Environmental Science and Pollution Research - Metal contamination is a threat to estuarine environments. They can accumulate in the food chain and cause toxic effects on aquatic organisms and... 相似文献
Oils and grease (O&G) have low affinity for water and represent a class of pollutants present in the dairy industry. Enzyme-mediated bioremediation using biocatalysts, such as lipases, has shown promising potential in biotechnology, as they are versatile catalysts with high enantioselectivity and regioselectivity and easy availability, being considered a clean technology (white biotechnology). Specially in the treatment of effluents from dairy industries, these enzymes are of particular importance as they specifically hydrolyze O&G. In this context, the objective of this work is to prospect filamentous fungi with the ability to synthesize lipases for application in a high-fat dairy wastewater environment. We identified and characterized the fungal species Aspergillus sclerotiorum as a good lipase producer. Specifically, we observed highest lipolytic activity (20.72 U g−1) after 96 h of fermentation using sunflower seed as substrate. The fungal solid fermented was used in the bioremediation in dairy effluent to reduce O&G. The experiment was done in kinetic from 24 to 168 h and reduced over 90% of the O&G present in the sample after 168 h. Collectively, our work demonstrated the efficiency and applicability of fungal fermented solids in bioremediation and how this process can contribute to a more sustainable wastewater pretreatment, reducing the generation of effluents produced by dairy industries.
The concentrations of organochlorine pesticides and PCBs were determined in surface sediments and freshwater molluscs (Angulyagra sp.) from water canals in the region of Hanoi city. Results obtained show that the concentration of sigma DDT compounds in sediments range from 7 to 80 ng/g (dry weight) and from 6 to 864 ng/g (dry weight) in the soft tissues of molluscs. The concentrations of sigma DDTs were higher in populated sites and much lower in rural sites, indicating that the DDT has been used for mosquito control and not as a crop protection chemical. Hexachlocyclohexanes (HCHs) have also been widely used in the region but the current environmental concentrations are much lower than those of DDT's, which is due to the less persistence of those compounds. Polychlorinated biphenyls (PCBs) were measured, for example as aroclor 1254, in concentrations up to 40 ng/g (dry weight) and up to 76 ng/g (dry weight) in sediments and molluscs, respectively. Molluscs from water canals are a very popular food in the region. Taking into consideration the high DDT levels measured in these molluscs their consumption is worrisome and may expose the population to high levels of endocrine disrupting substances. Current PCB levels in sediments are lower than usually measured in industrialized countries. Therefore, PCB concentrations in aquatic molluscs are still also relatively low. These snails do not have enzyme ability to metabolize most of the CB congeners and, thus, are passive accumulators and a significant transfer pathway of CBs to consumers. Therefore, measures to phase out the use of these persistent and bioaccumulable chemicals should be adopted in order to prevent further environmental contamination. 相似文献
A solid-phase microextraction (SPME) procedure has been developed to extract eight organophosphorus pesticides (OPs) in water and the method was compared with a conventional solid phase extraction (SPE) technique. The extracted OPs were analyzed by gas chromatography using thermionic specific detection. Both extraction methods presented linear calibration at least over the concentration range investigated (100 to 1000 ng x mL(-1) for SPE and 1 to 100 ng x mL(-1) for SPME). SPME method presented higher sensitivity than SPE. The quantitation limits were between 0.1 to 1.0 ng x mL(-1) for SPME depending upon the analyte, and 100 ng x mL(-1) for SPE. The precision, as measured by the standard deviations (RSD), were in the range 3.6% to 5.8% for SPME and 2.4% to 9.2% for SPE. Along with the feature of being a solvent - free sampling technique, SPME offers additional benefits due to its high sensitivity, simplicity, and small size sample required (typically: SPE - 500 mL, SPME - 5 mL). 相似文献
Mass wasting processes, like slope failures, on the margins of dam reservoirs, lakes, bays and oceans may generate large water
waves that can produce disasters due to flooding over the banks, run up along the shoreline and overtopping dam crests. Therefore,
the study of slope failures, the subsequent generation of impulse waves and their consequences are of paramount importance
for safety. In this paper the generation and propagation of water waves in reservoirs induced by landslides and their impact
on banks were investigated by means of a laboratory study carried out at University of Coimbra wave channel, in a flume measuring
12.0 m × 1.5 m × 1.0 m (L × H × W), where two banks with variable slope were placed. The study considered the sliding
of calcareous blocks over a sliding slope bank into the reservoir, the generation of impulse waves, their propagation in the
reservoir and their impact on the downstream bank. A number of waves were generated by different fallings of calcareous blocks,
considering different volumes, sliding slopes, initial positions and reservoir depths. All fallings were recorded by video-camera
and the results were processed afterwards to obtain the time history of the falling. The water surface variations due to transient
waves were measured at five gauges placed between the banks. The waves overtopping and breaking on the downstream bank were
also filmed using a video camera, and the hydrodynamic forces on this bank were also measured using four pressure transducers. 相似文献
Amazonia contains more carbon (C) than a decade of global, human-induced CO2 emissions (60–80 billion tons). This C is gradually being released to the atmosphere through deforestation. Projected increases in Amazon deforestation associated with investments in road paving and other types of infra-structure may increase these C emissions. An increase of 25–40% in Amazon deforestation due to projected road paving could counterbalance nearly half of the reductions in C emissions that would be achieved if the Kyoto Protocol were implemented. Forecasted emission increases could be curtailed if development strategies aimed at controlling frontier expansion and creating economic alternatives were implemented. Given ancillary benefits and relative low costs, reducing deforestation in Amazonia and other tropical areas could be an attractive option for climate mitigation. Projects that help contain deforestation and reduce frontier expansion can play an important role in climate change mitigation but currently are not allowed as an abatement strategy under the climate regime. Creating incentives for forest conservation and decreased deforestation can be a unique opportunity for both forest conservation and climate mitigation. 相似文献