Finished leather waste chromium acid extraction and anaerobic biodegradation of the products

Due to the amounts of chromium in the leachate resulting from leather leaching tests, chromium sulfate tanned leather wastes are very often considered hazardous wastes. To overcome this problem, one option could be recovering the chromium and, consequently, lowering its content in the leather scrap. With this objective, chromium leather scrap was leached with sulfuric acid solutions at low temperature also aiming at maximizing chromium removal with minimum attack of the leather matrix. The effects of leather scrap dimension, sulfuric acid and sodium sulfate concentration in the solutions, as well as extraction time and temperature on chromium recovery were studied, and, additionally, organic matrix degradation was evaluated. The best conditions found for chromium recovery were leather scrap conditioning using 25 mL of concentrated H₂SO₄/L solution at 293 or 313 K during 3 or 6 days. Under such conditions, 30–60 ± 5% of chromium was recovered and as low as 3–6 ± 1% of the leather total organic carbon (TOC) was dissolved. Using such treatment, the leather scrap area and volume are reduced and the residue is a more brittle material showing enhanced anaerobic biodegradability. Although good recovery results were achieved, due to the fact that the amount of chromium in eluate exceeded the threshold value this waste was still hazardous. Thus, it needs to be methodically washed in order to remove all the chromium de-linked from collagen.     

Assessing Sustainability at Multiple Scales in a Rotational Bushmeat Hunting System

Abstract: Results of many studies show unsustainable levels of bushmeat hunting across West/Central Africa. Nevertheless, these results are usually derived from snapshot sustainability indices in which critical parameters are often taken from the literature. Simple, more informative tools for assessing sustainability are needed. We evaluated the impact of bushmeat hunting across a range of temporal, spatial, and taxonomic scales in a comparison of different measures of sustainability. Over 15 months in 2002–2004 in and around a village close to Equatorial Guinea's Monte Alén National Park, we collected data via a village offtake survey, hunter‐camp bushmeat‐consumption diaries, hunter interviews, and following hunters during hunts. We compared 2003 data with a previous offtake survey (1998–1999) and interview reports back to 1990. In the past 14 years, average distance from the village at which hunters operated remained constant, with hunters switching back and forth between long‐established camps, although trapping effort increased. In the past 5 years, overall offtake and number of active hunters did not change substantially, although catch per unit effort (CPUE) decreased slightly. Although the proportion of the two most commonly trapped species (Cephalophus monticola and Atherurus africanus) and gun‐hunted primates increased in the offtake, species presumably less robust to trapping decreased slightly. Apparent sustainability in economic terms may be masking gradual local extirpation of more vulnerable species before and during this study. Our results suggest that changes in prey profiles and CPUE may be the most accurate indicators of actual sustainability; these indices can be monitored with simple village‐based offtake surveys and hunter interviews to improve community management of bushmeat hunting.     

The Importance of Natural Processes in Understanding Ecosystem Change: A Case Study of Limed Lakes

In order to determine what effects human activities have on natural processes, it is important to thoroughly understand those processes. Unfortunately, we know little about what natural processes are operating, and even less about how they have functioned historically. This paper discusses the importance of natural processes in affecting surface water acidification and the necessity for developing quantitative estimates of natural, as well as anthropogenic, contributions to the acidification of surface waters. A review of the literature and the analysis of chemistry data from six limed lakes in New York and Massachusetts have identified a number of possible processes that may play important roles in acidifying surface waters. At present, these processes are poorly understood and require further research. Once we have such knowledge, we will be able to clearly see the effects of human activities on natural processes and modify those activities in ways that will mitigate negative impact in a predictable manner.     

Isoprene emissions and climate

Biogenic volatile organic compounds (BVOCs) play an important role in atmospheric chemistry and the carbon cycle. Isoprene is quantitatively the most important of the non-methane BVOCs (NMBVOCs), with an annual emission of about 400–600 TgC; about 90% of this is emitted by terrestrial plants. Incorporating a mechanistic treatment of isoprene emissions within land-surface schemes has recently become a focus for the modelling community, the aim being to quantify the potential magnitude of associated climate feedbacks. However, these efforts are hampered by major uncertainties about why plants emit isoprene and the relative importance of different environmental controls on isoprene emission. The availability and reliability of observations of isoprene fluxes from different types of vegetation is limited, and this also imposes constraints on model development. Nevertheless, progress is being made towards the development of mechanistic models of isoprene emission which, in conjunction with atmospheric chemistry models, will ultimately allow improved quantification of the feedbacks between the terrestrial biosphere and climate under past and future climate states.     

Can public participation help managing risks from natural hazards?

Most of the mitigation measures against natural hazards can not be perfectly allocated via the common market mechanism, given their principle character of being a public good. Thus, different instruments need to be applied to retrieve their values. Economic valuation tools are one alternative to estimate preferences of individuals towards these goods. These methods are often difficult to operationalise and are not a feasible task for every single project. An alternative is offered by direct preference representation through involving affected interest groups actively in decisions. A critical question is whether the decision on protection measures can be left to public participation or should remain in the experts’ decision responsibility. It can be observed that the latter mode shows inefficiencies. In this paper, it is argued that participation could be one way to bring about the desired goal of increasing efficiency. The present work offers a discussion of the relevant political economic concepts in order to introduce the idea that participation can increase efficiency through achieving the Pareto criterion claimed in the realm of constitutional economics. Furthermore it will be shown that decision aiding tools, namely multi-criteria analysis, can integrate participation into actual decision making processes in a structured way.     

Eco-efficiency evaluation of the petroleum and petrochemical group in the map Ta Phut Industrial Estate,Thailand

Map Ta Phut Industrial Estate (MTPIE), located in Rayong province, eastern of Thailand, was developed by the state enterprise, Industrial Estate Authority of Thailand, Ministry of Industry, to serve industries that use natural gas as the main raw material development. This research presents the eco-efficiency evaluation of the petroleum and petrochemical group (PP) in the MTPIE. There are 31 factories in the PP group, which can be divided into three categories: upstream, intermediate, and downstream. The eco-efficiency values of the PP group were evaluated according to the World Business Council for Sustainable Development recommendations. The comparison of eco-efficiency values between three industrial categories in the PP group demonstrates that factories in the downstream category obtained particularly good eco-efficiency results concerning material consumption, water use, and hazardous waste generation. The eco-efficiency trends of the PP group were simply analyzed by snapshot graph. With the availability of the data on environmental indicator, the water use indicator was selected to be an example indicator for analyzing the eco-efficiency trends of the PP group. The eco-efficiency snapshot concerning the net sale and water use during the year of 2003–2005 showed that the eco-efficiency trends of the PP group in the MTPIE shifted from half eco-efficient in 2004 to fully eco-efficient in 2005. This research can provide a basic framework on eco-efficiency evaluation for the industrial sector in Thailand, which will feed into strategic development, and would enable public participation in the discussion on branch developments and contributions to national trends.