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131.
介绍了煤炭地下气化技术的开发与应用,相比传统煤炭开采燃用技术,煤炭地下气化实现了煤炭清洁开采与利用,指出煤炭地下气化技术是环保型开采与利用技术,应用积极推广利用。 相似文献
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Adsorption of lambda-cyhalothrin and cypermethrin on two typical Chinese soils as affected by copper
Jun Liu Xiaomeng Lü Jimin Xie Yafei Chu Cheng Sun Qian Wang 《Environmental science and pollution research international》2009,16(4):414-422
Background, aim, and scope Pesticides and heavy metals pollution in soil environment has become a serious problem in many countries including China.
Repeated applications of bordeaux mixture (a blend of copper sulfate and calcium hydroxide) and pyrethroid (Pys) insecticides
have led to elevated copper (Cu) and Pys concentrations in vineyard surface soils. However, few studies focused on the interaction
of Pys and heavy metals in the soil environment. Our previous studies had indicated the combined effect of cypermethrin (CPM)
and Cu on soil catalase activity. Also, we had suggested that the addition of Cu could catalyze photo-degradation of CPM and
lambda-cyhalothrin (λ-CHT) in aqueous solution and restrain their degradation in soil. To better understand the potential
influence of Cu on the fate of Pys in the soil environment, the aim of the present work was to examine the effect of Cu on
the adsorption of λ-CHT and CPM on two typical Chinese soils with different soil characteristics, which was one of the key
processes controlling the fate of Pys, and to provide more information about the potential ecological risk of chemicals on
the soil ecosystem. Fourier transform infrared and point charges analysis using the MOPAC program of the Gaussian system were
also used to reveal the probable adsorption mechanism of λ-CHT and CPM on soils.
Materials and methods Two vineyard soils with different properties were chosen as experimental samples. They were sampled from 0 to 10 cm, dried,
and sieved to 2 mm. Each soil was spiked with copper sulfate solution to obtain the following total soil Cu concentrations:
100, 200, 400, 800, and 1,600 mg·kg−1. The treated soils were incubated for 2 weeks and then dried at 20°C. For each soil sample and at each soil Cu concentration,
the adsorption of λ-CHT and CPM was measured using a batch equilibrium method. The concentration of λ-CHT was determined by
HPLC, and the amount of λ-CHT and CPM adsorbed by the soil sample at equilibrium was determined by the difference between
the initial and equilibrium concentrations in solution corrected by the blank adsorption measurement.
Results Without the addition of Cu, the adsorption of λ-CHT and CPM on Black soil is greater than that on Red soil, while the adsorption
of λ-CHT on both soils is significantly stronger than that of CPM. As the soil Cu concentration increased from 19 (or 18;
background) to 1,600 mg·kg−1, the adsorption coefficient (K
d) of λ-CHT decreased from 12.2 to 5.9 L·kg−1 for Red soil, and from 26.1 to 16.8 L·kg−1 for Black soil, whereas the CPM adsorption coefficient in both soils decreased nearly by 100% (K
d decreased from 9.4 to 0.2 L·kg−1 for Red soil and from 16.2 to 0.5 L·kg−1 for Black soil).
Discussion Pys adsorption is a surface phenomenon which depends on the surface area and the organic matter content. Thus, the Black soil,
having higher organic matter and greater surface area than that of the Red soil, show greater adsorption affinity to λ-CHT
and CPM. In our study, the different adsorption affinity of the two Pys was obtained, which was probably attributed to differences
with respect to their physical–chemical properties. Further comparison upon the two Pys was conducted. The point charges of
halogen atoms in the λ-CHT and CPM were calculated, the differences of which probably lead to the fact that λ-CHT has a stronger
binding capacity to soils than CPM. Also, FTIR spectra show that competitive adsorption occurs between CPM and Cu for the
same adsorption sites, which is responsible for the obtained suppression of CPM adsorption affected by Cu.
Conclusions Lambda-cyhalothrin shows a significantly stronger adsorption than cypermethrin on both soils. This phenomenon may be due to
several reasons: (1) λ-CHT has lower solubility and a higher octanol–water partition coefficient value than CPM; (2) λ-CHT
consists of specific isomers, whereas CPM is mixtures of eight different isomers; (3) the chlorine and fluorine atoms in the
λ-CHT have a negative point charge, whereas the chlorine atoms in the CPM have a positive point charge. As the soil Cu concentrations
increased from 19 (or 18) mg·kg−1 to 1,600 mg·kg−1, the adsorption coefficient of λ-CHT and CPM decreased on both soils. This is mainly due to a competition between Cu and
Pys for occupying the adsorption sites on soils. The information from this study have important implications for vineyard
and orchard soils, which often contain elevated levels of Cu and Pys. These results are also useful in assessing the environmental
fate and health effect of λ-CHT and CPM.
Recommendations and perspectives It is important for environmental scientists and engineers to get a better understanding of soil–metal–organic contaminant
interactions. However, pesticide adsorption involves complex processes, and shortcomings in understanding them still restrict
the ability to predict the fate and behavior of pesticide. Therefore, considerable research should be carried out to understand
the mechanism of interaction between Pys and heavy metal on soils clearly. 相似文献
134.
有机磷降解酶的固定化及其工业化应用初探 总被引:3,自引:0,他引:3
采用一种新型的酶固定化方法,在大孔微球中对有机磷降解酶(OPHC2)固定化,制备固相载体化的交联酶聚集体固定化酶。对具有实际应用意义的参数:热稳定性、牢固度和连续反应批次进行了重点研究。结果表明,有机磷降解酶固定化酶的半衰期在70℃时比游离酶提高了2.1倍。固定化酶分别在37℃的摇床中经14 h高速振荡,以及在pH 8、37℃条件下循环反应49个批次降解甲基对硫磷后,均未发现固定化酶酶活力下降。在37℃,有机磷降解酶固定化酶柱以每小时3倍柱床体积的速率对甲基对硫磷农药乳油的稀释液(甲基对硫磷含量为216 mg/L)进行降解处理,系统连续工作156 h,甲基对硫磷的降解率保持在98.4%~99.9%。 相似文献
135.
136.
Fatin Samara Brian K. Gullett Robert O. Harrison Andrew Chu George C. Clark 《Environment international》2009,35(3):588-593
Determination of toxic activity requires knowledge of both the concentration and toxicity to evaluate the risk for adverse human health and environmental effects. A chemically-activated luciferase gene expression cell bioassay system (CALUX) and an antibody-based method enzyme immunoassay (EIA) were used to detect the dioxin-like response of several polybrominated, polychlorinated, and polybrominated/chlorinated dibenzo-p-dioxins/furans (PBDDs/Fs, PCDDs/Fs, and PBCDDs/Fs, respectively). It has been suggested that the biological activity of the brominated and mixed bromo/chloro compounds is similar to their chlorinated analogues (measured by binding to the Ah receptor). PBDD/F, PCDD/F, and PBCDD/F laboratory standards exhibited biological activity ranging over three orders of magnitude. The highest relative potency (REP) values from CALUX analysis, when compared to 2,3,7,8-TCDD, were 2,3,7,8-TBDD at 0.99 (± 0.07), 1,2,3,7,8-PeCDD at 0.69, and 2-Br-3,7,8-TriCDD at 0.72 (± 0.02). Cross-reactivities were calculated using EIA for several PBDDs/Fs and PBCDDs. The highest percent cross-reactivity was found for 2,3,7,8-TBDD at 138 (± 34%), and 2,3,7-TriBDD at 84 (± 36%). 相似文献
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138.
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140.
Environmental fate and non-target impact of glyphosate-based herbicide (Roundup) in a subtropical wetland 总被引:1,自引:0,他引:1
Mai Po Nature Reserve (Hong Kong) is an internationally important wetland for waterbirds. Roundup, a formulation based on glyphosate, has been used to control the widespread weeds within the reserve for many years but the fate and non-target impact of the herbicide is unknown. To fill this knowledge gap, we applied Roundup by hand-held sprayer to an estuarine and a freshwater pond in the dry season of year 2002. The surface water and sediment were sampled routinely for glyphosate concentrations following one month of application. In situ bioassays using local edible fish species were performed along with the herbicide application. Up to 52% of glyphosate in the surface water was transported to the unapplied regions by wind-driven current in the estuarine pond at 1 DPT (day post treatment). For both ponds, glyphosate concentrations in the water decreased rapidly after 1-3 DPT, but then decreased gradually over time. Both physical adsorption to the bottom sediments and microbial degradation are thought to contribute to these decreases. Interestingly, the persistence of glyphosate in the freshwater pond was longer than in the estuarine system, which is likely due to the considerably higher concentrations of chelating metals (i.e. Cu and Fe) present in the sediment (4.5 and 11-fold higher, respectively) which potentially reduced the bioavailability of glyphosate to the microbial decomposers. Lastly, fishes used in the in situ bioassays (both in applied and unapplied areas) showed similar survival rates, indicating that the use of Roundup at the provided application rate posed no serious hazard. 相似文献