LPG低温储存装置管道泄露风险分析

介绍了液化气的危险特性,结合实际对洛阳石化液化气低温储存装置存在的管道泄漏风险进行了原因分析,提出了相应的措施,保证了装置安全运行.     

贵州织金蒙家大坡地下水水化学特征分析

通过对贵州织金蒙家大坡地下水水化学指标进行分析。结果表明,研究区地下水Ca2+受环境影响最小、空间变异性最小,Na+受环境影响最大、空间变异性最大;各阴阳离子含量与TDS含量呈显著正相关关系,其相关性依次为:Ca2+SO2-4Mg2+Cl-HCO-3K+Na+;TDS含量的增加主要受SO2-4离子的影响,总硬度的变化主要受Ca2+的影响;地下水成分主要来自于碳酸盐矿物的溶解,其次是硫酸盐、含硫矿物、硅酸盐矿物以及盐岩的溶解,地下水类型主要向SO4·HCO3-Ca型和HCO3·SO4-Ca型转化。     

Assessment of potential dermal and inhalation exposure of workers to the insecticide imidacloprid using whole-body dosimetry in China

In China, although improvements to the pesticide registration process have beenmade in last thirty years, no occupational exposure data are required to obtain a commercial license for a pesticide product. Consequently, notably little research has been conducted to establish an exposure assessment procedure in China. The present study monitored the potential dermal operator exposure from knapsack electric sprayer wheat field application of imidacloprid in Liaocheng City, Shandong Province and in Xinxiang City, Henan Province, China, using whole-body dosimetry. The potential inhalation exposure was determined using a personal air pump and XAD-2 sample tubes. The analytical method was developed and validated, including such performance parameters as limits of detection and quantification, linear range, recovery and precision. The total potential dermal and inhalation exposures were 14.20, 16.80, 15.39 and 20.78 mL/hr, respectively, for the four operators in Liaocheng and Xinxiang, corresponding to 0.02% to 0.03% of the applied volume of spray solution. In all trials, the lower part (thigh, lower leg) of the body was the most contaminated, accounting for approximately 76% to 88% of the total exposure. The inhalation exposure was less than 1% of the total exposure. Such factors as the application pattern, crop type, spray equipment, operator experience and climatic conditions have been used to explain the exposure distribution over the different parts of the body. As indicated by the calculated Margin of Exposure, the typical wheat treatment scenarios when a backpack sprayer was used are considered to be safe in terms of imidacloprid exposure.     

A 1-dodecanethiol-based phase transfer protocol for the highly efficient extraction of noble metal ions from aqueous phase

A 1-dodecanethiol-based phase-transfer protocol is developed for the extraction of noble metal ions from aqueous solution to a hydrocarbon phase, which calls for first mixing the aqueous metal ion solution with an ethanolic solution of 1-dodecanethiol, and then extracting the coordination compounds formed between noble metal ions and 1-dodecanethiol into a non-polar organic solvent. A number of characterization techniques, including inductively coupled plasma atomic emission spectroscopy, Fourier transform infrared spectroscopy, and thermogravimetric analysis demonstrate that this protocol could be applied to extract a wide variety of noble metal ions from water to dichloromethane with an efficiency of >96%, and has high selectivity for the separation of the noble metal ions from other transition metals. It is therefore an attractive alternative for the extraction of noble metals from water, soil, or waste printed circuit boards.     

Mercury adsorption characteristics of HBr-modified fly ash in an entrained-flow reactor

In this study, the mercury adsorption characteristics of HBr-modified fly ash in an entrained-flow reactor were investigated through thermal decomposition methods. The results show that the mercury adsorption performance of the HBr-modified fly ash was enhanced significantly. The mercury species adsorbed by unmodified fly ash were HgCl₂, HgS and HgO. The mercury adsorbed by HBr-modified fly ash, in the entrained-flow reactor, existed in two forms, HgBr₂ and HgO, and the HBr was the dominant factor promoting oxidation of elemental mercury in the entrained-flow reactor. In the current study, the concentration of HgBr₂ and HgO in ash from the fine ash vessel was 4.6 times greater than for ash from the coarse ash vessel. The fine ash had better mercury adsorption performance than coarse ash, which is most likely due to the higher specific surface area and longer residence time.     

环境绩效评估在地方层面的应用——西双版纳案例

环境绩效评估是一种有效的环境管理工具,可将环境绩效纳入政府政绩考核内容。本文以云南省西双版纳傣族自治州为案例,探讨符合当地实际情况的环境评估指标体系和评估方法,利用DPSIR概念框架模式构建评估指标体系,通过一个时间系列的数据揭示和理清西双版纳州环境问题在"驱动力-压力-状态-影响-响应"各项指标间的相互关系,分析其联动状况,针对与预定目标的实现和可达程度低的指标,诊断西双版纳州环境状况和管理上存在的主要问题,判读西双版纳州在环境问题上的应对绩效,对环境保护政策、方案的制定提供直接依据,对促进和优化今后的规划和建设具有重要的指导意义,同时也为环境绩效评估在区域(东盟)和国家层面制度化和主流化提供基础。     

滁州地区覆盖层厚度对场地地震动参数的影响

以滁州地区近百个钻孔资料为原型建立土层模型,采用一维频域等效线性化波动方法进行了土层地震反应分析,重点分析了覆盖层厚度对场地地震动参数的影响。研究结果表明,随着覆盖层厚度的增加,地表峰值加速度及土层放大系数逐渐增大,当覆盖层厚度超过一定值时,地表峰值加速度及土层放大系数呈逐渐缓慢减小的趋势;而反应谱特征周期总体上随着覆盖层厚度的增加而逐渐增大。     

基于致灾因子指标体系的海冰灾害风险评估和区划方法

中国是世界上受海冰危害严重的国家之一,历史上曾发生过多次严重海冰灾害,造成重大损失。根据我国结冰海区海冰灾害风险的自然过程、社会经济状况和成灾机制,综合考虑致灾因子危险性、承灾体分类、分布及脆弱性以及防灾减灾能力等因素,对海冰灾害发生的可能性及其不确定性等进行综合分析,提出了开展海冰灾害风险评估和区划的理论依据,同时给出了利用致灾因子指标体系对海冰灾害风险进行评估和区划的具体方法。     

Magnesium-rich minerals in sediment and suspended particulates of South Florida water bodies: implications for turbidity

Fine sediments in shallow water bodies such as Lake Okeechobee are prone to resuspension. Predominantly inorganic "mud" sediment that covers approximately 670 km2 of the lake has been recognized as a persistent source of turbidity. The objective of this study was to determine if mineral components of sediments in Lake Okeechobee and water conveyances of the northern Everglades also occur as suspended sediment and hence constitute a potential abiotic contributor to turbidity. Sediment samples were collected from nine stations within the lake and eight locations north of Water Conservation Area 2A in the Everglades. Water samples were also collected at selected locations. The silt and clay mineralogy of sediment and suspended particles was determined using X-ray diffraction, thermogravimetry, scanning-electron microscopy, energy-dispersive X-ray elemental microanalysis, and high-resolution transmission-electron microscopy. Clay fractions of the lake sediment contained the Mg silicate minerals sepiolite and palygorskite, along with smectite, dolomite, calcite, and kaolinite. Sediment silt fractions were dominated by carbonates and/or quartz, with smaller amounts of Ca phosphates and sepiolite. Mineralogy of the mud sediment was similar to that reported for geologic phosphate deposits. This suggests that the mud sediment might have accumulated by stream transport of minerals from these deposits. Suspended solids and mud-sediment mineralogy were similar, except that smectite was more abundant in suspended solids. Everglade samples also contained Mg-rich minerals. The small size, low density, and fibrous or platy nature of the prevalent mud sediment minerals make them an abiotic, hydrodynamically sensitive source of persistent turbidity in a shallow lake. Mitigation efforts focused exclusively on P-induced biogeochemical processes do not address the origin or effects of these minerals. Ecological management issues such as turbidity control, P retention, geologic P input, and suitability of dredging are related to mud-sediment properties and provenance.     

Integration of chemical and biological methods: A case study of polycyclic aromatic hydrocarbons pollution monitoring in Shandong Peninsula, China

Polycyclic aromatic hydrocarbons(PAHs), as persistent toxic substances(PTS), have been widely monitored in coastal environment, including seawater and sediment. However, scientific monitoring methods, like ecological risk assessment and integrated biomarker response, still need massive researches to verify their availabilities. This study was performed in March, May, August and October of 2018 at eight sites, Yellow River estuary(S1), Guangli Port(S2), Xiaying(S3), Laizhou(S4), Inner Bay(S5), Ou...