Quantifying ozone uptake and its effects on the stand level of common beech (Fagus sylvatica L.) in Southern Germany

Stand level O(3) fluxes were calculated using water balance calculations for 21 Common beech (Fagus sylvatica L.) stands and O(3) data from 20 monitoring stations in Southern Germany. For this intention, the daily loss of water by evapotranspiration per stand area was set against the daily O(3) uptake. During the last 30 years, O(3) uptake ranges between 0 and 187 mmol ha(-1) d(-1) per stand area. Cumulative O(3) uptake (CUO(3)), ranging between 0.1 and 0.7 mmol m(-2) yr(-1) per stand area, shows increasing trends since 1971 with considerably greater values at high altitudes. Effects in radial growth were used to derive an initial approximate critical threshold value for O(3) impacts on the vitality and growth of mature beech stands in Southern Germany. It is concluded that this concept of O(3) flux estimation in combination with dendroecological analyses offers both a site specific and regional applicable approach to derive new critical levels for O(3).     

Assessing the transformation of chlorinated ethenes in aquifers with limited potential for natural attenuation: added values of compound-specific carbon isotope analysis and groundwater dating

The evaluation of biotransformation of chlorinated ethenes (CEs) in contaminated aquifers is challenging when variable redox conditions and groundwater flow regime are limiting factors. By using compound-specific stable carbon isotope analysis (C-CSIA) and ³H-³He based groundwater dating, we assessed three CE-contaminated field sites that differed in groundwater flow velocities, redox conditions, and level of contamination. CE isotopic signatures and carbon isotopic mass balances were applied to quantify CE transformation, whereas groundwater dating allowed determining degradation timescales and assessing hydrodynamic regimes. The combination of these techniques enabled at all field sites to indicate zones within the aquifers where CE dechlorination preferably occurred, sometimes even to metabolites of no toxic concern. However, the natural transformation processes were insufficient to mitigate the entire CE contamination at the studied sites. Such situations of limited transformation are worldwide far more common than sites where optimal natural (mainly redox) conditions are enabling complete CEs degradation. Despite such constraints for natural transformation, this study showed that even under non-favorable biogeochemical CEs degradation, the combination of CSIA and groundwater dating provide valuable information to the understanding of the fate of the CEs, thus, being an important contribution in the definition of efficient remediation measures at any given biogeochemical conditions.     

Sampling for landscape elements—a case study from Lower Saxony,Germany

The estimation of coverage, i.e., the proportion of the total area in a study region covered by a given target class, is essential to many aspects of environmental monitoring. We analyze and compare the efficiency of different sample-based approaches for the estimation of coverage of different land cover classes from aerial imagery in a case study in Lower Saxony, Germany on the basis of the estimated standard errors. A complete delineation of vegetation classes in n?=?279 aerial photo plots of 400 × 400 m thrown onto the study region of 1,117.7 km² in accordance with a systematic grid is compared to different configurations of line intercept sampling and clusters of points. The observation designs under study are characterized by different complexity and total size of the observation units and therefore also to the efforts related to yield a single observation. Especially for those classes that cover a relatively large proportion of the sampling frame, our results show that difference in performance between the different designs are negligible. A cluster of four transects of 200 m each allows estimating the area of land cover classes with high coverage with nearly similar precision as a complete mapping of fixed area plots of 16 ha each. Clusters of points show unexpected high precision for the estimated coverage of land cover classes with relatively high coverage.     

PCDD/F and dioxin-like PCB profiles in soils amended with sewage sludge,compost, farmyard manure,and mineral fertilizer since 1962

Background, aim, and scope  

Biowaste contains compounds of agricultural value such as organic carbon, nutrients, and trace elements and can partially replace mineral fertilizer (MIN) and improve the physical properties of the soil. However, the obvious benefits of land spreading need to be carefully evaluated against potential adverse effects on the environment and human health. Environmental contamination resulting from biowaste application is one of the key variables when assessing cost/benefits. This study provides data on the resulting concentration of polychlorinated dibenzodioxins and dibenzofurans (PCDD/Fs) and dioxin-like polychlorinated biphenyls (DL-PCBs) in the soil column as a result of the different types of fertilizers.     

Biogeochemical Control of the Coupled CO2–O2 System of the Baltic Sea: A Review of the Results of Baltic-C

Past, present, and possible future changes in the Baltic Sea acid–base and oxygen balances were studied using different numerical experiments and a catchment–sea model system in several scenarios including business as usual, medium scenario, and the Baltic Sea Action Plan. New CO₂ partial pressure data provided guidance for improving the marine biogeochemical model. Continuous CO₂ and nutrient measurements with high temporal resolution helped disentangle the biogeochemical processes. These data and modeling indicate that traditional understandings of the nutrient availability–organic matter production relationship do not necessarily apply to the Baltic Sea. Modeling indicates that increased nutrient loads will not inhibit future Baltic Sea acidification; instead, increased mineralization and biological production will amplify the seasonal surface pH cycle. The direction and magnitude of future pH changes are mainly controlled by atmospheric CO₂ concentration. Apart from decreasing pH, we project a decreasing calcium carbonate saturation state and increasing hypoxic area.     

Responses to projected changes in climate and UV-B at the species level

Environmental manipulation experiments showed that species respond individualistically to each environmental-change variable. The greatest responses of plants were generally to nutrient, particularly nitrogen, addition. Summer warming experiments showed that woody plant responses were dominant and that mosses and lichens became less abundant. Responses to warming were controlled by moisture availability and snow cover. Many invertebrates increased population growth in response to summer warming, as long as desiccation was not induced. CO2 and UV-B enrichment experiments showed that plant and animal responses were small. However, some microorganisms and species of fungi were sensitive to increased UV-B and some intensive mutagenic actions could, perhaps, lead to unexpected epidemic outbreaks. Tundra soil heating, CO2 enrichment and amendment with mineral nutrients generally accelerated microbial activity. Algae are likely to dominate cyanobacteria in milder climates. Expected increases in winter freeze-thaw cycles leading to ice-crust formation are likely to severely reduce winter survival rate and disrupt the population dynamics of many terrestrial animals. A deeper snow cover is likely to restrict access to winter pastures by reindeer/caribou and their ability to flee from predators while any earlier onset of the snow-free period is likely to stimulate increased plant growth. Initial species responses to climate change might occur at the sub-species level: an Arctic plant or animal species with high genetic/racial diversity has proved an ability to adapt to different environmental conditions in the past and is likely to do so also in the future. Indigenous knowledge, air photographs, satellite images and monitoring show that changes in the distributions of some species are already occurring: Arctic vegetation is becoming more shrubby and more productive, there have been recent changes in the ranges of caribou, and "new" species of insects and birds previously associated with areas south of the treeline have been recorded. In contrast, almost all Arctic breeding bird species are declining and models predict further quite dramatic reductions of the populations of tundra birds due to warming. Species-climate response surface models predict potential future ranges of current Arctic species that are often markedly reduced and displaced northwards in response to warming. In contrast, invertebrates and microorganisms are very likely to quickly expand their ranges northwards into the Arctic.     

The Influence of Temperature on Chemical Fluid-Rock Reactions in Geological CO2 Sequestration

For a Bunter formation in the German Federal State of North Rhine Westphalia, we use numerical models to consider reactions between the supercritical, aqueous, and solid phases. These reactions may occur in a CO₂-water system representing a saline aquifer CO₂ storage scenario. Thus, the models are used for determining the extent of fluid–rock reactions during mineral dissolution or precipitation. In particular, we study the effect of temperature by comparing results for our system set at 100 °C and at 58 °C. Results show that the abundance of dissolved ions changes as a result of elevated temperature. For the entire 10,000-year simulation period, the overall geochemical behavior of the Bunter reservoir rock at the Minden site is explained in terms of different mineral transformations, although some of them are not changed significantly. This mainly comprises the alteration of carbonate minerals such as calcite, and aluminium silicates such as oligoclase, chlorite, illite, albite, kaolinite, and Na-smectite. Another chemical behavior derives from the generation and consumption of new secondary minerals such as dawsonite, pyrite, and Ca-smectite. In contrast to a system temperature of 58 °C, the mineralogical transformations of other minerals such as siderite, ankerite, dolomite, and magnesite are not observed at 100 °C. Also, the numerical simulation results show that at elevated temperature, the dominant role played by hydrodynamic mechanism dwarfs the role of other trapping mechanisms including dissolution and mineralization. Results also demonstrate how geological, petrophysical, and geochemical data can be integrated to estimate quantitatively the magnitude of the fluid–rock reactions. These reactions may entail new geotechnical problems, such as rock self-fracturing which ultimately decreases the CO₂ sequestration projects security.     

Levels of PCDD/Fs and trace elements in superficial soils of Pavia Province (Italy)

Trace elements and polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) were analyzed in soils from rural and light-industrialized sites (n=168) of Province of Pavia (Northern Italy). Most of the trace element values fit in typical ranges of concentrations in soils and are similar to the ones reported for rural sites in Italy or sites with no direct anthropogenic impact. Total concentrations of 2,3,7,8 chlorine substituted PCDD/Fs in superficial soils ranged between 24.4 and 1287 pg g(-1) dw (0.5-28.9 pg WHO(98)-TEQ g(-1) dw). The North Eastern part of the Province presented significantly higher levels (p<0.001) than the rest of the Province for As, Cd, Hg, Pb, Zn and PCDD/Fs. While the existence of a defined heavy metal polluting source for this specific site has been suggested, in the case of PCDD/Fs, profiles were not linked to any specific emission source fingerprint. In the whole extension of Pavia Province, OCDD/F dominated the 2,3,7,8 chlorine substituted congener soil pattern, followed by the 1,2,3,4,6,7,8 hepta-CDD/F congener. Principal Component Analysis (PCA) showed that this profile could not be associated to any described PCDD/F emission source fingerprint and was relatively similar to the baseline deposition of sites with no direct impact of PCDD/F emission sources independently of land use.