There are concerns that microplastics act as a vector of pharmaceuticals in the aquatic environment. Most studies have focussed on pharmaceutical adsorption and have not investigated desorption in the various matrices that microplastics enter. Therefore we studied the desorption of the antidepressant drug fluoxetine from polyethylene terephthalate (PET) microplastics in river water, sea water, and simulated gastric and intestinal fluids. We found that most desorption occurred rapidly, within a few hours of exposure. Fluoxetine desorption fitted well to the Freundlich isotherm with r2 values ranging from 0.97 to 0.99. Desorption decreased in the following order: gastric fluid at 20 °C and 37 °C; sea water at 20 °C; intestinal fluid at 20 °C and 37 °C; then river water at 20 °C. The little difference in desorption in gastrointestinal fluids at 20 °C and 37 °C suggests a similar exposure risk to cold- and warm-blooded organisms following PET microplastic ingestion. Total desorption following sequential incubation 2 h in gastric fluid then 4 h in intestinal fluid to mimic gastrointestinal digestion was 37% at 20 °C and 41% at 37 °C. Interestingly, higher desorption of 18–23% occurred in sea water compared to river water, of 4–11%. Under a worst-case scenario, more than 44 mg kg−1 body weight d−1 or more than 52 mg kg−1 body weight d−1 of PET microplastics from river water or sea water, respectively, need to be consumed to exceed the mammalian acceptable daily intake for fluoxetine. Further studies are needed on microplastic ingestion and the bioavailability of adsorbed pharmaceuticals to a range of exposed aquatic organisms.
A series of experiments is presented that model the generation of internal gravity waves in the ocean by the forcing of turbulent eddies in the surface mixed layer.The experimental setup consists of a shallow mixed upper layer and a deep continuously stratified lower layer. A source of turbulence is dragged through the upper layer. Internal waves can freely propagate in the lower layer. The internal waves are measured using synthetic schlieren to determine the frequencies of the generated waves. Consistent with other studies, it is found that the characteristic frequencies of internal waves generated by turbulence are an approximate constant fraction of the buoyancy frequency. 相似文献
Free-ranging cervids acquire most of their essential minerals through forage consumption, though occasionally seek other sources to account for seasonal mineral deficiencies. Mineral sources occur as natural geological deposits (i.e., licks) or as anthropogenic mineral supplements. In both scenarios, these sources commonly serve as focal sites for visitation. We monitored 11 licks in Rocky Mountain National Park, north-central Colorado, using trail cameras to quantify daily visitation indices (DVI) and soil consumption indices (SCI) for Rocky Mountain elk (Cervus elaphus) and mule deer (Odocoileus hemionus) during summer 2006 and documented elk, mule deer, and moose (Alces alces) visiting licks. Additionally, soil samples were collected, and mineral concentrations were compared to discern levels that explain rates of visitation. Relationships between response variables; DVI and SCI, and explanatory variables; elevation class, moisture class, period of study, and concentrations of minerals were examined. We found that DVI and SCI were greatest at two wet, low-elevation licks exhibiting relatively high concentrations of manganese and sodium. Because cervids are known to seek Na from soils, we suggest our observed association of Mn with DVI and SCI was a likely consequence of deer and elk seeking supplemental dietary Na. Additionally, highly utilized licks such as these provide an area of concentrated cervid occupation and interaction, thus increasing risk for environmental transmission of infectious pathogens such as chronic wasting disease, which has been shown to be shed in the saliva, urine, and feces of infected cervids. 相似文献
We describe the use of bivariate stochastic differential equations (SDE) for modeling movements of 216 radio‐collared female Rocky Mountain elk at the Starkey Experimental Forest and Range in northeastern Oregon. Spatially and temporally explicit vector fields were estimated using approximating difference equations and nonparametric regression techniques. Estimated vector fields of movement were mapped onto the project area at selected times of the day to examine spatial patterns of movement in relation to topography. Using the concept of a potential function, we were able to study the influence of roads and grassland foraging areas on elk movements. Doing so we identified broad spatial patterns of elk movements and showed the time dependent effects of habitat features within the habitat mosaic at Starkey. Our analyses quantify the cycles of movements in spring and summer in terms of attraction or repulsion to specific habitat features, and illustrate the magnitude, timing and direction of these movements. An extensive list of references is included. Published in 2004 by John Wiley & Sons, Ltd. 相似文献
Understanding within-stand variation in diversity of epiphytes will provide an improved basis for producing timber while conserving biological diversity. Two 80-ha, 50–year–old managed stands of conifers were surveyed to locate 0.4 ha putative "diversity" plots, the areas appearing most diverse in lichen epiphytes. These plots were generally located in areas made heterogeneous by canopy gaps, wolf trees (trees with large-diameter lower branches), and old-growth remnant trees. "Matrix" plots, in contrast, were chosen at random from the remaining, more homogenous forest. Diversity plots hosted from 25% to 40% more epiphytic lichen species than matrix plots in both stands. The strongest within-stand gradients in species composition were correlated with percentage of plot occupied by gaps and wolf trees. Percentage of the plot in gaps was correlated with species richness (r = 0.79). In the more structurally diverse stand, diversity and abundance of nitrogen-fixing "cyanolichens" were correlated with percentage of the plot occupied by gaps (0.5 < r < 0.9), and alectorioid lichens were correlated with percentage of the plot occupied by old-growth remnant trees (0.5 < r < 0.6). In the stand with more homogenous structure, percentage of the plot under gaps was correlated with regionally common species that were otherwise absent or sparse in the matrix. Protecting gaps, hardwoods, wolf trees, and old-growth remnant trees during thinning or other partial cutting is likely to promote the majority of epiphytic macrolichens in young conifer forests. Because these features are easily recognized on aerial photos and on the ground by land managers, it is practical to manage for forest structures that would promote lichen diversity. 相似文献
Summary Data from a natural population of California gulls (Larus californicus) demonstrated that increasing reproductive effort with age was associated with reduced survivorship. Number of offspring fledged but not clutch size was inversely related to adult survivorhip indicating that reproductively induced mortality resulted from the cumulative effects of the entire breeding season. Agerelated increases in fledging success were correlated with increased adult mortality. Young gulls fledged few offspring and had high survival rates. Old gulls tended to fledge more offspring and had low survival rates. However, those old gulls fledging few offspring survived as well as young gulls. Data also invalidate the assumption that survivorship is age-constant in this species. 相似文献
• 5R (Recover, Reduce, Recycle, Resource and Reuse) approaches to manage urban water.• 5R harvests storm water, gray water and black water in several forms.• 5R offers promise for moving solutions for urban water scarcity in practice. Demand for water is expanding with increases in population, particularly in urban areas in developing countries. Additionally, urban water system needs a novel perspective for upgradation with urbanization. This perspective presents a novel 5R approach for managing urban water resources: Recover (storm water), Reduce (toilet flushing water), Recycle (gray water), Resource (black water), and Reuse (advanced-treated wastewater). The 5R generation incorporates the latest ideas for harvesting storm water, gray water, and black water in its several forms. This paper has briefly demonstrated each R of 5R generation for water treatment and reuse. China has the chance to upgrade its urban water systems according to 5R principles. Already, a demonstration project of 5R generation has been installed in Qingdao International Horticultural Exposition, and Dalian International Convention Center (China) has applied 5R, achieving over 70% water saving. The 5R offers promise for moving solutions for urban water scarcity from “hoped for in the future” to “realistic today”. 相似文献