全文获取类型
收费全文 | 18147篇 |
免费 | 185篇 |
国内免费 | 162篇 |
专业分类
安全科学 | 514篇 |
废物处理 | 752篇 |
环保管理 | 2507篇 |
综合类 | 2485篇 |
基础理论 | 4830篇 |
环境理论 | 5篇 |
污染及防治 | 5264篇 |
评价与监测 | 1174篇 |
社会与环境 | 838篇 |
灾害及防治 | 125篇 |
出版年
2022年 | 127篇 |
2021年 | 158篇 |
2020年 | 99篇 |
2019年 | 142篇 |
2018年 | 246篇 |
2017年 | 245篇 |
2016年 | 405篇 |
2015年 | 343篇 |
2014年 | 509篇 |
2013年 | 1543篇 |
2012年 | 600篇 |
2011年 | 775篇 |
2010年 | 610篇 |
2009年 | 717篇 |
2008年 | 823篇 |
2007年 | 876篇 |
2006年 | 762篇 |
2005年 | 642篇 |
2004年 | 661篇 |
2003年 | 614篇 |
2002年 | 619篇 |
2001年 | 757篇 |
2000年 | 563篇 |
1999年 | 311篇 |
1998年 | 233篇 |
1997年 | 222篇 |
1996年 | 270篇 |
1995年 | 269篇 |
1994年 | 256篇 |
1993年 | 230篇 |
1992年 | 206篇 |
1991年 | 187篇 |
1990年 | 208篇 |
1989年 | 190篇 |
1988年 | 181篇 |
1987年 | 171篇 |
1986年 | 150篇 |
1985年 | 146篇 |
1984年 | 176篇 |
1983年 | 175篇 |
1982年 | 166篇 |
1981年 | 170篇 |
1980年 | 136篇 |
1979年 | 162篇 |
1978年 | 108篇 |
1977年 | 103篇 |
1976年 | 88篇 |
1975年 | 95篇 |
1973年 | 93篇 |
1972年 | 99篇 |
排序方式: 共有10000条查询结果,搜索用时 203 毫秒
551.
552.
C. Nguyen A. J. Soulier P. Masson S. Bussière J. Y. Cornu 《Environmental science and pollution research international》2016,23(4):3152-3164
This work focuses on the exposure of maize plants to nanomolar concentrations of Cd, which is relevant for agricultural soils cropped with food and feed plants. Maize plants were cultivated in nutrient solution at 0.8 or 20 nM Cd during the vegetative growth stages. No significant hormesis or toxic effects of Cd were observed on maize growth, but a decrease in the allocation of Cd to shoots between the 0.8 and 20 nM Cd exposures revealed that the plants already responded to these low concentrations of Cd according to a shoot Cd excluder strategy. The Cd, Cu and Zn concentrations in shoots decreased with time as the result of an early decrease in the root/shoot ratio and of a decrease in the coefficient of allocation to aboveground for Zn and Cd at 20 nM. As a consequence, shoots of young plants were richer in micronutrients Cu and Zn but also in toxic Cd. The rate of delivery of Cd, Cu and Zn from xylem sap was successfully used to predict the time course of concentrations of Cd, Cu and Zn in the shoot. However, it overestimated the actual concentrations of Cd in the shoot, presumably because the reallocation of this trace element from shoots back to roots was not taken into account. 相似文献
553.
Release of PCBs from Silvretta glacier (Switzerland) investigated in lake sediments and meltwater 总被引:1,自引:0,他引:1
P. A. Pavlova M. Zennegg F. S. Anselmetti P. Schmid C. Bogdal C. Steinlin M. Jäggi M. Schwikowski 《Environmental science and pollution research international》2016,23(11):10308-10316
This study is part of our investigations about the release of persistent organic pollutants from melting Alpine glaciers and the relevance of the glaciers as secondary sources of legacy pollutants. Here, we studied the melt-related release of polychlorinated biphenyls (PCBs) in proglacial lakes and glacier streams of the catchment of the Silvretta glacier, located in the Swiss Alps. To explore a spatial and temporal distribution of chemicals in glacier melt, we combined two approaches: (1) analysing a sediment record as an archive of past remobilization and (2) passive water sampling to capture the current release of PCBs during melt period. In addition, we determined PCBs in a non-glacier-fed stream as a reference for the background pollutant level in the area. The PCBs in the sediment core from the Silvretta lake generally complied with trends of PCB emissions into the environment. Elevated concentrations during the most recent ten years, comparable in level with times of the highest atmospheric input, were attributed to accelerated melting of the glacier. This interpretation is supported by the detected PCB fractionation pattern towards heavier, less volatile congeners, and by increased activity concentrations of the radioactive tracer 137Cs in this part of the sediment core. In contrast, PCB concentrations were not elevated in the stream water, since no significant difference between pollutant concentrations in the glacier-fed and the non-glacier-fed streams was detected. In stream water, no current decrease of the PCBs with distance from the glacier was observed. Thus, according to our data, an influence of PCBs release due to accelerated glacier melt was only detected in the proglacial lake, but not in the other compartments of the Silvretta catchment. 相似文献
554.
555.
Petra C. Lindholm-Lehto Heidi S. J. Ahkola Juha S. Knuutinen Jaana Koistinen Kirsti Lahti Heli Vahtera Sirpa H. Herve 《Environmental science and pollution research international》2016,23(18):18043-18054
The occurrence of five pharmaceuticals, consisting of four anti-inflammatory and one antiepileptic drug, was studied by passive sampling and grab sampling in northern Lake Päijänne and River Vantaa. The passive sampling was performed by using Chemcatcher® sampler with a SDB-RPS Empore disk as a receiving phase. In Lake Päijänne, the sampling was conducted during summer 2013 at four locations near the discharge point of a wastewater treatment plant and in the years 2013 and 2015 at four locations along River Vantaa. The samples were analyzed by liquid chromatography coupled to tandem mass spectrometry (LC-MS/MS) in the multiple reaction monitoring mode. The concentrations of carbamazepine, diclofenac, ibuprofen, ketoprofen, and naproxen in Lake Päijänne determined by passive sampling ranged between 1.4–2.9 ng L?1, 15–35 ng L?1, 13–31 ng L?1, 16–27 ng L?1, and 3.3–32 ng L?1, respectively. Similarly, the results in River Vantaa ranged between 1.2–40 ng L?1, 15–65 ng L?1, 13–33 ng L?1, 16–31 ng L?1, and 3.3–6.4 ng L?1. The results suggest that the Chemcatcher passive samplers are suitable for detecting pharmaceuticals in lake and river waters. 相似文献
556.
Richard M. Nthumbi Jane C. Ngila 《Environmental science and pollution research international》2016,23(20):20214-20231
A novel approach for the electrospinning and functionalization of nanocatalyst-loaded polyvinylidene fluoride/polyacrylonitrile (PVDF/PAN) composite grafted with acrylic acid (AA; which form polyacrylic acid (PAA) brush) and decorated with silver (Ag/PAN/PVDF-g-PAA-TiO2/Fe–Pd) designed for the dechlorination and photodegradation of pesticides was carried out. PAN was used both as a nitrogen dopant as well as a co-polymer. Smooth nanofibers were obtained by electrospinning a solution of 12:2 wt.% PVDF/PAN blend using dimethylformamide (DMF) as solvent. The nanofibers were grafted with AA by free-radical polymerization using 2,2′azobis(2-methylpropionitrile) (AIBN) as initiator. Both bimetallic iron–palladium (Fe–Pd) and titania (TiO2) nanoparticles (NP) were anchored on the grafted nanofibers via the carboxylate groups by in situ and ex situ synthesis. The Fe–Pd and nitrogen-doped TiO2 nanoparticles were subsequently used for dechlorination and oxidation of target pollutants (dieldrin, chlorpyrifos, diuron, and fipronil) to benign products. Structural and chemical characterizations of the composites were done using various techniques. These include surface area and porosity analyzer (ASAP) using the technique by Brunner Emmett Teller (BET), Fourier transform infrared (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscope (TEM) analyses were done. After dechlorination, the transformation products (TPs) for dieldrin, chlorpyrifos, diuron, and fipronil were obtained and identified using two-dimensional gas chromatography (time-of-flight) with a mass spectrometer detector (GCxGC-TOFMS). Analysis of total organic carbon (TOC) was carried out and used to extrapolate percentage mineralization. Experimental results showed that dechlorination efficiencies of 96, 93, 96, and 90 % for 1, 2, 2, and 3 h treatment period were respectively achieved for 5 ppm solutions of dieldrin, chlorpyrifos, diuron, and fipronil. The dechlorination of dieldrin, diuron, and fipronil follows first-order kinetics while that of chlorpyrifos followed pseudo-first order. Mineralization performance of 34 to 45 % were recorded when Fe–Pd was used, however upon electrospinning, doping, and grafting (Ag/PAN/PVDF-g-PAA-TiO2/Fe–Pd composite); it significantly increased to 99.9999 %. This composite reveals great potential for dechlorination and mineralization of pesticides in contaminated water. 相似文献
557.
Athar Habib-ur-Rehman Ambreen Sarah Javed Muhammad Hina Mehwish Rasul Sumaira Zafar Zafar Ullah Manzoor Hamid Ogbaga Chukwuma C. Afzal Muhammad Al-Qurainy Fahad Ashraf Muhammad 《Environmental science and pollution research international》2016,23(18):18320-18331
Environmental Science and Pollution Research - Maize tolerance potential to oil pollution was assessed by growing Zea mays in soil contaminated with varying levels of crude oil (0, 2.5 and... 相似文献
558.
Scholz C. Jones T. G. West M. Ehbair A. M. S. Dunn C. Freeman C. 《Environmental science and pollution research international》2016,23(18):18192-18199
Environmental Science and Pollution Research - The objective of this study was to monitor a newly constructed wetland (CW) in north Wales, UK, to assess whether it contributes to an improvement in... 相似文献
559.
P. Lemieux J. Wood J. Drake S. Minamyer E. Silvestri C. Yund 《Journal of the Air & Waste Management Association (1995)》2016,66(1):17-27
The Bio-response Operational Testing and Evaluation (BOTE) Project was a cross-government effort designed to operationally test and evaluate a response to a biological incident (release of Bacillus anthracis [Ba] spores, the causative agent for anthrax) from initial public health and law enforcement response through environmental remediation. The BOTE Project was designed to address site remediation after the release of a Ba simulant, Bacillus atrophaeus spp. globigii (Bg), within a facility, drawing upon recent advances in the biological sampling and decontamination areas. A key component of response to a biological contamination incident is the proper management of wastes and residues, which is woven throughout all response activities. Waste is generated throughout the response and includes items like sampling media packaging materials, discarded personal protective equipment, items removed from the facility either prior to or following decontamination, aqueous waste streams, and materials generated through the application of decontamination technologies. The amount of residual contaminating agent will impact the available disposal pathways and waste management costs. Waste management is an integral part of the decontamination process and should be included through “Pre-Incident” response planning. Overall, the pH-adjusted bleach decontamination process generated the most waste from the decontamination efforts, and fumigation with chlorine dioxide generated the least waste. A majority of the solid waste generated during pH-adjusted bleach decontamination was the nonporous surfaces that were removed, bagged, decontaminated ex situ, and treated as waste. The waste during the two fumigation rounds of the BOTE Project was associated mainly with sampling activities. Waste management activities may represent a significant contribution to the overall cost of the response/recovery operation. This paper addresses the waste management activities for the BOTE field test.Implications: Management of waste is a critical element of activities dealing with remediation of buildings and outdoor areas following a biological contamination incident. Waste management must be integrated into the overall remediation process, along with sampling, decontamination, resource management, and other important response elements, rather than being a stand-alone activity. The results presented in this paper will provide decision makers and emergency planners at the federal/state/tribal/local level information that can be used to integrate waste management into an overall systems approach to planning and response activities. 相似文献
560.
Lawrence C. Larsen Mena Shah 《Journal of the Air & Waste Management Association (1995)》2016,66(1):38-52
Although networks of environmental monitors are constantly improving through advances in technology and management, instances of missing data still occur. Many methods of imputing values for missing data are available, but they are often difficult to use or produce unsatisfactory results. I-Bot (short for “Imputation Robot”) is a context-intensive approach to the imputation of missing data in data sets from networks of environmental monitors. I-Bot is easy to use and routinely produces imputed values that are highly reliable. I-Bot is described and demonstrated using more than 10 years of California data for daily maximum 8-hr ozone, 24-hr PM2.5 (particulate matter with an aerodynamic diameter <2.5 μm), mid-day average surface temperature, and mid-day average wind speed. I-Bot performance is evaluated by imputing values for observed data as if they were missing, and then comparing the imputed values with the observed values. In many cases, I-Bot is able to impute values for long periods with missing data, such as a week, a month, a year, or even longer. Qualitative visual methods and standard quantitative metrics demonstrate the effectiveness of the I-Bot methodology.Implications: Many resources are expended every year to analyze and interpret data sets from networks of environmental monitors. A large fraction of those resources is used to cope with difficulties due to the presence of missing data. The I-Bot method of imputing values for such missing data may help convert incomplete data sets into virtually complete data sets that facilitate the analysis and reliable interpretation of vital environmental data. 相似文献