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排序方式: 共有356条查询结果,搜索用时 401 毫秒
301.
M.M. van der Voort R.M.M. van Wees J.M. Ham M.P.N. Spruijt A.C. van den Berg P.C.J. de Bruijn P.G.A. van Ierschot 《Journal of Loss Prevention in the Process Industries》2013,26(4):830-838
The need for transportation and storage of CO2 in bulk quantities is likely to increase in the near future. The handling of CO2 on such scale gives rise to a number of technological challenges and safety aspects. The accidental rupture of a vessel containing liquefied CO2 may lead to a Boiling Liquid Expanding Vapour Explosion (BLEVE). Whether explosive evaporation of liquefied CO2 is also possible at storage temperatures below the homogeneous nucleation temperature 271 K (?2 °C) is unclear.This article describes the results of 12 experiments with 40 L CO2 cylinders at various temperatures to investigate the temperature dependence of explosive evaporation. The cylinders were opened with linear shaped charges to simulate a near instantaneous rupture, and blast was measured at various locations. The observed blast could be clearly attributed to explosive evaporation. The results show that below the homogeneous nucleation temperature, BLEVE blast does not disappear abruptly, but instead follows a gradual decay. Predictions with a numerical BLEVE blast model overestimate the observed blast peak overpressure and impulse, but qualitatively show a similar behaviour. The energy lost by the acceleration of the cylinder parts is a possible reason for overestimations of the model.The consequence of the test results is that for accident scenarios with CO2 at low temperatures a BLEVE should not be neglected in hazard assessments. Future large scale bulk storage will take place at a 105 times larger volume than the cylinders applied in the current small scale experiments. We expect that the blast-reducing effects of a tank shell will disappear at such scale.The research leading to these results has received funding from the European Community's Seventh Framework Programme (FP7/2007–2013) under grant agreement n° 241381. 相似文献
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Mats Tysklind Albertus Bart T. C. Bosveld Patrik Andersson Eeske Verhallen Theo Sinnige Willem Seinen Christoffer Rappe Martin van den Berg 《Environmental science and pollution research international》1995,2(4):211-216
Induction of ethoxyresorufin-O-deethylase (EROD) activity and porphyrin accumulation shows different structure-activity relationships for different polychlorinated biphenyls (PCBs) and 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD). Interactions between the two responses can strongly influence the induction and activity of EROD. The results support the conclusion that there are nonadditive interactions between nondioxin-like PCBs and dioxin-like compounds. The interaction between EROD activity and the porphyrin biosynthesis makes the prerequisite of additivity in the toxic equivalency factor concept for environmental mixtures highly spurious. Inhibition of EROD activity caused by non-dioxin like compounds could have a significant impact on the value of EROD activity as a biomarker in the present methods of risk assessment for these compounds. 相似文献
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Environmental Geochemistry and Health - A high soluble salt content in processed oil shales or other mineral wastes can pose problems in vegetation establishment on disposal piles and in water... 相似文献
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Techniques to monitor growth and mortality of live trees, and longevity of snags were developed and tested on 8 units in the Oregon and Washington Cascades where new forestry (structural retention) cuttings were utilized. Time and costs were quantified. The total area of three aggregated units and five dispersed units was 27.8 ha, with 2407 trees and snags measured on 25.1 ha of sample area. Cost of field work was approximately $4590 (4 person crew at 6 weeks) while costs of data entry, analysis and report writing were approximately $2000 (250 person hours). Monitoring is an important component of adaptive management and is essential if we are to understand the ramifications of new silvicultural systems. 相似文献
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Murk AJ Van den Berg JH Fellinger M Rozemeijer MJ Swennen C Duiven P Boon JP Brouwer A Koeman JH 《Environmental pollution (Barking, Essex : 1987)》1994,86(1):21-30
In this study the possible toxic and biochemical effects of one intraperitoneal dose of 5 or 50 mg kg(-1) of 3,3',4,4'-tetrachlorobiphenyl (CB-77) or 50 or 200 mg kg(-1) of Clophen A50 (CloA50) on 28-day-old eider ducklings (Somateria mollissima) were investigated. After ten days, no significant differences could be observed in any of the toxic and biochemical parameters studied, apart from ethoxyresorufin (EROD) activity, when comparing group average values of the dosed and control animals. However, significant correlations were observed at day 10 after exposure between the individual internal PCB concentration and body weight gain and beak length growth (negative correlations in the CloA50 groups); relative liver weight and cytochrome P4501A activity (positive correlations in CB-77 and CloA50 groups); plasma thyroid-hormone and hepatic retinoid levels (negative correlations in CB-77 groups); and plasma retinol levels and the ratio plasma retin/hepatic retinyl palmitate (positive correlations in CB-77 groups only). Animal activity was significantly reduced in the group that received 50 mg CB-77 kg(-1). These observations indicate that eider ducks are a sensitive species to PCB toxicity and may be at risk for development of adverse health effects in relatively highly contaminated areas such as the Waddenzee. 相似文献
310.
Indications for the tracking of elevated nitrogen levels through the fungal route in a soil food web 总被引:1,自引:0,他引:1
Hogervorst RF Dijkhuis MA van der Schaar MA Berg MP Verhoef HA 《Environmental pollution (Barking, Essex : 1987)》2003,126(2):257-266
The objective of the present study was to determine the effects of elevated N in dead organic matter on the growth of fungi and to establish the consequences for the development of microbivores. Therefore, three fungal species were cultured on Scots pine litter differing in N content. The growth of the soil fungal species Trichoderma koningii, Penicillium glabrum and Cladosporium cladosporioides was directly influenced by the N content (ranging from 1.25 to 2.19% N) of the substrate. For all three fungal species maximum growth was highest at intermediate N content (1.55%) of the substrate. The fungivorous collembolan Orchesella cincta reached highest asymptotic body mass when fed with C. cladosporioides, grown on litter medium with intermediate N content (1.55%). The growth of O. cincta was lower when fed with C. cladosporioides from litter medium with the highest N content (2.19%). Similar results were obtained in mesocosm experiments in which pine litter with three levels of N (1.11, 1.78, 2.03% N) was used as substrate for the fungi. On litter with the highest N content (2.03%) hyphal length and asymptotic body mass of O. cincta were reduced. The results show that the N content of the substrate determines the growth of both fungi and fungivores, and suggest that elevated levels of N in soil track through the fungal part of the soil food web. 相似文献