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571.
This article draws on three separate research and monitoring studies to describe 20-year trends in the number and condition of campsites in the backcountry of Grand Canyon National Park. Results are used to assess the effectiveness of a complex and innovative management program, adopted in 1983, that sought to concentrate use on designated campsites in popular places and disperse camping in more remote places. In 1984, conditions on 12 high-use campsites and 12 low-use campsites were carefully assessed. Conditions on 22 of these campsites were reassessed in 2005. In addition, campsite-monitoring surveys were conducted between 1985 and 1992 and again in 2003 and 2004. In these surveys, all campsites were located and their condition rapidly assessed. The detailed assessment of a sample of sites suggests relatively little change in condition during the 20-year period. The high-use sites were more highly disturbed than the low-use sites, but they did not change more during the study period. In contrast, changes at larger scales were dramatic. The total number of campsites more than doubled during the study period. Surprisingly, the proliferation of new campsites was greater in places where camping was only allowed on designated campsites than in places where camping was allowed anywhere. Concern that concentration of use on designated sites would cause unacceptable impact was unfounded. Management implications for other internationally significant protected areas that allow backcountry camping are explored.  相似文献   
572.
Regional Environmental Change - The published online version contains mistake. Anna Maria Jönsson was inadvertently omitted in the author group section. Correct author group section is shown...  相似文献   
573.
One of the biggest environmental concerns caused by coal-fired power plants is the emission of mercury (Hg), which is toxic metal. To control the emission of Hg from coal-derived flue gas, it is important to understand the behavior and speciation of Hg as well as the interaction between Hg and solid materials in the flue gas stream. In this study, atomic-scale theoretical investigations using density functional theory (DFT) were carried out in conjunction with laboratory-scale experimental studies to investigate the adsorption behavior of Hg on hematite (α-Fe2O3). According to the DFT simulation, the adsorption energy calculation proposes that Hg physisorbs to the α-Fe2O3(0001) surface with an adsorption energy of ?0.278 eV, and the subsequent Bader charge analysis confirms that Hg is slightly oxidized. In addition, Cl introduced to the Hg-adsorbed surface strengthens the Hg stability on the α-Fe2O3(0001) surface, as evidenced by a shortened Hg-surface equilibrium distance. The projected density of states (PDOS) analysis also suggests that Cl enhances the chemical bonding between the surface and the adsorbate, thereby increasing the adsorption strength. In summary, α-Fe2O3 has the ability to adsorb and oxidize Hg, and this reactivity is enhanced in the presence of Cl. For the laboratory-scale experiments, three types of α-Fe2O3 nanoparticles were prepared using the precursors Fe(NO3)3, Fe(ClO4)3, and FeCl3, respectively. The particle shapes varied from diamond to irregular stepped and subrounded, and particle size ranged from 20 to 500 nm depending on the precursor used. The nanoparticles had the highest surface area (84.5 m2/g) due to their highly stepped surface morphology. Packed-bed reactor Hg exposure experiments resulted in this nanoparticles adsorbing more than 300 μg Hg/g. The Hg LIII-edge extended X-ray absorption fine structure spectroscopy also indicated that HgCl2 physisorbed onto the α-Fe2O3 nanoparticles.

Implications: Atomic-scale theoretical simulations proposes that Hg physisorbs to the α-Fe2O3(0001) surface with an adsorption energy of ?0.278 eV, and the subsequent Bader charge analysis confirms that Hg is slightly oxidized. In addition, Cl introduced to the Hg-adsorbed surface strengthens the Hg stability on the α-Fe2O3(0001) surface, as evidenced by a shortened Hg-surface equilibrium distance. The PDOS analysis also suggests that Cl enhances the chemical bonding between the surface and the adsorbate, thereby increasing the adsorption strength. Following laboratory-scale experiment of Hg sorption also shows that HgCl2 physisorbs onto α-Fe2O3 nanoparticles which have highly stepped structure.  相似文献   
574.
Parks and protected areas are a global ecological, social and health resource visited by over 8 billion people annually. Their use can yield substantial benefits, but only if a balance between ecological integrity and sustainable visitation is struck. This research explores the potential influence of climate-driven environmental change on visitation to North America's most popular glacier, the Athabasca Glacier in Jasper National Park, Canada. Photorealistic environmental visualizations were used to gauge visitors’ perceptions of environmental change and potential impacts on consumer behaviour. Results suggest that impacts could substantially diminish the site's pull as a tourism destination. Rather than improving visitation prospects, expert-proposed adaptations underestimated the importance of perceived naturalness and contributed to further potential decline. Findings are relevant to protected areas planning and management. They suggest that a natural path to climate change adaptation is the best way to support both ecological integrity and the long-term tourism pull of protected areas.  相似文献   
575.
Urban stormwater run-off is a threat to stream ecosystems. New approaches to stormwater management aim to protect urban streams from such impacts, by retaining, treating and using stormwater at its source. As up to ~50% of runoff from urban surfaces comes from private property, fostering stormwater retention requires effective householder engagement. We evaluated householder participation in the Little Stringybark Creek project, a stormwater retrofit programme aimed at waterway protection, using qualitative enquiry through formal and informal interviews to identify factors that influenced participation. Participation was governed by multiple factors, with financial incentives and personal co-benefits of tanks primary motivators, while process complexity and distrust were primary barriers. Results suggest an approach combining education to encourage review of subjective norms and attitudes, with incentives to mitigate behavioural controls can transform public behaviour towards sustainable stormwater management.  相似文献   
576.
Riparian zones in semi‐arid, mountainous regions provide a disproportionate amount of the available wildlife habitat and ecosystem services. Despite their importance, there is little guidance on the best way to map riparian zones for broad spatial extents (e.g., large watersheds) when detailed maps from field data or high‐resolution imagery and terrain data are not available. Using well‐established accuracy metrics (e.g., kappa, precision, computational complexity), we evaluated eight methods commonly used to map riparian zones. Focusing on a semi‐arid, mountainous watershed, we found that the most accurate and robust method for mapping riparian zones combines data on upstream drainage area and valley topography. That method performed best regardless of stream order, and was most effective when implemented with fine resolution topographic and stream line data. Other commonly used methods to model riparian zones, such as those based on fixed‐width buffers, yielded inaccurate results. We recommend that until very‐high resolution (<1 m) elevation data are available at broad extents, models of riparian zones for semi‐arid mountainous regions should incorporate drainage area, valley topography, and quantify uncertainty.  相似文献   
577.
The effort to transition energy sources away from dependence on fossil fuels has become highly divided along partisan lines in some countries, but the social-science literature has not yet caught up with this important problem. Policy-adoption studies do not address the specific problem of polarization and gridlock, and the literature on gridlock does not examine conditions for breaking gridlock for renewable energy and energy efficiency (REEE) policy. Qualitative research can help to fill the void by identifying strategies that legislators use for achieving support for REEE policy where there is gridlock, polarization, and/or strong opposition. Interview data from a stratified sample of US states reveals three strategies that state-government legislators use to enhance REEE policy development under these conditions: bring to the process countervailing industrial interests to align REEE with business; transfer decision making to public service commissions; and use extra-legislative consultation processes to develop stakeholder consensus.  相似文献   
578.
Extent of pyrolysis impacts on fast pyrolysis biochar properties   总被引:2,自引:0,他引:2  
A potential concern about the use of fast pyrolysis rather than slow pyrolysis biochars as soil amendments is that they may contain high levels of bioavailable C due to short particle residence times in the reactors, which could reduce the stability of biochar C and cause nutrient immobilization in soils. To investigate this concern, three corn ( L.) stover fast pyrolysis biochars prepared using different reactor conditions were chemically and physically characterized to determine their extent of pyrolysis. These biochars were also incubated in soil to assess their impact on soil CO emissions, nutrient availability, microorganism population growth, and water retention capacity. Elemental analysis and quantitative solid-state C nuclear magnetic resonance spectroscopy showed variation in O functional groups (associated primarily with carbohydrates) and aromatic C, which could be used to define extent of pyrolysis. A 24-wk incubation performed using a sandy soil amended with 0.5 wt% of corn stover biochar showed a small but significant decrease in soil CO emissions and a decrease in the bacteria:fungi ratios with extent of pyrolysis. Relative to the control soil, biochar-amended soils had small increases in CO emissions and extractable nutrients, but similar microorganism populations, extractable NO levels, and water retention capacities. Corn stover amendments, by contrast, significantly increased soil CO emissions and microbial populations, and reduced extractable NO. These results indicate that C in fast pyrolysis biochar is stable in soil environments and will not appreciably contribute to nutrient immobilization.  相似文献   
579.
This paper focuses on policy change under scientific uncertainty. This is done by exploring two case studies of Canadian pesticide policy evolution applied to Sabatier's ‘Advocacy Coalition Framework’. ‘Stakeholder’ and ‘narrative policy’ analyses are emphasised to understand pesticide policy changes in Calgary (public education without a restrictive by-law) and Halifax (restrictive by-law). The parallel case studies consist of qualitative interviews with members of pesticide policy advisory committees in each city and a content analysis of local newspaper articles. Key resources mobilised by coalitions to achieve their policy goals include skillful leadership, and the use by those leaders of the media to disseminate coalition narratives. Further, the context of policy change contributed to the scenarios whereby pro-by-law grassroots activists were particularly successful in Halifax and anti-by-law city employees were most influential in Calgary.  相似文献   
580.
Environmental Flows (EFlows) are defined as the quantity, timing and quality of the flow of water, sediment and biota necessary to sustain freshwater and estuarine ecosystems, and the human livelihoods and well-being that depend on these ecosystems. As such they are a vital component of Integrated Water Resource Management (IWRM). A recent survey found that, in general, Africa lags behind schedule with respect to the global SDG Target 6.5 to implement IWRM at all levels, including through transboundary cooperation as appropriate. This web-based review explores progress made in EFlows Assessments and implementing their outcomes in southern Africa. It outlines the apparent impetus to the uptake of EFlows provided by legislation, common funding mechanisms for EFlows assessment and evolving trends in EFlows assessment. It also highlights instances of implementation of EFlows in both in-country and transboundary settings.  相似文献   
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