The past two decades have witnessed an increasing interest in the use of space-time models for a wide range of environmental
problems. The fundamental tool used to embody both the temporal and spatial components of the phenomenon in question is the
covariance model. The empirical estimation of space-time covariance models can prove highly complex if simplifying assumptions
are not employed. For this reason, many studies assume both spatiotemporal stationarity, and the separability of spatial and
temporal components. This second assumption is often unrealistic from the empirical point of view. This paper proposes the
use of a model in which non-separability arises from temporal non-stationarity. The model is used to analyze tropospheric
ozone data from the Emilia-Romagna Region of Italy. 相似文献
Nowadays, adaptation has become a key focus of the scientific and policy-making communities and is a major area of discussion in the multilateral climate change process. As climate change is projected to hit the poorest the hardest, it is especially important for developing countries to pay particular attention to the management of natural resources and agricultural activities. In most of these countries such as Cameroon, forest can play important role in achieving broader climate change adaptation goals. However, forest generally receives very little attention in national development programme and strategies such as policy dialogues on climate change and poverty reduction strategies. Using a qualitative approach to data collection through content analysis of relevant Cameroon policy documents, the integration of climate change adaptation was explored and the level of attention given to forests for adaptation analysed. Results indicate that, with the exception of the First National Communication to UNFCCC that focused mostly on mitigation and related issues, current policy documents in Cameroon are void of tangible reference to climate change, and hence failing in drawing the relevance of forest in sheltering populations from the many projected impacts of climate change. Policies related to forest rely on a generalized concept of sustainable forest management and do not identify the specific changes that need to be incorporated into management strategies and policies towards achieving adaptation. The strategies and recommendations made in those documents only serve to improve understanding of Cameroon natural resources and add resilience to the natural systems in coping with anthropogenic stresses. The paper draws attention to the need to address the constraints of lack of awareness and poor flow of information on the potentials of forests for climate change adaptation. It highlights the need for integrating forest for adaptation into national development programmes and strategies, and recommends a review of the existing environmental legislations and their implications on poverty reduction strategy and adaptation to climate change. 相似文献
Twenty-five strains of filamentous fungi, encompassing 14 different species and belonging mainly to Ascomycetes, were tested for their ability to degrade benzo[a]pyrene (BaP) in mineral liquid medium. The most performing isolates for BaP degradation (200 mg?l?1) in mineral medium were Cladosporium sphaerospermum with 29 % BaP degradation, i.e., 82.8 μg BaP degraded per day (day?1), Paecilomyces lilacinus with 20.5 % BaP degradation, i.e., 58.5 μg BaP day?1, and Verticillium insectorum with 22.3 % BaP degradation, i.e., 64.3 μg BaP day?1, after only 7 days of incubation. Four variables, e.g., biomass growth on hexadecane and glucose, BaP solubilization, activities of extracellular- and mycelium-associated peroxidase, and polyethylene glycol degradation, were also studied as selective criteria presumed to be involved in BaP degradation. Among these variables, the tests based on polyethylene glycol degradation and on fungal growth on hexadecane and glucose seemed to be the both pertinent criteria for setting apart isolates competent in BaP degradation, suggesting the occurrence of different mechanisms presumed to be involved in pollutant degradation among the studied micromycetes. 相似文献
Acid mine drainage (AMD), characterized by low pH and high concentrations of sulfate and heavy metals, is an important and widespread environmental problem related to the mining industry. Sulfate-reducing passive bioreactors have received much attention lately as promising biotechnologies for AMD treatment. They offer advantages such as high metal removal at low pH, stable sludge, very low operation costs, and minimal energy consumption. Sulfide precipitation is the desired mechanism of contaminant removal; however, many mechanisms including adsorption and precipitation of metal carbonates and hydroxides occur in passive bioreactors. The efficiency of sulfate-reducing passive bioreactors is sometimes limited because they rely on the activity of an anaerobic microflora [including sulfate-reducing bacteria (SRB)] which is controlled primarily by the reactive mixture composition. The most important mixture component is the organic carbon source. The performance of field bioreactors can also be limited by AMD load and metal toxicity. Several studies conducted to find the best mixture of natural organic substrates for SRB are reviewed. Moreover, critical parameters for design and long-term operation are discussed. Additional work needs to be done to properly assess the long-term efficiency of reactive mixtures and the metal removal mechanisms. Furthermore, metal speciation and ecotoxicological assessment of treated effluent from on-site passive bioreactors have yet to be performed. 相似文献
Summary. Surrogate leaves treated with methanolic leaf
surface extracts of Brassica napus L. (cv Express) plants
that received three different sulphur fertilisation treatments
showed even more marked differences by the oviposition
choice of Delia radicum L. than the potted plants. This
confirms that the oviposition preference of D. radicum is
mediated by chemical compounds on the leaf surface and
that the quality of host-plants in terms of their nutrition
status can be perceived by the female insect.The oviposition data were positively correlated with the
content of fractionated surface extracts containing either
CIF (cabbage identification factor; 1,2-dehydro-3-thia-
4,10,10b-triaza-cyclopenta[.a.]fluorine-1-carboxylic acid)
or glucosinolates. Electrophysiological recordings from the
tarsal chemoreceptor sensilla C5 and D3,4 showed that receptor
neurons react to glucosinolate- and CIF-fractions. We
found that the chemosensory activity of specific glucosinolate-
and CIF-receptor neurons corresponded with the
respective behavioural activity in the oviposition choice
assays. The responses of D. radicum to glucosinolates in
the electrophysiological recordings studies corresponded
to the observed oviposition preference on plants or artificial
leaves characterised with an higher amount of glucosinolates
on leave surfaces. The presented data suggested
that CIF and glucosinolates are involved in host-plant
preference of D. radicum and are perceived by tarsal
chemoreceptors. 相似文献
The objective of this study was to assess the time variation of mineral and water stress levels across the life of a declining, Mg-deficient, spruce stand, in order to clarify the factors that caused the decline. Since 1985, strong soil acidification linked to a large leaching of nitrate and base cations was measured at the study site. In 1994, 5 trees were felled and tree rings were measured and analysed for Ca, Mg, K, Sr, 13C12C and 87Sr/86Sr isotopic ratios. Strontium pools and fluxes as well as root Sr isotope ratio in relation to depth were also measured. Wood chemical concentrations and isotope ratios were strongly related to the dominance status of each tree. On average during the study period, the 87Sr/86Sr ratio of spruce wood decreased. Using a mechanistic model computing long term variations of 87Sr/86Sr ratio in trees and soils, we reproduced the observed trend by simulating soil acidification – increasing Sr drainage from the whole profile, and particularly from the organic horizon –, and root uptake becoming more superficial with time. Between 1952 and 1976, tree ring 13C decreased strongly and continuously, which, in addition to other factors, might be related to an increase in water stress. Thus, a decrease in rooting depth, possibly related to soil acidification, appeared as a possible cause for the long term increase in water stress. The extreme drought event of 1976 appears to have revealed and triggered the decline. 相似文献
Petroleum products are generally volatile hydrocarbon mixtures. These mixtures may contaminate land surfaces, the unsaturated zone and ground waters at numerous sites and thus represent a long-term source of environmental subsurface pollution. Based on laboratory and field evidence obtained by our research groups and others we emphasize in the present review paper the effect of leaching on the abiotic processes controlling the fate of volatile petroleum hydrocarbon mixtures (VPHMs) in the soil environment. The modification of petroleum hydrocarbon mixtures due to changes in the soil water content is considered the result of a “leaching phenomenon”. The experimental evidence of VPHM behavior in the porous media is linked to four major processes: retention, redistribution and attenuation in the subsurface, and dissolution in the soil water.
Once VPHMs reach the soil surface, their residual concentration and composition is influenced by the amount and quality of the leaching water. The transport and natural attenuation of the VPHMs in the unsaturated zone is affected by the amount and rate of leaching. Since VPHM are a mixture of volatile and non-volatile hydrocarbons whose components differ by several orders of magnitude in their vapor pressure and water solubility, their fates in the soil environment under leaching will be diverse too. This will influence the temporal concentrations of the VPHM components and their distributions with depth, as vapors, solutes, or water-immiscible solutions. Wetting the soil before or after the VPHMs reach it, differentially affects the abiotic processes governing petroleum products behavior into the porous media. 相似文献