Prioritising objectives for waste reprocessing: a case study in secondary lead refining

Secondary lead refining produces a sulphidic slag that also contains varying quantities of lead. Initially, the objectives of this project were to treat the slag in order to recover the valuable lead as well as to render the slag environmentally benign. However, in keeping with the principles of clean technology and, specifically, the approach of clean production, the project was redefined with the following priorities: waste characterisation; waste minimisation through process improvement; waste modification; identification of slag treatment methods. Characterisation of the waste facilitated an overall process understanding and aided in identifying process deficiencies. Process improvement was aimed at reducing both the quantity of slag produced as well as the lead loss to the slag. Waste characterisation combined with local hazardous waste regulations enabled desirable waste modifications to be identified. These waste adaptations were implemented through process modification. Lastly, treatment methods for the slag were identified.     

SOME SIMPLE MODELS FOR CONTINUOUS VARIATE TIME SERIES1

ABSTRACT: A survey is given of recently developed models for continuous variate non–Gaussian time series. The emphasis is on marginally specific models with given correlation structure. Exponential, Gamma, Weibull, Laplace, Beta and Mixed Exponential models are considered for the marginal distributions of the stationary time series. Most of the models are random coefficient, additive linear models. Some discussion of the meaning of autoregression and linearity is given, as well as suggestions for higher–order linear residual analysis for non–Gaussian models.     

Corallum morphology and composition of crustacean cryptofauna of the hermatypic coralMadracis mirabilis

The motile crustacean cryptofauna of the hermatypic coralMadracis mirabilis (Duchassaing and Michelotti) was examined from three sites on reefs along the west coast of Barbados in 1985. In addition to site differences in degree of eutrophication, two distinct with-in-corallum habitats were recognized, based on differences in the growth form of the coral host. One form grows in isolated, hemispherical heads, with short, robust, widely separated branches covered by 50 to 80% live tissue. The second form occurs within large continuous beds of long, thin, tightly spaced branches tipped by 20 to 30% live tissue. Coral habitats consisting of small isolated heads support a crustacean fauna of high decapod and amphipod diversity, with numerous rare and site endemic species and an abundance of relatively large decapods and amphipods. The continuous beds favour a community of lower decapod and amphipod diversity, fewer rare and site endemic species and with an abundance of smaller sized isopods and copepods. It is suggested that spatial separation of branches and colonies as well as food availability associated with corallum morphology are factors influencing the variation in species abundance and faunal composition of the two habitats.     

An economist's remarks on landscaping

These costs and benefits may be more easily noticed or precisely defined by different persons. Some are seen by the landscape architect but not by the economist, and the other way round. This implies that a reasonably adequate enumeration of the benefits and costs, each considered in a very wide sense, can be achieved only if a proposal is viewed from the standpoints of different disciplines.

It may very well be that the mere enumeration of these costs and benefits will either convince the economist that the proposed scheme is ‘on’ or convince the landscape architect that it is ‘off’. In the latter case the landscape architect may say that while it would be wonderful to proceed with the scheme he can see that it would, in the wide ‘opportunity’ sense of the phrase, cost too much. But there may come a stage where the enumeration of costs and benefits leaves the landscape man wanting Scheme A and the social scientist wanting Scheme B. It is here that, first of all, adjustment must be tried. But if it fails then compromise may be needed, in which one side or the other, or both, reluctantly sacrifices some feature of his favoured scheme. If agreement cannot be reached, then the difference of opinion ought to be put to the client, who can reach his own decision.     

A multi-hazard history of Antigua*

Antigua experiences earthquakes, droughts and hurricanes. To isolate for study each of these as they occur, would be to over simplify the inter-relationships between the aftereffects of one and the occurrence and the effects of the next. Moreover, there will be conditions arising from factors outside the natural disaster spectrum which bear upon, and are themselves affected by, all of these phenomena. This interplay of events and conditions is readily illustrated in the case of island countries, which have a natural and clearly defined containment. Such interrelationships suggest a complex human-ecological system which must be recognized if environmental balance and compatability are to be maintained - particularly in respect of hazards. This documentary analysis of the colonial era in Antigua, has to conclude for the time being with questions concerning the environmental effectiveness of imported systems of administration which, with no knowledge of comparable natural hazards, assumed sectoral separation.     

Source apportionment of Phoenix PM2.5 aerosol with the Unmix receptor model

The multivariate receptor model Unmix has been used to analyze a 3-yr PM2.5 ambient aerosol data set collected in Phoenix, AZ, beginning in 1995. The analysis generated source profiles and overall average percentage source contribution estimates (SCEs) for five source categories:gasoline engines (33 +/- 4%), diesel engines (16 +/- 2%), secondary SO4(2-) (19 +/- 2%), crustal/soil (22 +/- 2%), and vegetative burning (10 +/- 2%). The Unmix analysis was supplemented with scanning electron microscopy (SEM) of a limited number of filter samples for information on possible additional low-strength sources. Except for the diesel engine source category, the Unmix SCEs were generally consistent with an earlier multivariate receptor analysis of essentially the same data using the Positive Matrix Factorization (PMF) model. This article provides the first demonstration for an urban area of the capability of the Unmix receptor model.