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471.
Removal of copper ions and dissolved phenol from water using micellar-enhanced ultrafiltration with mixed surfactants 总被引:11,自引:0,他引:11
A laboratory study was conducted to evaluate the effects of composition and concentration of mixed anionic/nonionic surfactants on the efficiency of a micellar-enhanced ultrafiltration (MEUF) operation in removing metal ions/organic solutes from aqueous solutions. Based on the analysis of surface tensions and micelle sizes, it was found that for mixed sodium dodecylsulfate (SDS)/Triton X-100 surfactants, the critical micelle concentration (cmc) was significantly lower than that of SDS and mixed micelles formed. The mixed surfactant system was then applied in a cross-flow mode of MEUF, in which the concentration polarization can be neglected, to remove Cu2+ from aqueous solutions. With a surfactant concentration of 10 mM, the Cu2+ rejection was negligible by using pure Triton X-100 and increased with increasing SDS mole fraction with a value as high as 85%, which suggests that the rejection of Cu2+ was due to the electrostatic attraction between Cu2+ and SDS. Furthermore, pronounced Cu2+ rejection was obtained for a 5 mM SDS solution, which was attributable to a decrease in the cmc of SDS by the existence of Cu2+. When the MEUF technique was applied to remove Cu2+ and phenol simultaneously from aqueous solutions, the Cu2+ rejection was slightly enhanced in the presence of phenol. However, the rejection of phenol was comparatively low, approximately 27%, which may be caused by its relatively hydrophilic characteristic. 相似文献
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迄今为止,国内外有关计算构件耐火极限的方法,是钢筋混凝土构件与防火研究的主要内容。而在结构设计中,由于直接考虑的是荷载作用,为此提出了一个新概念——等效火灾荷载,将火灾对结构的影响直接考虑成荷载作用。在确定了混凝土柱的截面温度场后,利用一种简化计算方法计算出钢筋混凝土柱的等效火灾荷载,进而计算出钢筋混凝土柱的耐火极限。在火灾中,作为结构最基本的构件柱可能受到单面或多面的火作用,这里仅介绍轴心受压钢筋混凝土柱等效火灾荷载的计算。 相似文献
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US/Fenton试剂协同处理焦化废水的研究 总被引:2,自引:0,他引:2
采用US (超声波)协同Fenton试剂氧化法处理焦化废水,考察了H2O2投加量、Fe2 投加量、废水的pH、反应时间和超声波功率对处理效果的影响,确定了最佳工艺条件.结果表明,在H2O2投加量7.0 g/L;Fe2 投加量500 mg/L;pH=3.0; 反应时间 40 min; 超声波功率 600 W 的条件下,COD、NH3-N、CN-和色度的去除率分别达95.8%、71.3%、69.5%和75.2%,出水COD降至41.0 mg/L.在相同条件下,US/Fenton试剂协同法的处理效率比单独Fenton试剂氧化法的处理效率提高了约20%,且反应时间显著缩短. 相似文献
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The discovery of cell-free DNA (cfDNA) in maternal plasma has opened up new promises for the development of non-invasive prenatal testing (NIPT). Application of cfDNA in NIPT of fetus diseases and abnormalities is restricted by the low amount of fetal DNA molecules in maternal plasma. Fetus-derived cfDNA in maternal plasma are shorter than maternal DNA, thus leveraging the maternal and fetus-derived cfDNA molecules size difference has become a novel and more accurate method for NIPT. However, multiple biological properties such as size distribution of plasma DNA, proportion of fetal-derived DNA and methylation levels in maternal plasma across different gestational ages still remain largely unknown. Further insights into the size distribution and fragmentation pattern of circulating plasma cfDNA will shed light on the origin and fragmentation mechanisms of cfDNA during physiological and pathological processes in prenatal diseases and enhance our ability to take the advantage of plasma cfDNA as a molecular diagnostic tool. In the review, we start by summarizing the research techniques for the determination of the fragmentation profiles of cfDNA in maternal plasma. We then summarize the main progress and findings in size profiles of maternal plasma cfDNA and cffDNA. Finally, we discuss the potential diagnostic applications of plasma cfDNA size profiling. 相似文献
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Min Zhu Fan Lü Li-Ping Hao Pin-Jing He Li-Ming Shao 《Waste management (New York, N.Y.)》2009,29(7):2042-2050
In this study, the effects of micro-aeration and liquid recirculation on the hydrolysis of vegetable and flower wastes during two-phase solid–liquid anaerobic digestion were assessed. To accomplish this, we evaluated the hydrolysis of five batches of waste that were treated under the following conditions: anaerobic, insufficient micro-aeration (aeration for 5 min every 24 h), and sufficient micro-aeration (aeration for 5 min every 12, 4 and 1 h). Hydrolysis was found to depend on the level of micro-aeration. Specifically, insufficient micro-aeration led to unstable and decreased performance. Conversely, sufficient micro-aeration promoted the hydrolysis of easily biodegradable carbohydrates and proteins, but the microbial activity was later impaired by liquid recirculation using methanogenic effluent. The hydrolysis efficiency under anaerobic conditions was comparable to the efficiency observed under sufficient micro-aeration, while the cumulative TOC of the anaerobic batch was 1.4–2.4 times higher than that of the micro-aerated batches. In addition, liquid recirculation did not have a negative effect on the development of microbial activity under anaerobic conditions, which resulted in the lignocelluloses having a higher hydrolysis efficiency. 相似文献