angerbjörn Anders Clark Karin Ecke Frauke Eide Nina E. Framstad Erik Frandsen Jay Franke Alastair Gilg Olivier Giroux Marie-Andrée Henttonen Heikki Hörnfeldt Birger Ims Rolf A. Kataev Gennadiy D. Kharitonov Sergey P. Killengreen Siw T. Krebs Charles J. Lanctot Richard B. Lecomte Nicolas Menyushina Irina E. Morris Douglas W. Morrisson Guy Oksanen Lauri Oksanen Tarja Olofsson Johan Pokrovsky Ivan G. Popov Igor Yu. Reid Donald Roth James D. Saalfeld Sarah T. Samelius Gustaf Sittler Benoit Sleptsov Sergey M. Smith Paul A. Sokolov Aleksandr A. Sokolova Natalya A. Soloviev Mikhail Y. Solovyeva Diana V. 《Ambio》2020,49(3):801-804
Ambio - In the original published article, some of the symbols in figure 1A were modified incorrectly during the typesetting and publication process. The correct version of the figure is provided... 相似文献
58.
Rouzbeh Tehrani Monica M. Lyv Benoit Van Aken 《Environmental science and pollution research international》2014,21(10):6346-6353
The polychlorinated biphenyl (PCB)-degrading bacterium, Burkholderia xenovorans LB400, was capable of transforming three hydroxylated derivatives of 2,5-dichlorobiphenyl (2,5-DCB) (2′-hydroxy- (2′-OH-), 3′-OH-, and 4′-OH-2,5-DCB) when biphenyl was used as the carbon source (i.e., biphenyl pathway-inducing condition), although only 2′-OH-2,5-DCB was transformed when the bacterium was growing on succinate (i.e., condition non-inductive of the biphenyl pathway). On the contrary, hydroyxlated derivatives of 2,4,6-trichlorobiphenyl (2,4,6-TCB) (2′-OH-, 3′-OH-, and 4′-OH-2,4,6-TCB) were not significantly transformed by B. xenovorans LB400, regardless of the carbon source used. Gene expression analyses showed a clear correlation between the transformation of OH-2,5-DCBs and expression of genes of the biphenyl pathway. The PCB metabolite, 2,5-dichlorobenzoic acid (2,5-DCBA), was produced following the transformation of OH-2,5-DCBs. 2,5-DCBA was not further transformed by B. xenovorans LB400. The present study is significant because it provides evidence that PCB-degrading bacteria are capable of transforming hydroxylated derivatives of PCBs, which are increasingly considered as a new class of environmental contaminants. 相似文献
59.
Monique Boily Benoit Sarrasin Christian DeBlois Philippe Aras Madeleine Chagnon 《Environmental science and pollution research international》2013,20(8):5603-5614
In Québec, as observed globally, abnormally high honey bee mortality rates have been reported recently. Several potential contributing factors have been identified, and exposure to pesticides is of increasing concern. In maize fields, foraging bees are exposed to residual concentrations of insecticides such as neonicotinoids used for seed coating. Highly toxic to bees, neonicotinoids are also reported to increase AChE activity in other invertebrates exposed to sub-lethal doses. The purpose of this study was therefore to test if the honey bee’s AChE activity could be altered by neonicotinoid compounds and to explore possible effects of other common products used in maize fields: atrazine and glyphosate. One week prior to pollen shedding, beehives were placed near three different field types: certified organically grown maize, conventionally grown maize or non-cultivated. At the same time, caged bees were exposed to increasing sub-lethal doses of neonicotinoid insecticides (imidacloprid and clothianidin) and herbicides (atrazine and glyphosate) under controlled conditions. While increased AChE activity was found in all fields after 2 weeks of exposure, bees close to conventional maize crops showed values higher than those in both organic maize fields and non-cultivated areas. In caged bees, AChE activity increased in response to neonicotinoids, and a slight decrease was observed by glyphosate. These results are discussed with regard to AChE activity as a potential biomarker of exposure for neonicotinoids. 相似文献
60.
Occurrence and toxicity of antimicrobial triclosan and by-products in the environment 总被引:1,自引:0,他引:1
Bedoux G Roig B Thomas O Dupont V Le Bot B 《Environmental science and pollution research international》2012,19(4):1044-1065