Fetal heart scanning in the first trimester

The detailed study of the fetal cardiac anatomy in the first trimester of pregnancy by means of ultrasound, transvaginally or transabdominally, is feasible and remains a safe procedure provided thermal and mechanical indices are taken into account. Optimal time for successful imaging of the four chambers and great arteries in early gestation appears to be between 13 to 14 weeks. In experienced hands, first-trimester fetal echocardiography is accurate in detecting major structural cardiac abnormalities and yields a high negative predictive value. Thus, in a clinical setting, it can be offered to families considered to be ‘at risk’ of cardiac defects (e.g. those with previous family history or when fetal nuchal translucency is increased) and can be a powerful tool to reassure families regarding normality of major cardiac structures and connections. However, the early detection of an important structural abnormality (chromosomally normal or not) may be associated with a high termination rate if this is an acceptable option. The high prevalence of associated chromosomal and extracardiac abnormalities for many of the high-risk families, who may benefit from this approach, cannot be ignored. Therefore, fetal heart scanning in the first trimester should be performed in conjunction with detailed first-trimester obstetric scanning. Copyright © 2004 John Wiley & Sons, Ltd.     

Intercomparison of Two Models,ETA and RAMS,with TRACT Field Campaign Data

In this work a model intercomparison between RAMS and ETA models is carried out, with the aim of evaluating the quality and accuracy of these mesoscale models in reproducing the time evolution of the meteorology in real complex terrain. This is of great importance not only for meteorological forecast but also for air quality assessment. Numerical simulations are performed to reproduce the mean variables' fields and to compare them with measurements collected during the field campaign TRACT. The domain covers the Rhine valley and surrounding mountainous region and we consider a time period of two days. Results from simulations are compared to observations relative to ground stations and radiosoundings. A qualitative analysis is joined to a quantitative estimation of some reference statistical indexes. Both RAMS and ETA models performances are satisfactory when compared to the measured data and also their relative agreement is good. The mean variable fields are reproduced with a satisfactory degree of reliability, even if the simulated profiles are not able to describe the largest fluctuations of the variables. At the surface stations, the best agreement between predictions and observations is obtained for the wind velocity, while the quality of the results is lower for temperature and humidity.     

Procedures for estimation of modelling uncertainty in air quality assessment

The main objectives of this work focus, firstly, on a review of the current existent methodologies to estimate air quality modelling uncertainty, and, secondly, in the preparation of guidelines for modelling uncertainty estimation, which can be used by local and regional authorities responsible for air quality management. From the application exercise, it was concluded that it is possible to define a subset of statistical parameters able to reproduce the general uncertainties estimation. Concerning the quality indicators defined by EU directives, the results show that the legislated uncertainty estimation measures are ambiguous and inadequate in several aspects, mainly in what concerns the error measures for hourly and daily indicators based on the highest observed concentration. A relative error at the percentile correspondent to the allowed number of exceedances of the limit value was suggested and tested, showing that is a more robust and appropriate parameter for model performance evaluation.     

Degradation features of pesticides: a review on (metallo)porphyrin-mediated catalytic processes

Environmental Science and Pollution Research - Pesticides have been used to kill pests such as insects, fungi, rodents, and unwanted plants. Since these compounds are potentially toxic to the...     

Accessibility and trust: the two dimensions of consumers’ perception on sustainable purchase intention

The aim of this article is to shed new light on which dimensions compose sustainable purchase intention (SPI) with the purpose of understanding what moves consumers to a potentially more sustainable behaviour. Even though several studies have researched which factors influence consumer’s intention to buy in a more sustainable way, no comparable research in consumer behaviour was found studying these dimensions in a triple bottom line perspective (profit, people, and planet) that could also provide future corporate and academic applications. Therefore, this article proposes a new construct – Consumers’ Perception on SPI, defined using the C-OAR-SE procedure and measured using exploratory and confirmatory factor analysis using two different samples. In-depth interviews and online survey to actual consumers of sustainable products were undertaken in partnership with a sustainable project using its database, guaranteeing that real consumers’ perceptions were gathered for this study. The construct is proposed with two dimensions (measured by nine items): Accessibility (including facets such as product lower pricing, availability in stores, and being sold within a convenient proximity to home) and Trust (including consumers needs such as: to get to know and trust products through understanding the labels; to have had good experiences in the past or simply to have new trial opportunities). Theoretical and practical implications of the findings are also discussed.     

An approach to simulate wind fields around an urban environment for wind energy application

This work proposes an approach to simulate wind flow fields around an urban environment with the aim of evaluating the potential impact of buildings on the general wind patterns and power production using the current generation of commercial wind turbines. The simulation process was performed with the aid of accessible computational tools that can potentially render the proposed procedure applicable in other cases of interest. The roughness of the urban environment was defined as the association of roughness map, topography, and an alternative process for obtaining the volumetry of buildings. A case study was conducted in a region located at the district of Boa Viagem (Recife-PE) for assessing the applicability of the approach. Scenarios were designed in order to simulate wind flow patterns and pre-identify sites that have suitable wind energy potential for electric power production by investigating the combination of wind speed magnitude and turbulence intensity. From the results obtained, it was possible to identify zones of potential wind sources that are not detected in classical wind atlas probably due to the influence of the built environment on local wind flow patterns.     

Preparation of CuO/SiO<Subscript>2</Subscript> and photocatalytic activity by degradation of methylene blue

A photocatalyst based on CuO/SiO₂ was prepared, and evaluated for the degradation of methylene blue in aqueous medium. The photocatalyst was obtained by calcination method of copper salt, in the presence of silica. The characterization by XRD, FTIR, and TPR techniques confirmed the formation of CuO as active phase. SEM studies showed CuO deposited on the surface of SiO₂. By ESI-MS, it was demonstrated that the degradation of methylene blue occurs through successive hydroxylations. Photodegradation assays showed that CuO/SiO₂ was efficient for degradation, and that the material worked better in the presence of UV light.     

An analysis of the problems of developing environmental education in Brazilian Federal protected areas

This paper describes the problems encountered in developing environmental education in Federal protected areas in Brazil. Results of a survey on the current status of environmental education in four categories of Federal protected areas; namely national parks, biological reserves, ecological stations and environmental protection areas, are described and discussed. The study suggests that the development of environmental education in protected areas in the country has several limitations: financial resources, lack of training, material resources and a lack of policy on environmental education. It also identifies that some of these problems seem to be inter-related with those of the National System of Conservation Units of the country which may result in a retarding of the development of environmental education in such areas.     

A roadmap for the conservation of freshwater mussels in Europe

Europe has a long history of human pressure on freshwater ecosystems. As pressure continues to grow and new threats emerge, there is an urgent need for conservation of freshwater biodiversity and its ecosystem services. However, whilst some taxonomic groups, mainly vertebrates, have received a disproportionate amount of attention and funds, other groups remain largely off the public and scientific radar. Freshwater mussels (Bivalvia, Unionida) are an alarming example of this conservation bias and here we point out six conceptual areas that need immediate and long-term attention: knowledge, threats, socioeconomics, conservation, governance and education. The proposed roadmap aims to advance research, policy and education by identifying the most pressing priorities for the short- and long-term conservation of freshwater mussels across Europe.