Kinetics of photocatalytic oxidation of trace organic compounds over titanium dioxide

The 350 nm UV-illuminated slurries of titanium dioxide were used to study the photocatalyzed degradation kinetics of dissolved organic carbon (DOC) as water contaminants. The initial rate data were well described by the Langmuir-Hinshelwood rate equation and the simplified Langmuir-Hinshelwood rate equation (i.e., ln(C₀/C)=K′t). The latter will be more easily used for predicting the degradation of DOC concentration at various elapsed times. In different DOC initial concentrations the apparent first-order rate constant (K′) decreased and half-life increased when the initial DOC concentration decreased. The Langmuir-Hinshelwood rate form will be the most convenient to describe the oxidation rate of DOC in the drinking water resources, if it is as brief as v=kKC.     

Unusual sonographic features of ARPKD

The classic sonographic appearance of the kidneys in fetuses with autosomal recessive polycystic kidney disease (ARPKD) has been well described. We report a case of enlarged kidneys with pyramidal hyperechogenicity quite similar to medullary nephrocalcinosis found in a fetus at 34 weeks' gestation. At 39 weeks, a female neonate was delivered and died after 22 h due to pulmonary insufficiency secondary to severe oligohydramnios. On pathological analysis, the gross and microscopic findings were typical of ARPKD with diffuse dilatation of tubules throughout. The fetal renal lobulation was prominent and on section, the pyramids were delineated within each lobule, accounting for the clear image of the pyramids observed on sonography. Copyright © 2006 John Wiley & Sons, Ltd.     

Insider or outsider? how employee perceptions of insider status affect their work behavior

Many researchers have used the insider–outsider distinction when discussing employment relationships (e.g., Graen & Scandura, 1987; Pfeffer & Baron, 1988). However, there is no known empirical research directly assessing employees' perceptions of their status as organizational insiders. This article is intended as an initial step to theoretically and empirically explore the concept of perceived insider status (PIS). First, we build theoretical arguments describing how organizations may differentiate between insider and outsider employees, leading to differences in perceptions of insider status. We then hypothesize and show empirical evidence that contrasts, but relates, actual inclusion and perceived organizational support to PIS. We subsequently examine two types of discretionary employee behavior, altruism and production deviance, as potential consequences of PIS. Our results suggest that both actual inclusion, as well as perceived insider status, have implications for organizational functioning via discretionary employee behaviors. Copyright © 2002 John Wiley & Sons, Ltd.     

Managing climate change risks in New York City’s water system: assessment and adaptation planning

Managing risk by adapting long-lived infrastructure to the effects of climate change must become a regular part of planning for water supply, sewer, wastewater treatment, and other urban infrastructure during this century. The New York City Department of Environmental Protection (NYCDEP), the agency responsible for managing New York City’s (NYC) water supply, sewer, and wastewater treatment systems, has developed a climate risk management framework through its Climate Change Task Force, a government-university collaborative effort. Its purpose is to ensure that NYCDEP’s strategic and capital planning take into account the potential risks of climate change—sea-level rise, higher temperature, increases in extreme events, changes in drought and flood frequency and intensity, and changing precipitation patterns—on NYC’s water systems. This approach will enable NYCDEP and other agencies to incorporate adaptations to the risks of climate change into their management, investment, and policy decisions over the long term as a regular part of their planning activities. The framework includes a 9-step Adaptation Assessment procedure. Potential climate change adaptations are divided into management, infrastructure, and policy categories, and are assessed by their relevance in terms of climate change time-frame (immediate, medium, and long term), the capital cycle, costs, and other risks. The approach focuses on the water supply, sewer, and wastewater treatment systems of NYC, but has wide application for other urban areas, especially those in coastal locations.     

After-effects of job-related stress: Families as victims

In recent years, the unique stress experienced by those who do ‘people work’ has been acknowledged by the helping professions as a widespread problem and has been recognized by social scientists as a topic requiring systematic research. This paper begins by briefly reviewing research on the type of job stress experienced by workers in the helping professions. Then, a study of 142 police couples is reported, illustrating the effects of job stress on family life. In a survey study, police officers and their wives described family interactions. Officers who were experiencing stress, as measured by the Maslach Burnout Inventory, were more likely to display anger, spend time off away from the family, be uninvolved in family matters, and to have unsatisfactory marriages. An examination of the coping patterns used to deal with the stress of police work highlights differences between coping strategies used by husbands versus wives.     

Determination of selected semi-volatile organic compounds in water using automated online solid-phase extraction with large-volume injection/gas chromatography/mass spectrometry

A rapid, sensitive, and cost-effective analytical method was developed for the analysis of selected semi-volatile organic compounds in water. The method used an automated online solid-phase extraction technique coupled with programmed-temperature vaporization large-volume injection gas chromatography/mass spectrometry. The water samples were extracted by using a fully automated mobile rack system based on x-y-z robotic techniques using syringes and disposable 96-well extraction plates. The method was validated for the analysis of 30 semivolatile analytes in drinking water, groundwater, and surface water. For a sample volume of 10 mL, the linear calibrations ranged from 0.01 or 0.05 to 2.5 ??g·L^?1, and the method detection limits were less than 0.1 ??g·L^?1. For the reagent water samples fortified at 1.0 ??g·L^?1 and 2.0 ??g·L^?1, the obtained mean absolute recoveries were 70%?C130% with relative standard deviations of less than 20% for most analytes. For the drinking water, groundwater, and surface water samples fortified at 1.0 ??g·L^?1, the obtained mean absolute recoveries were 50%?C130% with relative standard deviations of less than 20% for most analytes. The new method demonstrated three advantages: 1) no manipulation except the fortification of surrogate standards prior to extraction; 2) significant cost reduction associated with sample collection, shipping, storage, and preparation; and 3) reduced exposure to hazardous solvents and other chemicals. As a result, this new automated method can be used as an effective approach for screening and/or compliance monitoring of selected semi-volatile organic compounds in water.