Inter- and Intra-Annual Chemical Variability During the ice-Free Season in Lakes with Different Flushing Rates and Acid Deposition Histories

Quantifying chemical variability in different lake types is important for the assessment of both chemical and biological responses to environmental change. For monitoring programs that emphasize a large number of lakes at the expense of frequent samples, high variability may influence how representative single samples are of the average conditions of individual lakes. Intensive temporal data from long-term research sites provide a unique opportunity to assess chemical variability in lakes with different characteristics. We compared the intra- and inter-annual variability of four acidification related variables (Gran alkalinity, pH, sulphate concentration, and total base cation concentration) in four lakes with different flushing rates and acid deposition histories. Variability was highest in lakes with high flushing rates and was not influenced by historic acid deposition in our study lakes. This has implications for the amount of effort required in monitoring programs. Lakes with high flushing rates will require more frequent sampling intervals than lakes with low flushing rates. Consideration of specific lake types should be included in the design of monitoring programs.     

A laboratory study of behavioral interactions of the Antarctic keystone sea star Odontaster validus with three sympatric predatory sea stars

The circumpolar sea star Odontaster validus is ubiquitous in the nearshore marine benthos of Antarctica. Despite its ecological importance, little is known of its behavioral interactions with other common sympatric sea stars. To examine these interactions we employed time-lapse video analyses conducted in a large laboratory tank (1.8 m diameter circular tank, 1,629 L). In each experimental trial, 34 adult O. validus were placed in a tight circular grouping on one side of the tank, and one adult individual of one of three common sympatric species of predatory sea star (Labidiaster annulatus, Diplasterias brandti, or Perknaster aurorae) was placed on the opposite side of the tank. Digital images of sea star movements were then captured at one min intervals over a 24 h period and aspects of sea star movements subsequently analyzed. Each 24 h treatment was replicated three times, as was a control treatment consisting only of O. validus. O. validus had significantly elevated levels of activity in the presence of P. aurorae when compared with the other two sea stars (potential chemically mediated response), and displayed a distinct “flight response” (change in direction and twofold to sixfold increase of speed) upon tactile contact with this species. Moreover, an “alarm response” was detected when individuals of O. validus that encountered a fleeing conspecific also fled the vicinity. In contrast, our results indicated that O. validus displays virtually no chemical or tactile behavioral responses to the large multi-armed L. annulatus and only weak tactile responses to D. brandti.     

Variations in Epilimnion Thickness in Small Boreal Shield Lakes: Relationships with Transparency, Weather and Acidification

We used multiple linear regression analysis to investigate relationships between late-summer epilimnion thickness, transparency, lake area, acidity and summer weather conditions in a large ($n = 116$) multi-year data set for 9 small Boreal Shield lakes. Dissolved organic carbon (DOC) was the best individual predictor of late summer epilimnion thickness ($r^{2} = 0.69$). Total chlorophyll~$a$, the number of days between ice-out and late-summer stratification, and lake area collectively explained an additional 14% of the variation in epilimnion thickness. The three attributes of summer weather that we examined, mean daily temperature, mean daily wind speed, and mean daily hours of bright sunshine, did not add to the predictive ability of our regression model. Lake acidity also did not add directly to the predictive ability of the model, likely because DOC concentrations already reflected the effects of pH. Our study supports an increasing body of evidence indicating that the dominant effects of climate change on lake thermal structure in small lakes will be through effects on processes that affect lake transparency.     

Characterization of gaseous pollutant and particulate matter emission rates from a commercial broiler operation part I: Observed trends in emissions

This paper characterizes the emission rates of size fractionated particulate matter, inorganic aerosols, acid gases, ammonia and methane measured over four flocks at a commercial broiler chicken facility. Mean emission rates of each pollutant, along with sampling notes, were reported in this paper, the first in a series of two. Sampling notes were needed because inherent gaps in data may bias the mean emission rates.The mean emission rates of PM₁₀ and PM_2.5 were 5.0 and 0.78 g day^?1 [Animal Unit, AU]^?1, respectively, while inorganic aerosols mean emission rates ranged from 0.15 to 0.46 g day^?1 AU^?1 depending on the season. The average total acid gas emission rate was 0.43 g day^?1 AU^?1 with the greatest contribution from nitrous and nitric acids and little contribution from sulfuric acid (as SO₂).Ammonia emissions were seasonally dependent, with a mean emission rate of 66.0 g day^?1 AU^?1 in the cooler seasons and 94.5 g day^?1 AU^?1 during the warmer seasons. Methane emissions were relatively consistent with a mean emission rate of 208 g day^?1 AU^?1.The diurnal pattern in each pollutant’s emission rate was relatively consistent after normalizing the hourly emissions according to each daily mean emission rate. Over the duration of a production cycle, all the measured pollutants’ emissions increased proportionally to the total live mass of birds in the house, with the exception of ammonia.Interrelationships between pollutants provide evidence of mutually dependent release mechanisms, which suggests that it may be possible to fill data gaps with minimal data requirements. In the second paper (Roumeliotis, T.S., Dixon, B.J., Van Heyst, B.J. Characterization of gaseous pollutants and particulate matter emission rates from a commercial broiler operation part II: correlated emission rates. Atmospheric Environment, 2010.), regression correlations are developed to estimate daily mean emission rates for data gaps and, using the normalized hourly diurnal patterns from this paper, emission factors were generated for each pollutant.     

Occurrence and behavior of per‐ and polyfluoroalkyl substances from aqueous film‐forming foam in groundwater systems

Per‐ and polyfluoroalkyl substances (PFAS) are fluorinated compounds and the active ingredient in aqueous film‐forming foam (AFFF). AFFF has been identified as a significant source of PFAS contamination in groundwater. PFAS are also present in many other industrial and consumer products and their manufacture and use has led to numerous contaminated sites. Human health risks have been identified with studies linking firefighter cancers to training facilities where AFFF was used. Given the widespread release of these compounds to the environment and their potential health risks, understanding their mobility characteristics is important. This article details the occurrence and behavior of these substances in groundwater systems to help guide the emerging fields of PFAS investigation and remediation. Background is presented on AFFF and PFAS source characteristics, including common industrial and consumer PFAS sources. In addition, chemical properties, sorption and retention parameters, and observed transformation properties of PFAS and related compounds are discussed. Finally, knowledge gaps are identified for future laboratory and field studies.     

Open-path,closed-path,and reconstructed aerosol extinction at a rural site

The Handix Scientific open-path cavity ringdown spectrometer (OPCRDS) was deployed during summer 2016 in Great Smoky Mountains National Park (GRSM). Extinction coefficients from the relatively new OPCRDS and from a more well-established extinction instrument agreed to within 7%. Aerosol hygroscopic growth (f(RH)) was calculated from the ratio of ambient extinction measured by the OPCRDS to dry extinction measured by a closed-path extinction monitor (Aerodyne’s cavity-attenuated phase shift particulate matter extinction monitor [CAPS PMex]). Derived hygroscopicity (relative humidity [RH] < 95%) from this campaign agreed with data from 1995 at the same site and time of year, which is noteworthy given the decreasing trend for organics and sulfate in the eastern United States. However, maximum f(RH) values in 1995 were less than half as large as those recorded in 2016—possibly due to nephelometer truncation losses in 1995. Two hygroscopicity parameterizations were investigated using high-time-resolution OPCRDS+CAPS PMex data, and the κ_ext model was more accurate than the gamma model. Data from the two ambient optical instruments, the OPCRDS and the open-path nephelometer, generally agreed; however, significant discrepancies between ambient scattering and extinction were observed, apparently driven by a combination of hygroscopic growth effects, which tend to increase nephelometer truncation losses and decrease sensitivity to the wavelength difference between the two instruments as a function of particle size. There was not a statistically significant difference in the mean reconstructed extinction values obtained from the original and the revised IMPROVE (Interagency Monitoring of Protected Visual Environments) equations. On average, IMPROVE reconstructed extinction was ~25% lower than extinction measured by the OPCRDS, which suggests that the IMPROVE equations and 24-hr aerosol data are moderately successful in estimating current haze levels at GRSM. However, this conclusion is limited by the coarse temporal resolution and the low dynamic range of the IMPROVE reconstructed extinction.

Implications: Although light extinction, which is directly related to visibility, is not directly measured in U.S. National Parks, existing IMPROVE protocols can be used to accurately infer visibility for average humidity conditions, but during the large fraction of the year when humidity is above or below average, accuracy is reduced substantially. Furthermore, nephelometers, which are used to assess the accuracy of IMPROVE visibility estimates, may themselves be biased low when humidity is very high. Despite reductions in organic and sulfate particles since the 1990s, hygroscopicity, particles’ affinity for water, appears unchanged, although this conclusion is weakened by the previously mentioned nephelometer limitations.     

Simulating water and nitrogen loss from an irrigated paddy field under continuously flooded condition with Hydrus-1D model

Environmental Science and Pollution Research - Agricultural non-point source pollution is a major factor in surface water and groundwater pollution, especially for nitrogen (N) pollution. In this...     

On dispersion above a forest—Measurements and methods

Data collected over a mixed conifer/deciduous forest at the U.S. Department of Energy’s Savannah River Site in South Carolina using sonic anemometry reveal that on-site and real-time measurements of the velocity component standard deviations, σ_v and σ_w, are preferred for dispersion modeling. Such data are now easily accessible, from the outputs of cost-effective and rugged sonic anemometers. The data streams from these devices allow improvements to conventional methodologies for dispersion modeling. In particular, extrapolation of basic input data from a nearby location to the site of the actual release can be facilitated. In this regard reliance on the velocity statistics σ_v and σ_w appears to be preferred to the conventional σ_θ and σ_?. In the forest situations addressed here, the uncertainties introduced by extrapolating initializing properties (u, θ, σ_θ, and σ_?, or alternatively, σ_v and σ_w) from some location of actual measurement to some nearby location where an actual release occurs are similar to those associated with the spread of the plume itself and must be considered in any prediction of the likelihood of downwind concentration (exposure) exceeding some critical value, i.e., a regulatory standard. Consideration of plume expansion factors related to meander will not necessarily cause predicted downwind maxima within a particular plume to be decreased; however, the probability of exposure to this maximum value at any particular location will be reduced. Three-component sonic anemometers are affordable and reliable, and are now becoming a standard for meteorological monitoring programs subject to regulatory oversight. The time has come for regulatory agencies and the applied dispersion community to replace the traditional discrete sets of dispersion coefficients based on Pasquill stability by the direct input of measured turbulence data.

Implications: The continued endorsement of legacy Pasquill-Gifford stability schemes is presently under discussion among professional groups and regulatory agencies. The present paper is an attempt to introduce some rationality, for the case of a forested environment.     

Nitrate Concentrations in Springs Flowing into the Lower Flint River Basin,Georgia U.S.A.1

Allums, Stephanie E., Stephen P. Opsahl, Stephen W. Golladay, David W. Hicks, and L. Mike Conner, 2012. Nitrate Concentrations in Springs Flowing Into the Lower Flint River Basin, Georgia U.S.A. Journal of the American Water Resources Association (JAWRA) 48(3): 423-438. DOI: 10.1111/j.1752-1688.2011.00624.x Abstract: Analysis of long-term data from (2001-2009) in four springs that discharge from the Upper Floridan aquifer into the Flint River (southwestern Georgia, United States) indicate aquifer and surface-water susceptibility to nutrient loading. Nitrate-N concentrations ranged from 1.74 to 3.30 mg/l, and exceeded historical levels reported for the Upper Floridan aquifer (0.26-1.52 mg/l). Statistical analyses suggest increasing nitrate-N concentration in groundwater discharging at the springs (n = 146 over eight years) and that nitrate-N concentration is influenced by a dynamic interaction between depth to groundwater (an indicator of regional hydrologic conditions) and land use. A one-time synoptic survey of 10 springs (6 springs in addition to the 4 previously mentioned) using stable isotopes generated δ¹⁵N-NO₃⁻ values (4.8-8.4‰ for rural springs and 7.7-13.4‰ for developed/urban springs) suggesting mixed sources (i.e., fertilizer, animal waste, and soil organic nitrogen) of nitrate-N to rural springs and predominantly animal/human waste to urban springs. These analyses indicate a direct relation between nitrate-N loading since the 1940s and intensification of agricultural and urban land use. This study demonstrates the importance of evaluating long-term impacts of land use on water quality in groundwater springs and in determining how rapidly these changes occur.     

Dechlorination of trichloroethylene formed from 1,1,2,2-tetrachloroethane by dehydrochlorination in Portland cement slurry including Fe(II)

Transformation of 1,1,2,2-tetrachloroethane (1,1,2,2-TeCA) by Fe(II) in 10% cement slurries was characterized using a batch reactor system. 1,1,2,2-TeCA was completely converted to trichloroethylene (TCE) within 1h in all experiments, even in controls with cement that did not include Fe(II). Therefore, complete degradation of 1,1,2,2-TeCA depends on the behavior of TCE. The half-life of TCE was observed to be 15d when concentrations of Fe(II) and 1,1,2,2-TeCA were 98mM and 0.245mM, respectively. The kinetics of TCE removal was observed to be dependent on Fe(II) dose, pH and initial substrate concentration. Pseudo-first-order rate constants linearly increased with Fe(II) dose up to 198mM when initial target concentration was 0.245mM. Pseudo-first-order kinetics generally described the degradation reactions of TCE at a specific initial concentration, but a modified Langmuir-Hinshelwood model was necessary to describe the degradation kinetics of TCE over a wide range of initial concentrations. A surface reaction of TCE on active solids, which were formed from Fe(II) and products of cement hydration appears to control observed TCE degradation kinetics.