铅锌矿产资源开发重金属污染风险评价

在论述环境风险评价的概念、理论和方法的基础上,通过对某典型铅锌矿山重金属污染程度、重金属毒性响应系数和生态危害系数的计算与探讨,建立了铅锌矿山重金属生态风险评价指标体系.根据所建立的指标体系,计算了每个样点的生态风险指数,结果认为该矿山总体环境质量很差,重金属污染极其严重.     

安全科学学科建设理论研究

安全科学是一门新兴的大交叉综合学科,为促进安全科学的快速发展,运用科学学思想和知识溯源等方法,从安全学科建设的高度,首先阐述交叉科学的属性、研究层次、交叉形式、知识命名和现有交叉科学研究存在的问题,在此基础上提出了安全科学研究的创新思路、安全科学研究的多视角与分类和安全科学研究成果的多样性特征,最后给出了安全科学新分支创建的实例。研究结果表明:只有了解交叉学科的基础问题,才能理解安全科学的发展,才能快速地创新安全科学。     

安全降变原理及C-S-R事故致因新模型

为发展安全科学原理和给事故防控与调查提供新的方法,根据变化对系统安全的影响机制,开展安全降变原理及事故致因新模型研究。首先,提出安全降变原理并解析其内涵及研究意义。其次,基于安全降变原理,给出不同层级安全系统变化的分类实例,并对作业场所事故及其致因重新定义和分类。再次,构建基于安全降变原理的C-S-R事故致因新模型。最后,基于事故案例分析,验证所提出的C-S-R事故致因新模型与安全降变原理的有效性。结果表明,各级安全系统中自发或是受联动的变化超出系统的变化承受水平时,将导致事故的发生。经事故案例分析验证可知,安全降变原理及C-S-R事故致因新模型具有充分的实用性。     

Identification of a novel hydroxylated metabolite of 2,2′,3,5′,6-pentachlorobiphenyl formed in whole poplar plants

Polychlorinated biphenyls (PCBs) are a group of persistent organic pollutants consisting of 209 congeners. Oxidation of several PCB congeners to hydroxylated PCBs (OH-PCBs) in whole poplar plants has been reported before. Moreover, 2,2′,3,5′,6-pentachlorobiphenyl (PCB95), as a chiral congener, has been previously shown to be atropselectively taken up and transformed in whole poplar plants. The objective of this study was to determine if PCB95 is atropselectively metabolized to OH-PCBs in whole poplar plants. Two hydroxylated PCB95s were detected by high-performance liquid chromatography-mass spectrometry in the roots of whole poplar plants exposed to racemic PCB95 for 30 days. The major metabolite was confirmed to be 4′-hydroxy-2,2′,3,5′,6-pentachlorobiphenyl (4′-OH-PCB95) by gas chromatography-mass spectrometry (GC-MS) using an authentic reference standard. Enantioselective analysis showed that 4′-OH-PCB95 was formed atropselectively, with the atropisomer eluting second on the Nucleodex β-PM column (E2-4′-OH-PCB95) being slightly more abundant in the roots of whole poplar plants. Therefore, PCB95 can at least be metabolized into 4′-OH-PCB95 and another unknown hydroxylated PCB95 (as a minor metabolite) in whole poplar plants. Both atropisomers of 4′-OH-PCB95 are formed, but E2-4′-OH-PCB95 has greater atropisomeric enrichment in the roots of whole poplar plants. A comparison with mammalian biotransformation studies indicates a distinctively different metabolite profile of OH-PCB95 metabolites in whole poplar plants. Our observations suggest that biotransformation of chiral PCBs to OH-PCBs by plants may represent an important source of enantiomerically enriched OH-PCBs in the environment.     

Impact of land use on shallow groundwater quality characteristics associated with human health risks in a typical agricultural area in Central China

Environmental Science and Pollution Research - Groundwater pollution seriously threatens water resource safety due to high-intensity land use throughout the world. However, the relationship between...     

Markers of oxidative stress and toxicant exposure among young waterpipe smokers in the USA

Waterpipe (aka hookah) tobacco smokers are exposed to toxicants that can lead to oxidative DNA and RNA damage, a precursor to chronic disease formation. This study assessed toxicant exposure and biomarkers of DNA [8-oxo-7, 8-dihydro-2′-deoxyguanosine (8-oxodG)] and RNA [8-oxo-7,8-dihydroguanosine (8-oxoGuo)] oxidative damage during smoking of flavored and non-flavored waterpipe tobacco. Thirty waterpipe smokers completed two counterbalanced 2-h lab waterpipe smoking sessions (flavored vs. non-flavored waterpipe tobacco). Urinary concentrations of 8-oxodG and 8-oxoGuo and expired carbon monoxide (eCO) were measured before and after the smoking sessions. A significant increase in the urinary concentrations of 8-oxodG (from 2.12 ± 0.83 to 2.35 ± 0.91 ng/mg creatinine, p = 0.024) and 8-oxoGuo (from 2.96 ± 0.84 to 3.45 ± 0.76 ng/mg creatinine, p = 0.003) were observed after smoking the non-flavored and flavored waterpipe tobacco, respectively. Our results also showed that the mean ± SD of eCO increased significantly after smoking the flavored (from 1.3 ± 1.1 to 20.3 ± 23.6 ppm, p < 0.001) and non-flavored waterpipe tobacco (from 1.8 ± 1.2 to 24.5 ± 26.1 ppm, p < 0.001). There were no significant differences in the means of 8-oxodG (p = 0.576), 8-oxoGuo (p = 0.108), and eCO (p = 0.170) between the flavored and non-flavored tobacco sessions. Smoking non-flavored and flavored waterpipe tobacco leads to oxidative stress and toxicant exposure. Our findings add to the existing evidence about the adverse effects of waterpipe tobacco smoking (WTS) and the need for strong policies to inform and protect young people from the risks of WTS.

     

The improved activity of Co3O4 nanorods using silver in the catalytic oxidation of toluene

Environmental Science and Pollution Research - Co3O4 nanorods with diameters of ~0.15 μm and lengths of ~1 μm were prepared using a hydrothermal method via the assembly of microcrystals...     

Delayed association of acute particulate matter 2.5 air pollution exposure with loss of complexity in cardiac rhythm dynamics: insight from detrended fluctuation analysis

Environmental Science and Pollution Research - There is a delayed (lag 1 to 2&nbsp;days) correlation between acute PM 2.5 (particulate matter &lt;?2.5&nbsp;μm in aerodynamic...     

NO2 catalytic formation,consumption, and efflux in various types of diesel particulate filter

Environmental Science and Pollution Research - The high NO2/NOX ratio in the after-treatment system is beneficial to its performance and achieved by NO catalytic conversion in diesel oxidation...     

Explanation of heavy metal pollution in coal mines of china from the perspective of coal gangue geochemical characteristics

Environmental Science and Pollution Research - In the process of coal gangue surface accumulation and underground filling disposal, the heavy metals contained in coal gangue will inevitably...