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281.
错流式生物滴滤床净化甲苯废气 总被引:2,自引:0,他引:2
采用焦化厂污泥为菌源驯化甲苯降解菌,接种错流式生物滴滤床,净化含甲苯废气。研究了生物滴滤床的挂膜启动和长期运行情况,填料和营养液对滴滤床去除能力的影响,并对长期运行的压降进行了观察分析。反应器挂膜启动需要6 d时间,稳定运行的平均去除效率为95%,单位体积最大去除负荷为251 g/(m3·h)。结果表明,采用错流式生物滴滤床可以有效去除甲苯废气;以比表面积大的生物陶粒作为填料以及定期适量更换营养液,均有助于提高生物滴滤床的去除能力;错流式生物滴滤床具有压降小、气液分布均匀的特点。 相似文献
282.
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285.
Zhang B Hong M Zhang B Zhang XL Zhao YS 《Environmental monitoring and assessment》2007,133(1-3):379-386
Endemic fluorosis was investigated and studied in the west region of the Songnen plain, Northeast China in 2001–2002. The
results showed that the fluorine distribution in aquatic environment was that the fluorine concentrations in the lake water
and unconfined ground water were higher than that in the river water and confined ground water. The lake water (Alkali lake)
is connected with unconfined ground water. In unconfined ground water, from the east and southeast areas to the west and the
northwest areas of the plain, fluorine concentration fluctuated with high and low alternatively. The fluorine in the water
comes from the weathering of rocks and minerals in the mountains and hills around the Songnen Plain. The main influence factors
of the fluorine distribution in aquatic environment are discussed. Unconfined ground water containing high fluorine is used
as drinking water. In this region, the fluorine concentration in drinking water is evidently correlated to the morbidity of
dental and skeletal fluorosis. High fluorine concentration in drinking water has endangered human health. 相似文献
286.
Zhalong National Nature Reserve in the northeast of China is a large wetland and a habitat of hundreds species of fauna and
flora. The rare red-crowned crane is one kind of endangered birds in it. Recently, Zhalong wetland is shrinking and it encounters
many problems including occasional fires, bad water quality, human activities, etc. In order to find out a proper way to protect
and restore the wetland, this study, using a geographic information system, the global positioning system and remote sensing
techniques, analyses the spatial characteristics of the changes in marsh landscape pattern and examines the driving factors
for these changes. Data sources include 8 Landsat Thematic Mapper satellite images of Zhalong area in the period of 1986–2002
and the investigation information on site. Based on the analysis of changes of marsh area and annual precipitation during
the 16 years, it is found that there is a close correlation between annual precipitation and marsh area. It means that climate
is one of driving factors of marsh pattern changes. To understand influences of other kinds of land uses on marsh spatial
distribution in Zhalong wetland, this paper analyses the relationship between marsh and different kinds of land uses, such
as water surface, residential area, farmland, salina land and grass land, respectively. According to the patch analysis theory,
a fragmental index and a fractal dimension of the marsh are calculated with perimeter-area method. The results indicate that
the marsh pattern is affected by human activities significantly. In addition, the location alteration of marsh centroid point
over the 16 years is studied. The movement trace of marsh centroid point is concerned with different hydrological situation
in different areas of the wetland. In summary the characteristics of the marsh landscape pattern evolution during the 16 years
are affected by multiple driving factors. The main driving factors are climate, human activities, distribution of other kinds
of land uses and hydrological situation in different areas. 相似文献
287.
This aqueous reaction between ozone and two alkylphenols (APs), namely octylphenol (OP) and nonylphenol (NP), has been investigated. Both compounds are important endocrine disrupting chemicals, which arise from the biodegradation of alkylphenol ethoxylates and are often found at relatively high concentrations in wastewater effluents. In this paper the results of an experimental study are presented which provide values for the reaction rate constants between molecular ozone and undissociated OP and NP, and overall reaction rate constants for the degradation of the two APs at pH values in the range of 7-9. The kinetic rate constants for OP and NP degradation by molecular ozone were 4.33(+/-0.18) x 10(4) and 3.90(+/-0.10) x 10(4) M(-1) s(-1), and the reaction stoichiometry was similar in both cases and equal to approximately 1.3:1 ([O3]:[AP]). The overall second order reaction rate constants for the two APs increased significantly with increasing pH, which is believed to be mainly due to the increasing influence of indirect radical reaction with increasing pH; this aspect is considered in more detail in a companion paper. A preliminary investigation of the reaction mechanism suggests that an initial product of ozonation is hydroxyl-alkyl phenol. 相似文献
288.
Effects of potassium alkalis and sodium alkalis on the dechlorination of o-chlorophenol in supercritical water 总被引:1,自引:0,他引:1
Effects of potassium alkalis and sodium alkalis on the dechlorination of o-chlorophenol (o-CP) in supercritical water (SCW) were studied in this paper under the conditions of 450 degrees C and 25 MPa. Experimental results indicated that the dechlorination of o-CP can be accelerated significantly by all alkalis investigated. The dechlorination of o-CP proceeded mainly via two pathways: hydrodechlorination and hydrolysis. Both of the two pathways can be promoted by alkalis, and the dechlorination of o-CP can be accelerated by both the cations and hydroxide ion dissociated from alkalis. The overall dechlorination of o-CP can be accelerated by cations via promoting the hydrodechlorination pathway, while, hydroxide ion via promoting the hydrolysis pathway. In addition, the hydrodechlorination can be accelerated faster by sodium alkalis than that by potassium ones, while, the hydrolysis can be promoted faster by potassium alkalis. This difference may be caused by the different charge density between potassium ion and sodium ion, and the different solubility and dissociation constant between potassium alkalis and sodium alkalis in SCW. Dechlorination of o-CP with addition of alkalis prior to supercritical water oxidation (SCWO) process not only can avoid the reactor corrosion caused by the generated hydrochloric acid in direct SCWO of o-CP, but also can reduce the formation of toxic chlorinated byproducts compared with direct SCWO process or SCWO of o-CP with addition of alkali. 相似文献
289.
290.
铅锌尾矿废弃地的化学性质研究 总被引:2,自引:0,他引:2
凡口铅锌尾矿废弃地的不同区位及不同深度的尾矿中铅锌含量存在着较大的差异 ,总锌为 70 3~ 19657mg/ kg、总铅 10 4 13~ 94 988mg/ kg。正常尾矿中 ,有效态锌含量达到 151.6~ 84 1.7mg/ kg,有效态铅含量很低 ( 0 .75~ 2 .50 mg/ kg) ,有机质、总氮、有效磷及速效钾等营养物质缺乏。当尾矿酸化后 ,p H降低 ,有效态 Pb、Zn含量升高 ,有效锌达到 175.8~ 2 82 8.0 mg/ kg,有效铅含量最高为 10 0 .0 mg/kg,而有机质、总氮和有效磷为零 ,使尾矿更加贫瘠。在尾矿库的边缘区位和尾矿表面的覆盖土壤区位 ,基质中营养物质含量增加 ,但是营养状况的改善又引起了有效态的 Pb、Zn含量升高。 相似文献