234U and 238U isotopes in water and sediments of the southern Baltic

The aim of this work was to determine the concentration of 234U and 238U and calculate the values of the 234U/238U activity ratio in waters and sediments from the various regions of the southern Baltic Sea: Gdańsk Deep, S?upsk Narrow and Bornholm Deep. The concentration of uranium in analysed sediments from southern Baltic increase with core depth to what probably is connected with diffusion from sediments to water through interstitial water, where uranium concentration is much higher than in bottom water. The highest concentrations of uranium were observed in sediments of S?upsk Narrow (0.66-7.11 mg kg(-1) d.w.) and S?upsk Bank (0.61-6.93 mg kg(-1) d.w.), the lowest in sediments from Bornholm Deep (0.54-3.77 mg kg(-1) d.w.). The 234U/238U activity ratio results indicated that the sedimentation of terrigenic material and Vistula River transport are the general sources of uranium in the southern Baltic sediments. The value of 234U/238U activity ratio in sediments from reduction areas from southern Baltic (Gdańsk Deep and Bornholm Deep) indicated that reduction process of U(VI) to U(IV) and removing of anthropogenic uranium from seawater to sediments constitutes a small part only in Gdańsk Deep.     

Locking of retractable type fall arresters--test method and stand.

Retractable type fall arresters are very effective personal equipment protecting against falls from a height. These devices are used under different atmospheric conditions and in the presence of various types of industrial pollution. For this reason appropriate locking after conditioning simulating extreme conditions of a worksite is one of the essential characteristics of retractable type fall arresters. This article presents the requirements for locking of the devices. A previously used locking test method and its disadvantages are discussed. The article suggests an improved test method and test equipment. Measurement of the test mass acceleration is the most important improvement introduced into the test method. The article shows laboratory tests used to verify the method, which turned out to be a valuable source of information concerning the performance of retractable type fall arresters.     

Metals distribution and interactions in tissues of shrews (Sorex spp.) from copper- and zinc-contaminated areas in Poland

To assess the risk from heavy metal accumulation to insectivorous species exposed to different pollutants, shrews [Sorex araneus (Linnaeus 1758) and Sorex minutus (Linnaeus 1766)] were collected in the Olkuski Ore Region (OOR; a Zn and Cd smelter area), Legnicko-G?ogowski Copper Mine Region (LGCR; a copper ore-mining area), and Bia?owieza Forest (BF; a control area). A few sites were chosen in each region and a total of 57 animals were collected from them. The liver and kidneys were dissected from the animals, dried, and digested in a 4:1 mixture of HNO3 (nitric acid) and HClO4 (perchloric acid). Cadmium, lead, zinc, copper, and iron were determined in the samples by flame or flameless atomic absorption spectrometry. The interactions between toxic and essential metals were calculated for each tissue. The data showed that accumulation of metals by insectivores is high; shrews accumulated much higher amounts of cadmium and lead than bank voles, studied by other researchers, from the same areas. The expected high tissue accumulation of copper at LGCR and zinc at OOR was not seen, but the levels of both elements were higher in the tissues of shrews from OOR than from LGCR. The lowest copper concentrations were in the tissues of shrews from BF. The highest cadmium and lead concentrations were found in the tissues of shrews from OOR. Some significant correlations were found between the tissue concentrations of xenobiotic and essential metals (e.g., between cadmium and zinc and between lead and iron).     

Effects of cadmium and zinc on larval growth and survival in the ground beetle,Pterostichus oblongopunctatus

Carabid beetles, like Pterostichus oblongopunctatus, living in metal contaminated areas may be exposed to elevated levels of metals within their diets. However, when compared to other second order consumers, they have one of the lowest observed levels of metals, indicating methods of detoxification to deal with such toxicants. In this study, we investigated if chronic, multigenerational exposure to metals leads to resistance to toxic metal concentrations, and if so, what are the costs associated with them. Adult organisms were collected from two sites, a polluted and a reference site near Olkusz, in southern Poland. These adults were immediately mated, and eggs were collected twice weekly to assess the effects in the larvae of the F(1) generation. Larvae were randomly exposed to one of four artificial mediums: control, 50 mg kg(-1) Cd, 500 mg kg(-1) Zn, and a combined treatment of 50 mg kg(-1) Cd and 500 mg kg(-1) Zn to investigate possible interactions. Individuals were sacrificed at 10, 30, and 40 days. Although metals were not accumulated in larvae (p>0.05), larvae fed the Cd or the Zn treatment grew significantly slower, and had the lowest survival rate (p<0.05) in respect to control. Out of metal treated animals, those on the combined treatment of CdZn grew the quickest and had the highest observed survival (p<0.05). Although previous studies have demonstrated changes in adult population parameters under chronic, multigeneration exposure to toxic metal concentrations, our study did not reveal any changes in the larval stage.     

An assessment of the toxicity of pyridinium chlorides and their biodegradation intermediates

Toxicity investigations were conducted for four pyridinium chlorides belonging to cationic surface-active substances (CSAS), which differed from each other in the numbers of methyl groups (CH(3)) in pyridinium ring.The crustacean Daphnia magna, the fish Lebistes reticulatus and the alga Scenedesmus quadricauda were chosen as biotests. Toxicity of examined preparations appeared to be very high but did not depend on their chemical structure. S. quadricauda was the most sensitive organism. Toxicity of intermediate products obtained in biological oxidation process was also examined. Biodegradation was conducted according to the "river water test". It was found that only partial degradation took place while pyridinium chlorides constituted main energy and carbon source. Presence of biodegradation intermediate products was shown on the basis of 1H NMR analysis. Intermediates were not toxic to any biotests.     

Thermal manikin measurements--exact or not?

According to the European prestandard ENV 342:1998, the thermal insulation of cold-protective clothing is measured with a thermal manikin. Systematic studies on the reproducibility of the values, measured with different types of clothing on the commonly used standing and walking manikins, have not been reported in the literature. Over 300 measurements were done in 8 different European laboratories. The reproducibility of the thermal insulation test results was good. The coefficient of variation was lower than 8%. The measured clothing should fit the manikin precisely, because poorly fitting clothing gave an error in the results. The correlation between parallel and serial insulation values was excellent and parallel values were about 20% lower than serial ones. The influence of ambient conditions was critical only in the case of air velocity. The reproducibility of thermal insulation test results in a single laboratory was good, and the variation was lower than 3%.     

A vibroacoustic model of selected human larynx diseases.

With the present development of digital registration and methods for processing speech it is possible to make effective objective acoustic diagnostics for medical purposes. These methods are useful as all pathologies and diseases of the human vocal tract influence the quality of a patient's speech signal. Diagnostics of the voice organ can be defined as an unambiguous recognition of the current condition of a specific voice source. Such recognition is based on an evaluation of essential acoustic parameters of the speech signal. This requires creating a vibroacoustic model of selected deformations of Polish speech in relation to specific human larynx diseases. An analysis of speech and parameter mapping in 29-dimensional space is reviewed in this study. Speech parameters were extracted in time, frequency and cepstral (quefrency) domains resulting in diagrams that qualified symptoms and conditions of selected human larynx diseases. The paper presents graphically selected human larynx diseases.     

Monitoring of odors emitted from stabilized dewatered sludge subjected to aging using proton transfer reaction–mass spectrometry

Environmental Science and Pollution Research - One of the potential emission sources of odorous compounds from wastewater treatment plants is sludge processing. The odorous compounds released from...     

Effects of secondary metabolites produced by different cyanobacterial populations on the freshwater zooplankters Brachionus calyciflorus and Daphnia pulex

Environmental Science and Pollution Research - Cyanobacterial blooms in eutrophic water bodies are a worldwide problem. Combined effects of mixtures of secondary metabolites produced by different...     

The field experiments and model of the natural dust deposition effects on photovoltaic module efficiency

Environmental Science and Pollution Research - The maximisation of the efficiency of the photovoltaic system is crucial in order to increase the competitiveness of this technology. Unfortunately,...