Optimizing Bankfull Discharge and Hydraulic Geometry Relations for Streams in New York State1

Mulvihill, Christiane I. and Barry P. Baldigo, 2012. Optimizing Bankfull Discharge and Hydraulic Geometry Relations for Streams in New York State. Journal of the American Water Resources Association (JAWRA) 48(3): 449-463. DOI: 10.1111/j.1752-1688.2011.00623.x Abstract: This study analyzes how various data stratification schemes can be used to optimize the accuracy and utility of regional hydraulic geometry (HG) models of bankfull discharge, width, depth, and cross-sectional area for streams in New York. Topographic surveys and discharge records from 281 cross sections at 82 gaging stations with drainage areas of 0.52-396 square miles were used to create log-log regressions of region-based relations between bankfull HG metrics and drainage area. The success with which regional models distinguished unique bankfull discharge and HG patterns was assessed by comparing each regional model to those for all other regions and a pooled statewide model. Gages were also stratified (grouped) by mean annual runoff (MAR), Rosgen stream type, and water-surface slope to test if these models were better predictors of HG to drainage area relations. Bankfull discharge models for Regions 4 and 7 were outside the 95% confidence interval bands of the statewide model, and bankfull width, depth, and cross-sectional area models for Region 3 differed significantly (p < 0.05) from those of other regions. This study found that statewide relations between drainage area and HG were strongest when data were stratified by hydrologic region, but that co-variable models could yield more accurate HG estimates in some local regional curve applications.     

Sorption of polycyclic aromatic hydrocarbons (PAHs) to low and high density polyethylene (PE)

Background, aim, and scope

According to their high sorption capacity polyethylene (PE) passive samplers are often used for the analysis of polycyclic aromatic hydrocarbons (PAHs) in the aquatic environment. PE is also one of the primary synthetic polymers found in oceans, and sorption of PAHs to marine PE debris may determine PAH exposure and therefore hazards in marine ecosystems. Thus, an understanding of the sorption process is of great importance. In the present study, the sorption of several PAHs with different polarities to low density polyethylene (LDPE) and high density polyethylene (HDPE) was studied in order to improve our understanding of the influence of material properties on the Fickian diffusion of PAHs into PE.

Materials and methods

Batch sorption experiments were performed with aqueous solutions containing acenaphthylene, acenaphthene, fluorene, phenanthrene, anthracene, fluoranthene, and LPDE or HDPE pellets. Samples were shaken in the dark at 20?±?1°C for 16 time intervals within one week. Concentrations of PAHs were determined in the aqueous samples using solid-phase microextraction coupled with gas chromatography–mass spectrometry. The distribution coefficients (K _PE) between PE and water were estimated from different models reported in the literature. Kinetic sorption of the PAHs into the plastic pellets was described by a diffusion model based on Fick’s second law in spherical coordinates.

Results and discussion

A comparison between different models describing the equilibrium distribution of PAHs between PE and water revealed that the sorption equilibrium seemed to be driven by parameters other than, or in addition to, organic carbon. For both plastic types, diffusion coefficients decreased while the molecular weight of the PAHs increased which indicates a hindered diffusion through the matrix as a result of a larger molecule size. Higher diffusion coefficients were derived for LPDE than for HDPE indicating a greater sorption velocity for LPDE according to the lower polymer density.

Conclusions

Our results revealed that equilibrium time could be shortened during passive sampling as polymer membranes of lower density are used. In some areas, marine ecosystems may not be in equilibrium with respect to concentrations of organic contaminants and abundance of marine plastic debris. In such cases, different polymer densities should be taken into account in risk assessments.

     

Rates of apical septal extension of Desmophyllum dianthus: effect of association with endolithic photo-autotrophs

It has been hypothesized that endolithic photo-autotrophs inside the skeleton of cold-water corals may have a mutualistic relationship with the coral host positively affecting coral calcification. This study investigated the effect of endolithic photo-autotrophs on the apical septal extension of the cold-water coral Desmophyllum dianthus at Fjord Comau, southern Chile (42.41°–42.15°S, 72.5°W). The fluorescent staining agent calcein was used to document the linear apical extension of septae for a period of one and a half years between 2006 and 2007. The results showed a severe reduction in extension rates associated with the presence of endolithic photo-autotrophs. Infested individuals grew about half as fast as non-infested polyps with a median value of 1.18 μm day^?1 compared to 2.76 μm day^?1. Contrary to the initial hypothesis, these results point toward a parasitic relationship between D. dianthus and its endolithic photo-autotrophs potentially impairing coral fitness. However, further data on physiological parameters and other aspects of the calcification process are necessary to confirm these findings.     

Experimental study on the thermal oxidation of 2-chlorophenol in air over the temperature range 450-900 degrees C

The thermal oxidation of 2-chlorophenol (2-CP) in air was investigated using a perfectly stirred reactor at 1 atm over the temperature range 450–900 °C. The relative concentration of 2-CP was 1000 ppmV (equivalence ratio Φ = 0.03). About fifty organic products were identified as trace species. The concentration profiles of 2-CP, carbon oxides as well as those of seventeen major organic intermediates and six non-to-lower chlorinated dioxins and furans were presented as a function of temperature for a residence time of 2 s. The most abundant intermediate products were carbon monoxide, 2 H-pyran-2-one, chlorobenzene, 4-cyclopenten-1,3-dione, phenol, benzofuran, 2-chlorohydroquinone and 2-indanone. These concentration profiles have revealed that temperatures of at least 900 °C were needed to completely oxidize 2-CP, CO and all other organic byproducts to carbon dioxide. Reaction pathways accounting for the formation of most observed products are proposed.     

Melanin pattern morphs do not differ in metabolic rate: implications for the evolutionary maintenance of a melanophore polymorphism in the green swordtail, <Emphasis Type="Italic">Xiphophorus helleri</Emphasis>

Variation in melanin patterns among individuals, populations, and species is common in fishes of the genus Xiphophorus. In the variable platyfish, Xiphophorus variatus, variation in metabolic rate is associated with melanin coloration and the color morphs appear to be physiological specialists adapted to particular environmental conditions. This study investigates whether a melanin polymorphism in the green swordtail, Xiphophorus helleri, is likewise associated with variation in metabolic rate. We measured metabolic rate as oxygen consumption rate of both adult male and juvenile X. helleri in static respirometers. The oxygen consumption rate does not differ significantly between the spotted and nonspotted morphs in either group, suggesting that-unlike in X. variatus-selection on metabolic rate is not involved in maintaining the polymorphism in X. helleri. We suggest that explanations need to be sought for the evolution of melanophore diversity in Xiphophorus that are pertinent to each melanin pattern polymorphism or groups of similar polymorphisms.