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101.
Transformation of 1,1,2,2-tetrachloroethane (1,1,2,2-TeCA) by Fe(II) in 10% cement slurries was characterized using a batch reactor system. 1,1,2,2-TeCA was completely converted to trichloroethylene (TCE) within 1h in all experiments, even in controls with cement that did not include Fe(II). Therefore, complete degradation of 1,1,2,2-TeCA depends on the behavior of TCE. The half-life of TCE was observed to be 15d when concentrations of Fe(II) and 1,1,2,2-TeCA were 98mM and 0.245mM, respectively. The kinetics of TCE removal was observed to be dependent on Fe(II) dose, pH and initial substrate concentration. Pseudo-first-order rate constants linearly increased with Fe(II) dose up to 198mM when initial target concentration was 0.245mM. Pseudo-first-order kinetics generally described the degradation reactions of TCE at a specific initial concentration, but a modified Langmuir-Hinshelwood model was necessary to describe the degradation kinetics of TCE over a wide range of initial concentrations. A surface reaction of TCE on active solids, which were formed from Fe(II) and products of cement hydration appears to control observed TCE degradation kinetics. 相似文献
102.
Bill S. Hansson Markus Knaden Silke Sachse Marcus C. Stensmyr Dieter Wicher 《Chemoecology》2010,20(2):51-61
Drosophila melanogaster is today one of the three foremost models in olfactory research, paralleled only by the mouse and
the nematode. In the last years, immense progress has been achieved by combining neurogenetic tools with neurophysiology,
anatomy, chemistry, and behavioral assays. One of the most important tasks for a fruit fly is to find a substrate for eating
and laying eggs. To perform this task the fly is dependent on olfactory cues emitted by suitable substrates as e.g. decaying
fruit. In addition, in this area, considerable progress has been made during the last years, and more and more natural and
behaviorally active ligands have been identified. The future challenge is to tie the progress in different fields together
to give us a better understanding of how a fly really behaves. Not in a test tube, but in nature. Here, we review our present
state of knowledge regarding Drosophila plant-odor-related olfactory neuroethology to provide a basis for new progress. 相似文献
103.
Abiotic reductive dechlorination of chlorinated ethylenes by soil in anaerobic environments was characterized to improve knowledge of the behavior of chlorinated ethylenes in natural systems, including systems modified to promote attenuation of contaminants. Target organics in the soil suspension reached sorption equilibrium in 2 days and the sorption isotherm of target organics was properly described by the linear sorption model. A modified Langmuir-Hinshelwood model was developed to describe the kinetics of reductive dechlorination of target organics by soil. The rate constants for the reductive dechlorination of chlorinated ethylenes at the reactive surfaces of reduced soils were found in the range between 0.055 (+/- 8.9%) and 2.60 (+/- 3.2%) day(-1). The main transformation products in reduced soil suspensions were C2 hydrocarbons. No chlorinated intermediates were observed at concentrations above detection limits. Five cycles of reduction of the soil followed by oxidation of the soil with trichloroethylene (TCE) did not affect the removal of TCE. The removal was affected by the reductants used and increased in the order: Fe(II) < dithionite < Fe(II) + dithionite. 相似文献
104.
Physicochemical soil parameters affecting sequestration and mycobacterial biodegradation of polycyclic aromatic hydrocarbons in soil 总被引:14,自引:0,他引:14
Six soils, obtained from grasslands and wooded areas in Northeastern Illinois, were physicochemically characterized. Measured parameters included total organic carbon (TOC) content, contents of humic acid, fulvic acid and humin, pore volume and pore size distribution, and chemical makeup of soil organic matter (determined using solid-state 13C-NMR). Moistened, gamma-sterilized soils were spiked with 200 ppm of either phenanthrene or pyrene (including 14C label); following 0, 40, or 120 days of aging, the contaminant-spiked soils were then inoculated with Mycobacterium austroafricanum strain GTI-23, and evolution of 14CO2 was assessed over a 28-day period. Results for both phenanthrene and pyrene indicated that increased contact time led to increased sequestration and reduced biodegradation, and that TOC content was the most important parameter governing these processes. One soil, although only tested with phenanthrene, showed significantly lower-than-expected sequestration (higher-than-expected mineralization) after 40 days of aging, despite a very high TOC value (>24%). Because the level of sequestration in this soil was proportional to the others after 120 days of aging, this implies some difference in the temporal progression of sequestration in this soil, although not in its final result. The primary distinguishing feature of this soil was its considerably elevated fulvic acid content. Further experiments showed that addition of exogenous fulvic acid to a soil with very low endogenous humic acids/fulvic acids content greatly enhanced pyrene mineralization by M. austroafricanum. Extractabilities of 13 three- to six-ring coal tar PAHs in n-butanol from the six soils after 120 days of sequestration were strongly TOC-dependent; however, there was no discernible correlation between n-butanol extractability and mycobacterial PAH mineralization. 相似文献
105.
Sustainable Development: A New World Deception 总被引:1,自引:0,他引:1
Bill Willers 《Conservation biology》1994,8(4):1146-1148
106.
107.
108.
Bill Prindle 《环境质量管理》2003,12(3):107-114
109.
Laboratory analog and numerical study of groundwater flow and solute transport in a karst aquifer with conduit and matrix domains 总被引:4,自引:0,他引:4
Jonathan Faulkner Bill X. Hu Stephen Kish Fei Hua 《Journal of contaminant hydrology》2009,110(1-2):34-44
New mathematical and laboratory methods have been developed for simulating groundwater flow and solute transport in karst aquifers having conduits imbedded in a porous medium, such as limestone. The Stokes equations are used to model the flow in the conduits and the Darcy equation is used for the flow in the matrix. The Beavers–Joseph interface boundary conditions are adopted to describe the flow exchange at the interface boundary between the two domains. A laboratory analog is used to simulate the conduit and matrix domains of a karst aquifer. The conduit domain is located at the bottom of the transparent plexiglas laboratory analog and glass beads occupy the remaining space to represent the matrix domain. Water flows into and out of the two domains separately and each has its own supply and outflow reservoirs. Water and solute are exchanged through an interface between the two domains. Pressure transducers located within the matrix and conduit domains of the analog provide data that is processed and stored in digital format. Dye tracing experiments are recorded using time-lapse imaging. The data and images produced are analyzed by a spatial analysis program. The experiments provide not only hydraulic head distribution but also capture solute front images and mass exchange measurements between the conduit and matrix domains. In the experiment, we measure and record pressures, and quantify flow rates and solute transport. The results present a plausible argument that laboratory analogs can characterize groundwater water flow, solute transport, and mass exchange between the conduit and matrix domains in a karst aquifer. The analog validates the predictions of a numerical model and demonstrates the need of laboratory analogs to provide verification of proposed theories and the calibration of mathematical models. 相似文献
110.
William Bill L. Mostia 《Journal of Loss Prevention in the Process Industries》2009,22(6):778-782
Process safety can be viewed as part of a triad that supports safety in a petrochemical facility. The other two parts are OSHA-type people safety (slips, falls, etc.) and industrial hygiene. The paper will look at process safety from a top down, plant centric view. Process safety can be distilled down to the basic concept of risk reduction. If we reduce risk, our facility will be safer. The obvious problem is that we have potential risks everywhere so how are we going to reduce all these risks to an acceptable level. Clearly we need a strategy or to use a less fancy word – a plan.Too many times it is easy to concentrate on certain aspects such as safety instrumented systems (SIS), layer of protection analysis (LOPA), behavioral safety, prevention, etc. and lose track of the whole picture of what risk reduction entails in a plant.This paper will look at risk reduction in a facility from a plant viewpoint and will cover the details and concepts of risk reduction across a wide spectrum of plant functionalities – safety climate and culture, process safety management, mechanical integrity and risk, layers of protection in risk reduction, loss of containment/hazard relationship, the risk reduction bow-tie diagram, developing a risk reduction strategy, risk reduction strategy elements, and sustainability.It will also discuss some key concepts in dealing with risk reduction in general. 相似文献