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991.
Sundström M Ehresman DJ Bignert A Butenhoff JL Olsen GW Chang SC Bergman A 《Environment international》2011,37(1):178-183
The widespread presence of perfluorooctanesulfonate (PFOS), perfluorooctanoate (PFOA), and perfluorohexanesulfonate (PFHxS) in human general populations and their slow elimination profiles have led to renewed interest in understanding the potential human neonatal exposures of perfluoroalkyls (PFAs) from consumption of human milk. The objective of this study was to evaluate the concentrations of PFOS, PFHxS, and PFOA in pooled human milk samples obtained in Sweden between 1972 and 2008 (a period representing the most significant period of PFA production) and to see whether the time trend of these analytes parallels that indicated in human serum. Chemical analysis of PFOS, PFHxS, and PFOA was performed on pooled Swedish human milk samples from 1972 to 2008 after methodological refinements. The 20 samples which formed the 2007 pool were also analyzed individually to evaluate sample variations. Analyses were performed by HPLC-MS/MS. Due to the complexities of the human milk matrix and the requirement to accurately quantitate low pg/mL concentrations, meticulous attention must be paid to background contamination if accurate results are to be obtained. PFOS was the predominant analyte present in the pools and all three analytes showed statistically significant increasing trends from 1972 to 2000, with concentrations reaching a plateau in the 1990s. PFOA and PFOS showed statistically significant decreasing trends during 2001-2008. At the end of the study, in 2008, the measured concentrations of PFOS, PFHxS, and PFOA in pooled human milk were 75 pg/mL, 14 pg/mL, and 74 pg/mL, respectively. The temporal concentration trends of PFOS, PFHxS, and PFOA observed in human milk are parallel to those reported in the general population serum concentrations. 相似文献
992.
S.M. Pan S.G. TimsX.Y. Liu L.K. Fifield 《Journal of environmental radioactivity》2011,102(10):930-936
A sediment core collected from the sub-aqueous delta of the Yangtze River estuary was subjected to analyses of 137Cs and plutonium (Pu) isotopes. The 137Cs was measured using γ-spectrometry at the laboratories at the Nanjing University and Pu isotopes were determined with Accelerator Mass Spectrometry (AMS), measurements made at the Australian National University. The results show considerable structure in the depth concentration profiles of the 137Cs and 239+240Pu. The shape of the vertical 137Cs distribution in the sediment core was similar to that of the Pu. The maximum 137Cs and 239+240Pu concentrations were 16.21 ± 0.95 mBq/g and 0.716 ± 0.030 mBq/g, respectively, and appear at same depth. The average 240Pu/239Pu atom ratio was 0.238 ± 0.007 in the sediment core, slightly higher than the average global fallout value. The changes in the 240Pu/239Pu atom ratios in the sediment core indicate the presence of at least two different Pu sources, i.e., global fallout and another source, most likely close-in fallout from the Pacific Proving Grounds (PPG) in the Marshall Islands, and suggest the possibility that Pu isotopes are useful as a geochronological tool for coastal sediment studies. The 137Cs and 239+240Pu inventories were estimated to be 7100 ± 1200 Bq/m2 and 407 ± 27 Bq/m2, respectively. Approximately 40% of the 239+240Pu inventory originated from the PPG close-in fallout and about 50% has derived from land-origin global fallout transported to the estuary by the river. This study confirms that AMS is a useful tool to measure 240Pu/239Pu atom ratio and can provide valuable information on sedimentary processes in the coastal environment. 相似文献
993.
This study was conducted to identify the principle selenate carrier phases for two selected soils, by comparing their reactivity with selenate to that of pure phases of the solids. Silica, calcium carbonate, aluminium hydroxide, goethite, bentonite and humic acid were selected as the main soil carrier phases. Comparisons were made first on the parameter values obtained with the best fit of a kinetic sorption model which can discriminate instantaneous sorption from kinetically limited sorption. Then comparisons were made of the ability for each solid to stabilise selenate by measuring the ratio of the partition coefficient for sorption (Kdsorption) over that of the desorption (Kddesorption). Kinetics and stabilisation were used to help elucidate the nature of interactions with the test solid phases for a large range of selenate concentrations. The experiments were conducted over 165 h in batch reactors, the solid being isolated from the solution by dialysis tubing, at two pH (5.4 and 8) and three selenate concentrations (1 × 10−3, 1 × 10−6 and 1 × 10−8 mol L−1). The results obtained showed that only aluminium hydroxide can sorb selenate throughout the studied pH range (pH 5.4 to 8.0). The sorption capacity on this mineral was high (Kdsorption > 100 to 1 × 104 L kg−1) and the selenate was mainly stabilized by the formation of inner sphere complexes. The sorption on goethite occurred at pH 5.4 (Kdsorption 52 L kg−1), mainly as outer sphere complexes, and was null at pH 8. On silica, a weak sorption was observed only at pH 5.4 and at 165 h (Kdsorption 4 L kg−1). On bentonite, calcium carbonate and humic acid no significant sorption was observed. Concerning the two soils studied, different behaviours were observed for selenate. For soil Ro (pH 5.4), Kdsorption was low (8 L kg−1) compared to soil Bu (pH 8) (70 L kg−1). The sorption behaviour of selenate on soil Ro was mainly due to outer sphere complexes, as for goethite, whereas for soil Bu the sorption was mainly attributed to inner sphere complexes followed by reduction mechanisms, probably initiated by microorganisms, in which no steady state was reached at the end of the 165 h experiments. The sorption of selenate decreased when concentrations reached 1 × 10−3 mol L−1, due to solid saturation, except for aluminium hydroxide. Reduction of selenate seemed also to occur on goethite and soil Ro, for the same concentration, but without preventing a decrease in sorption. Thus, this work shows that the comparison of selenate behaviour between soil and pure phases helps to elucidate the main carrier phases and sorption mechanisms in soil. 相似文献
994.
Thaddeus Chidi Nzeadibe Chukwuedozie K. Ajaero 《Environment, Development and Sustainability》2011,13(1):163-177
Solid waste management (SWM) in many low- and middle-income countries is sometimes driven by the informal sector. Unfortunately,
contributions of the sector to SWM are not acknowledged in many developing countries. This situation often arises from inadequate
awareness and lack of advocacy for these development contributions. This article reports on the impact of a study conducted
by final-year geography undergraduates on the informal waste management sector in Nsukka urban area, Nigeria. The purposes
of this exercise were to stimulate development intervention on behalf of the sector to improve perceptions, attitudes and
performance, to impart a range of development research skills and to expose the students to the business opportunities provided
by SWM and recycling. Informal waste sector workers and government officials responsible for SWM were interviewed, and some
commercial data on recycling operations were collected. Findings of this study indicate that such advocacy initiatives were
effective in increasing students’ awareness of opportunities and interest in working in the informal waste sector to promote
better SWM and development in Nigeria. Lessons from this university case study are also drawn for other developing countries
struggling to achieve the poverty reduction and job creation Millennium Development Goals (MDGs). 相似文献
995.
Matilda Palm Madelene Ostwald Indu K. Murthy Rajiv K. Chaturvedi N. H. Ravindranath 《Regional Environmental Change》2011,11(2):423-435
This paper analyses environmental and socio-economic barriers for plantation activities on local and regional level and investigates
the potential for carbon finance to stimulate the increased rates of forest plantation on wasteland, i.e., degraded lands,
in southern India. Building on multidisciplinary field work and results from the model GCOMAP, the aim is to (1) identify
and characterize the barriers to plantation activities in four agro-ecological zones in the state of Karnataka and (2) investigate
what would be required to overcome these barriers and enhance the plantation rate and productivity. The results show that
a rehabilitation of the wasteland based on plantation activities is not only possible but also anticipated by the local population
and would lead to positive environmental and socio-economic effects at a local level. However, in many cases, the establishment
of plantation activities is hindered by a lack of financial resources, low land productivity and water scarcity. Based on
the model used and the results from the field work, it can be concluded that certified emission reductions such as carbon
credits or other compensatory systems may help to overcome the financial barrier; however, the price needs to be significantly
increased if these measures are to have any large-scale impact. 相似文献
996.
Stakeholder engagement in social learning to resolve controversies over land-use change to plantation forestry 总被引:1,自引:1,他引:0
Rapid land-use change arising from incentives for afforestation has created tensions in rural communities previously dominated
by agricultural enterprises. This paper reports on an innovative experiment with social learning that incorporated participatory
modelling to resolve community concerns in a case study of plantation forestry in the Upper Clarence catchment of north-eastern
NSW Australia. The development of a diagnostic framework helped identify socioeconomic and environmental issues within the
community for investigation by a self-selected participatory advisory committee (PAC) representing a diversity of views. Implementation
of a social learning exercise offered empathetic and intellectual engagement among PAC members that maintained interest, built
confidence, and improved problem-solving capacity while fostering group ownership over decision making. A shared understanding
of dynamic landscape problems helped empower participants to collaboratively develop solutions for improved management and
operational practices, and cooperate to explore further options for plantation industry development under existing policy
guidelines which are presented in this paper. As a result of frank discussions between diverse stakeholders in a mutually
respectful learning environment that combined local, scientific and expert knowledge, concerns dissipated and participants
developed a more favourable view of plantation forestry activity. 相似文献
997.
Adaptive capacity determinants in developed states: examples from the Nordic countries and Russia 总被引:1,自引:1,他引:0
E. Carina H. Keskitalo Halvor Dannevig Grete K. Hovelsrud Jennifer J. West Åsa Gerger Swartling 《Regional Environmental Change》2011,11(3):579-592
Adaptive capacity in a community context has so far mainly been studied in developing countries as well as indigenous communities
in the industrialised world. This article adds to that literature through reviewing studies undertaken in the Nordic countries
and Russia, highlighting the ways in which general determinants of adaptive capacity play out in Northern, industrialised
contexts. The paper illustrates that the determinants of adaptive capacity in industrialised states exhibit systematic differences
from mixed subsistence-cash based communities such as those found in Arctic Canada. We discuss in particular the importance
of economic resources in a market-based system, technological competition, and infrastructure, in determining adaptive capacity
of natural resource-dependent communities in the Nordic countries and Russia. The paper also illustrates differences in adaptive
capacity within the case study region, including between peripheral and central locations with regard to economic resources
and diversification possibilities, and between Nordic and Russian cases with regard to infrastructure and technology access.
The findings indicate that understanding of determinants of adaptive capacity in resource-dependent communities would benefit
from both further contextualisation and broad comparison, across different types of political and administrative systems. 相似文献
998.
Meghann E. Jarchow Justin W. Rice Rebekah M. Ritson Sarah K. Hargreaves 《Sustainability Science》2011,6(2):253-254
Conference organizers are increasingly making efforts to reduce resource use at conferences, yet few responsibilities are
placed on attendees. We hosted an ecology conference and offered attendees a discount if they took a sustainability pledge
agreeing to reduce their resource use at the conference. In a post-conference survey, 83% of respondents reported fulfilling
the pledge, but 62% indicated that convenience was the biggest obstacle impeding their ability to continue the pledge during
and after the conference. We found great willingness by attendees to reduce resource use at and beyond our conference, and
facilitating their participation was an important part of our success. 相似文献
999.
This study projected responses of forest net primary productivity (NPP) to three climate change scenarios at a resolution
of 5 km × 5 km across the state of Louisiana, USA. In addition, we assessed uncertainties associated with the NPP projection
at the grid and state levels. Climate data of the scenarios were derived from Community Climate System Model outputs. Changes
in annual NPP between 2000 and 2050 were projected with the forest ecosystem model PnET-II. Results showed that forest productivity
would increase under climate change scenarios A1B and A2, but with scenario B1, it would peak during 2011–2020 and then decline.
The projected average NPP under B1 over the years from 2000 to 2050 was significantly different from those under A1B and A2.
Forest NPP appeared to be primarily a function of temperature, not precipitation. Uncertainties of the NPP projection were
due to large spatial resolution of the climate variables. Overall, this study suggested that in order to project effects of
climate change on forest ecosystem at regional level, modeling uncertainties could be reduced by increasing the spatial resolution
of the climate projections. 相似文献
1000.
Long-term (1860–2010) catchment mass balance calculations rely on models and assumptions which are sources of uncertainty
in acidification assessments. In this article, we report on an application of MAGIC to model acidification at the four Swedish
IM forested catchments that have been subject to differing degrees of acidification stress. Uncertainties in the modeled mass
balances were mainly associated with the deposition scenario and assumptions about sulfate adsorption and soil mass. Estimated
base cation (BC) release rates (weathering) varied in a relatively narrow range of 47–62 or 42–47 meq m−2 year−1, depending on assumptions made about soil cation exchange capacity and base saturation. By varying aluminum solubility or
introducing a dynamic weathering feedback that allowed BC release to increase at more acidic pHs, a systematic effect on predicted
changes in acid neutralizing capacity (ΔANC ca. 10–41 μeq l−1) and pH (ca. ΔpH = 0.1–0.6) at all sites was observed. More robust projections of future changes in pH and ANC are dependent
on reducing uncertainties in BC release rates, the timing, and extent of natural acidification through BC uptake by plants,
temporal changes in soil element pools, and fluxes of Al between compartments. 相似文献