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Urban ambient air quality trend analysis was evaluated as an alternative to rollback analysis to estimate vehicle emission standards needed to achieve national ambient air quality standards. Examination of the trends of monthly maximum 8 hour average carbon monoxide concentrations, central business district traffic activity, and emission rates from vehicles on the road suggests that the automotive exhaust emission standard for carbon monoxide derived in response to the requirements of the Clean Air Act Amendments of 1970 may be ten times too severe. The excessive stringency of the vehicle emission standard for carbon monoxide was confirmed by two different analyses of the correlation between annual mean carbon monoxide concentration and frequency of occurrence of carbon monoxide concentrations above the level of the 8-hour standard. One correlation analysis using all available CAMP data involved an empirical approach and the other assumed that carbon monoxide concentrations are described by the lognormal distribution. Based on the analysis of CAMP air quality data, a vehicle carbon monoxide emission standard of approximately 29 grams per mile appears adequate to meet the ambient air quality standard. The large difference between the results of this analysis and the 1976 Federal vehicle carbon monoxide emission standard indicates the advisability of applying this methodology to verification of the standards for hydrocarbons and oxides of nitrogen.  相似文献   
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Animal‐mediated seed dispersal is important for sustaining biological diversity in forest ecosystems, particularly in the tropics. Forest fragmentation, hunting, and selective logging modify forests in myriad ways and their effects on animal‐mediated seed dispersal have been examined in many case studies. However, the overall effects of different types of human disturbance on animal‐mediated seed dispersal are still unknown. We identified 35 articles that provided 83 comparisons of animal‐mediated seed dispersal between disturbed and undisturbed forests; all comparisons except one were conducted in tropical or subtropical ecosystems. We assessed the effects of forest fragmentation, hunting, and selective logging on seed dispersal of fleshy‐fruited tree species. We carried out a meta‐analysis to test whether forest fragmentation, hunting, and selective logging affected 3 components of animal‐mediated seed dispersal: frugivore visitation rate, number of seeds removed, and distance of seed dispersal. Forest fragmentation, hunting, and selective logging did not affect visitation rate and were marginally associated with a reduction in seed‐dispersal distance. Hunting and selective logging, but not fragmentation, were associated with a large reduction in the number of seeds removed. Fewer seeds of large‐seeded than of small‐seeded tree species were removed in hunted or selectively logged forests. A plausible explanation for the consistently negative effects of hunting and selective logging on large‐seeded plant species is that large frugivores, as the predominant seed dispersers for large‐seeded plant species, are the first animals to be extirpated from hunted or logged forests. The reduction in forest area after fragmentation appeared to have weaker effects on frugivore communities and animal‐mediated seed dispersal than hunting and selective logging. The differential effects of hunting and selective logging on large‐ and small‐seeded tree species underpinned case studies that showed disrupted plant‐frugivore interactions could trigger a homogenization of seed traits in tree communities in hunted or logged tropical forests. Meta Análisis de los Efectos de la Perturbación Humana sobre la Dispersión de Semillas por Animales  相似文献   
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The General Motors Research Laboratories and the Sloan-Kettering Institue for Cancer Research are collaborating to determine the contribution by automotive vehicles to the polynuclear aromatic hydrocarbons in city air. Sampling of particulate matter at the rate of 140 M3/min (5000 cfm) was carried out at two heavily-trafficked sites in Detroit and one suburban site in Warren, Michigan. Carbon monoxide was determined continuously, and particulate matter was analyzed for “tar,” polynuclear aromatic hydrocarbons, lead, vanadium, and sulfates. Polynuclear aromatic hydrocarbons in automobile exhaust gas are assumed to be dispersed in air along with carbon monoxide or lead from automobiles. It is further assumed that automobiles are the sole source of carbon monoxide and lead in the atmosphere. Concentrations of carbon monoxide and lead in exhaust gas and in the air are utilized to estimate the percentage of polynuclear aromatic hydrocarbons in the air attributable to automobiles. The mean automobile contributions to benzo(a)pyrene in the air, based on lead concentrations, were 18% at a Freeway Interchange, 5% in a downtown commercial area, and 42% in suburban Warren. The average concentrations of benzo(a)pyrene at the sites were 6 μg/103 M3, 7 μg/103 M3 and 1 μg/103 M3, respectively. Mean contributions based on carbon monoxide concentrations were approximately twice the levels based on lead concentrations. Benzo(a)pyrene and benz(a)anthracene in air were not statistically related to carbon monoxide or lead in air, but were higher in winter than in summer, probably because of the higher levels of these materials emitted in space heating combustion in winter.  相似文献   
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Abstract

A method using direct flame ionization detector (FID) measurement was developed to study total volatile organic compound (VOC) emissions during thermal degradation of polymers. This method was used to estimate organic emissions from different polymers, such as low-density polyethylene (PE), polypropylene (PP), polyethylene terephthalate (PET), and commingled postconsumer streams, such as recycled carpet residue and auto shredder residue (ASR). The effects of process parameters, such as temperature, heating rate, and residence time, were also studied. Significant VOC emissions were observed at normal processing temperatures, particularly from recycled polymers. Each polymer showed a distinct evolution pattern during its thermal degradation. The kinetics of VOC emissions were also studied using a nonisothermal technique. The kinetic parameters were in agreement with data from the literature.  相似文献   
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The newly developed model system HILLS is used to simulate recent (1990–2000) and future (up to 2020) changes in land use and carbon sequestration over Central Germany. HILLS is unique as that it integrates the spatially explicit land-use-change model LUC-Hesse with the dynamic ecosystem model Century under a GIS platform. With this new tool, the concurrent effects of urbanization, afforestation and cropland abandonment on regional carbon sequestration are analyzed for an exemplary “Business as Usual” scenario. During the simulation period, afforestation was estimated to sequester 880 Gg C and cropland abandonment 783 Gg C. Urbanization was estimated to release 336 Gg C formerly stored in soil organic matter and thereby offsets about 20% of the C sequestered by cropland abandonment and afforestation. The case study shows that urbanization can partly counteract the benefits of carbon sequestration resulting from other land-use changes and should be investigated in other carbon balances.  相似文献   
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