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901.
Langston WJ O'Hara S Pope ND Davey M Shortridge E Imamura M Harino H Kim A Vane CH 《Environmental monitoring and assessment》2012,184(1):289-311
Biomonitoring of contaminants (metals, organotins, polyaromatic hydrocarbons (PAHs), PCBs) was undertaken in Milford Haven
Waterway (MHW) and a reference site in the Tywi Estuary (St Ishmael/Ferryside) during 2007–2008. Bioindicator species encompassed
various uptake routes—Fucus vesiculosus (dissolved contaminants); Littorina littorea (grazer); Mytilus edulis and Cerastoderma edule (suspension feeders); and Hediste (=Nereis) diversicolor (sediments). Differences in feeding and habitat preference have subtle implications for bioaccumulation trends though, with
few exceptions, contaminant burdens in MHW were higher than the Tywi reference site, reflecting inputs. Elevated metal concentrations
were observed at some MHW sites, whilst As and Se (molluscs and seaweed) were consistently at the higher end of the UK range.
However, for most metals, distributions in MH biota were not exceptional. Several metal-species combinations indicated increases
in bioavailability upstream, which may reflect the influence of geogenic/land-based sources—perhaps enhanced by lower salinity.
TBT levels in MH mussels were below OSPAR toxicity thresholds and in the Tywi were close to zero. Phenyltins were not accumulated
appreciably in M. edulis, whereas some H. diversicolor populations appear subjected to localized (historical) sources. PAHs in H. diversicolor were distributed evenly across most of MHW, although acenaphthene, fluoranthene, pyrene, benzo(a)anthracene and chrysene were highest at one site near the mouth; naphthalenes in H. diversicolor were enriched in the mid-upper Haven (a pattern seen in M. edulis for most PAHs). Whilst PAH (and PCB) concentrations in MH mussels were mostly above reference and OSPAR backgrounds, they
are unlikely to exceed ecotoxicological thresholds. Bivalve Condition indices (CI) were highest at the Tywi reference site
and at the seaward end of MH, decreasing upstream—giving rise to several significant (negative) relationships between CI and
body burdens. Despite the possible influence of salinity gradient as a complicating factor, multivariate analysis indicated
that a combination of contaminants could influence the pattern in condition (and the biomarkers metallothionein and TOSC).
Integrating bioaccumulation data with biological and biochemical endpoints is seen as a useful way to discriminate environmental
quality of moderately contaminated areas such as MHW and to prioritise cause and effect investigations. 相似文献
902.
Chlorinated paraffins (CPs) are straight chain hydrocarbons that are produced as complex mixtures and are used as flame retardants
and paint additives. These mixtures are extremely difficult to characterize using conventional chromatographic methods, as
conventional gas chromatography results in unresolved complex chromatograms that preclude the identification and quantification
of individual congeners or any reasonable assessment of the average carbon chain length. Carbon chain length is an important
parameter for assessing physical properties and the toxicity of these materials. We have modified and improved a previously
published gas chromatography–flame ionization detector method that uses Pd catalyst held in the gas chromatograph injector
to simultaneously dechlorinate the CPs and separate the resulting alkanes. In addition, we have adapted this method to gas
chromatography–mass spectrometry. Dehalogenation of other compounds was also studied with this system to investigate potential
application to other complex halogenated mixtures. 相似文献
903.
Sarath K. Guttikunda Ramani V. Kopakka Prasad Dasari Alan W. Gertler 《Environmental monitoring and assessment》2013,185(7):5585-5593
Air quality in Hyderabad, India, often exceeds the national ambient air quality standards, especially for particulate matter (PM), which, in 2010, averaged 82.2?±?24.6, 96.2?±?12.1, and 64.3?±?21.2 μg/m3 of PM10, at commercial, industrial, and residential monitoring stations, respectively, exceeding the national ambient standard of 60 μg/m3. In 2005, following an ordinance passed by the Supreme Court of India, a source apportionment study was conducted to quantify source contributions to PM pollution in Hyderabad, using the chemical mass balance (version 8.2) receptor model for 180 ambient samples collected at three stations for PM10 and PM2.5 size fractions for three seasons. The receptor modeling results indicated that the PM10 pollution is dominated by the direct vehicular exhaust and road dust (more than 60 %). PM2.5 with higher propensity to enter the human respiratory tracks, has mixed sources of vehicle exhaust, industrial coal combustion, garbage burning, and secondary PM. In order to improve the air quality in the city, these findings demonstrate the need to control emissions from all known sources and particularly focus on the low-hanging fruits like road dust and waste burning, while the technological and institutional advancements in the transport and industrial sectors are bound to enhance efficiencies. Andhra Pradesh Pollution Control Board utilized these results to prepare an air pollution control action plan for the city. 相似文献
904.
905.
906.
907.
908.
Vibrio species isolated from four different sampling stations in the west coast of Peninsular Malaysia were screened for their antimicrobial resistance and plasmid profiles. A total of 138 isolates belonging to 15 different species were identified. Vibrio campbellii, V. parahaemolyticus, V. harveyi, and V. tubiashii were found to predominance species at all stations. High incidence of erythromycin, ampicillin, and mecillinam resistance was observed among the Vibrio isolates. In contrast, resistance against aztreonam, cefepime, streptomycin, sulfamethoxazole, and sulfonamides was low. All the Vibrio isolates in this study were found to be susceptible to imipenem, norfloxacin, ofloxacin, chloramphenicol, trimethoprim/sulfamethoxazole, and oxytetracycline. Ninety-five percent of the Vibrio isolates were resistant to one or more different classes of antibiotic, and 20 different resistance antibiograms were identified. Thirty-two distinct plasmid profiles with molecular weight ranging from 2.2 to 24.8 kb were detected among the resistance isolates. This study showed that multidrug-resistant Vibrio spp. were common in the aquatic environments of west coast of Peninsular Malaysia. 相似文献
909.
910.
H. W. Zhang Y. Q. Sun Y. Li X. D. Zhou X. Z. Tang P. Yi A. Murad S. Hussein D. Alshamsi A. Aldahan Z. B. Yu X. G. Chen V. d. P. MUGWANEZA 《Environmental monitoring and assessment》2017,189(8):411
Assessment of groundwater quality plays a significant role in the utilization of the scarce water resources globally and especially in arid regions. The increasing abstraction together with man-made contamination and seawater intrusion have strongly affected groundwater quality in the Arabia Peninsula, exemplified by the investigation given here from the United Arab Emirates, where the groundwater is seldom reviewed and assessed. In the aim of assessing current groundwater quality, we here present a comparison of chemical data linked to aquifers types. The results reveal that most of the investigated groundwater is not suitable for drinking, household, and agricultural purposes following the WHO permissible limits. Aquifer composition and climate have vital control on the water quality, with the carbonate aquifers contain the least potable water compared to the ophiolites and Quaternary clastics. Seawater intrusion along coastal regions has deteriorated the water quality and the phenomenon may become more intensive with future warming climate and rising sea level. 相似文献