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111.
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环境样品中多氯联苯残留物的色谱/质谱定量测定 总被引:2,自引:0,他引:2
多氯联苯(简称PCB)是全球性的环境污染物之一,实际上它是由一百多种氯化联苯异构体所组成的。为了测定复杂环境样品中的PCB总残留量,Webb等首先提出了“各峰和”定量法,我们亦在先前的工作中采用二种国产PCB标样建立了相应的填充柱色谱定量方法,即分别定量测定样品中各氯化联苯色谱峰所含的PCB量,叠加后得到PCB总残留量。但是有机氯农药的广泛污染经常使PCB的测定受到干扰。我们研究了PCB及几种国内常用有机氯农药的质谱图,找出了一些能相互抗干扰的特征离子,将这些质量色谱图叠加所得的选择离子流可用于定量分析,使我们有可能同时测定几种化合物(见图1),省略了繁杂的化学分离和提纯步骤,缩短了分析时间,避免了处置过程中痕量样品的损失或沾污,增加了测定的可靠性。 相似文献
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北京市妫水河流域景观生态学分析 总被引:2,自引:0,他引:2
基于GIS的空间分析平台,以景观生态学的方法建模,分析了北京市妫水河流域的景观格局特征,并与妫水河平原的景观格局特征进行了比较,发现在妫水河平原范围内,由于人为干扰程度的加剧,整体生态格局的异质性下降、碎裂化增加,景观生态格局的稳定性和安全性比之妫水河流域有所下降.分析了妫水河流域面临的问题及其原因,进而提出妫水河流域生态恢复的建议和措施. 相似文献
116.
Jiejie Bian Huaqiao Gui Zhibo Xie Tongzhu Yu Xiuli Wei Wenyu Wang Jianguo Liu 《环境科学学报(英文版)》2020,32(4):275-285
In order to realize accurate dynamic control of supersaturation and to study condensation growth characteristics of nanoparticles through different levels of super saturation,a series of parametric analyses and systematic comparisons between two-stage and three-stage operating temperature designs were simulated with COMSOL Multiphysics.The simulation results showed that the three-stage operating temperature did not change peak supersaturation compared with two operating temperatures,and the three-stage operating temperature was superior in decreasing the amount of water vapor and the temperature,thus lowering particle loss and variation in detection and collection.The peak supersaturation level increased by 0.3 as the flow rate increased from 0.6 to 2.0 L/min,but the supersaturation peak moved from 0.0027 z0 to 0.08 z0(i.e.,the growth time and the final size decreased by 40%).Peak supersaturation increased as the temperature difference increased or the temperature difference window was shifting left,and minimum activation size decreased.Shifting the 70℃temperature difference window from 9℃,79℃-1℃,71℃for the condenser and initiator temperatures resulted in peak supersaturation in the centerline being above 5.8,and the activation size changed as low as 1 nm.Experiments with flow rates varying by a factor of 2.5(from 0.6 to 1.5 L/min) resulted in a final size decrease of 43%(from 3.2 to 1.8 μm),and experimental results of outlet particle size distributions were equivalent with theoretical analysis as the operating temperature was changed. 相似文献
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Absorption and accumulation of fluoride (F) from ambient air by mulberry leaves, and its transfer and effects on silkworm development, were examined. When the concentration of F in air exceeded 1.5 microg dm(-2). day (-1), using lime filter papers as static monitors, the F content of mulbery leaves was more than 30 ppm, the threshold for injury to silkworm larvae. Fluoride-polluted mulberry leaves inhibited growth and development of silkworms. Leaves containing more than 80 ppm F severely inhibited cocoon production. Fluoride was absorbed from the atmosphere by the mulberry leaf and was transferred to the silkworm, soil, water, and back to the atmosphere, forming a cycle. 相似文献
118.
阐述了大型锅炉排汽噪声治理的原理。通过对排汽噪声特征的分析以及消声效果试验,优选设计出一种效果良好的消声器———节流降压、小孔喷注复合消声器。 相似文献
119.
城市污水处理选址决策及程序设计 总被引:1,自引:0,他引:1
在分析影响城市污水处理场选址的自然及经济因素的基础上,利用层次分析方法构造选址模型.讨论了决策方法及利用计算机进行排序的程序设计步骤,并在IBM-PC机上对实际问题进行了计算. 相似文献
120.
Yu Shu-Wen Bian Yong-Mei Ma Guang-Jing Luo Jia-Ju 《Environmental monitoring and assessment》1990,14(2-3):239-246
Nanshan is located in the south suburb of Chongqing, Sichuan province in China. It is about 10 km from the city of Chongqing. There are about 2000 ha of forest, mainly Masson pines (Pinus massoniana Lamb) which have exhibited decline since the beginning of the 1980s. Surveys of stands estimated that 85% of Masson pines are injured. Symptomology of Masson pines includes tip necrosis of needles, thin crown, reduced needle length, premature abscission, branch dieback, reduced radial growth. The foliage of broadleaf treesRobinia pseudoacacia L,Quercus dentata Thunb,Eucalyptus robusta Sm,Erythrina variegata var. orientalis (L) Merr,Faulownia fortunei (Seem) Hemsl,Rosa chinensis Jacq, also displayed necrotic lesions, both marginal and interveinous, most are brown or bleached. Foliage symptoms are similar to that produced in laboratory fumigation experiments with gaseous air pollutants SO2 or HF. The foliage injury intensity is related to the distance from the city. Forest in some localities furthest from the city exhibit approximately normal growth.Three monitoring sites had been selected in Nanshan forest area. At two sites pine trees were severely damaged. At another site they showed little damage. Atmospheric SO2 and fluoride concentrations had been examined. The average value of SO2 and fluoride concentrations at the two former sites were much higher than that at the latter site. The injury intensity was consistent with an increase in the concentrations of SO2 and fluoride. The sulphur and fluoride contents of tree leaves were also monitored. Sulphur contents of pine needles at the two former sites were generally more than that at the latter. The same tendency is observed in broadleaf trees. Higher levels of fluoride had been found in foliage of injured trees compared to unijured trees.Chongqing is also an acid rain region. The yearly average pH value of precipitation approaches to 4.0, and the frequency 100%. The pH values of acid rain at the three sites in Nanshan region are 4.17, 4.20, and 4.38 respectively. The difference is not significant. Also no significant difference in soil pH among the three sites is observed. It is suggested that acid rain and the acidification of soil are not implicated in the decline of Masson pines in Nanshan region. 相似文献