自备电厂锅炉安全存在问题及解决措施

对自备电厂锅炉的历史背景、安全现状以及安全存在问题的原因进行了详细的阐述,并列举出解决安全问题的措施及建议.     

构建我国综合防灾法律体系的探讨——源于汶川地震的思考

本文在汲取汶川地震抗震救灾经验教训的基础上,分析了我国防灾领域立法的现状和存在的问题,提出制定综合性"防灾减灾基本法",出台指导防灾减灾各阶段工作的基础性法律,加强各单灾种法律法规等构建我国综合防灾法律体系的对策.     

吹扫捕集-气质联机法测定水中三氯乙醛

用吹扫捕集-气相色谱/质谱法对水中三氯乙醛进行了测定,研究了吹扫时间、NaOH溶液加入量对三氯乙醛响应值的影响,确定的实验条件为:吹扫4 min,每40 ml水样中加入0.20 ml NaOH溶液,标准曲线范围在1.0～200μg/L时,线性相关系数可达0.999,取样量5 ml时,检出限0.21μg/L。精密度和准确度实验结果为:空白水分别加标2.0μg/L和20μg/L时,6次平行测定的平均回收率分别为108%和94.4%,RSD分别为3.1%和2.4%。     

NOx photocatalytic degradation on active concrete road surface — from experiment to real-scale application

The use of titanium dioxide (TiO₂) as a photocatalyst in concrete pavements has received considerable attention in recent years due to its ability to decontaminate via photocatalytic processes. The objective of this study is to assess the effectiveness of activated concrete road in the degradation of nitrogen oxides (NO_x). We have used a TiO₂ and activated carbon (AC) permeable spray solution to coat concrete to assess its NO_x purifying ability. A number of experiments were undertaken to ascertain the conditions that affect NO_x purification. Indoor simulation experiments with active concrete road at optimum conditions show that it has good purification ability, self-regeneration and repetition ability, with a minimum decontamination rate for NO and NO₂ of 37.4% and 25.84%, respectively. Outdoor experiments show that the photodegradation of NO_x is related to light intensity and temperature. As the light intensity increases the reaction rate increases, and conversely as temperature increases the reaction rate decreases.     

孕鼠PFOS暴露对糖皮质激素水平及胎鼠生长发育的影响

为探究孕期全氟辛烷磺酸(PFOS)暴露与母源糖皮质激素(GC)水平、胎鼠生长发育之间的关系,将孕期为12 d(GD12)的24只SD雌性大鼠,随机分为4组给予不同剂量的PFOS(0,5,10,20 mg·kg-1),连续灌胃7 d,在GD19时对孕鼠和胎鼠的体重、胎鼠肝脏系数和肝脏生化指标、孕鼠血清的生化指标和GC水平、胎盘11β-羟基类固醇脱氢酶2(11β-HSD2)的酶学活性和胰岛素样生长因子-1(IGF-1)的mRNA表达水平分别进行检测。结果表明,与对照组相比:PFOS 20 mg·kg-1组,母鼠体重、胎鼠体重和体长显著下降(P0.001);PFOS 20 mg·kg-1组,胎鼠肝脏脏器系数低于对照组(P0.001);PFOS 10 mg·kg-1组,胎鼠肝脏中的酶活性(ALT、AST和ALP等)显著升高(P0.001);PFOS 20 mg·kg-1组,孕鼠血清GC水平升高(P0.05);胎盘IGF-1的mRNA表达水平随PFOS剂量升高而降低;胎盘11β-HSD2的活性随PFOS剂量升高而降低。研究表明,孕期暴露PFOS可以导致胎鼠肝脏毒性,降低胎盘11β-HSD2氧化活性导致GC浓度升高,进而影响胎鼠的生长发育。     

Investigation of the decomposition reaction and dust explosion characteristics of crystalline dicumyl peroxide

The dicumyl peroxide (DCP) is widely used as a polymerization initiator, catalyst and vulcanizing agent in the chemical industry. A number of accidents have been caused by its thermal instability in storage or manufacturing process. Thus, its hazard characteristics have to be clearly identified. First of all, the differential scanning calorimeter (DSC) is used to measure the heat of decomposition reaction, which can contribute to understanding the reaction characteristics of DCP. The accelerating rate calorimeter (ARC) is used to measure the rates of temperature and pressure rises of decomposition reaction, and then the kinetics parameters are estimated. Furthermore, the MIKE 3 apparatus and the 20-l-Apparatus are used to measure and analyze the dust explosion characteristics of DCP at room temperature and atmospheric pressure. Finally, Semenov's thermal explosion theory is applied to investigate the critical runaway condition and the stability criterion of decomposition reaction, and to build the relationship of critical temperature, convective heat transfer coefficient, heat transfer surface area and ambient temperature. These results contribute to improving the safety in the reaction, transportation and storage processes of DCP.     

Variability and predictability of sea-level extremes in the Hawaiian and U.S.-Trust Islands—a knowledge base for coastal hazards management

The objective of this study is to provide an improved climatology of sea level extremes on seasonal and long-term time scales for Hawaii and the U.S-Trust islands. Observations revealed that the Hawaiian and U.S.-Trust islands, by and large, display a strong annual cycle. For estimating the statistics of return period, the three-parameter generalized extreme value (GEV) distribution is fitted using the method of L-moments. In the context of extremes (20- to 100-year return periods), the deviations in most of the Hawaiian Islands (except at Nawiliwili and Hilo) displayed a moderate sea-level rise (i.e., close to 200 mm), but the deviations in the U.S.-Trust islands displayed a considerably higher rise (i.e., more than 300 mm) in some seasons due to typhoon-related storm surges. This rise may cause damage to roads, harbors, and unstable sandy beaches. Correlations between the El Niño-Southern Oscillation (ENSO) climate cycle and the variability of seasonal sea level have been investigated. Results show that correlation for the station located west of the International Date Line (DL) is strong, but it is moderate or even weaker for stations east of the DL. The skill of SST-based Canonical Correlation Analyses (CCA) forecasts was found to be weak to moderate (0.4–0.6 for Honolulu, Kahului, Hilo, and Wake, and 0.3 or below for Kahului, Mokuoloe, and Johnston). Finally, these findings are synthesized for evaluating the potential implications of sea level variability in these islands.     

Sterol production and phytosterol bioconversion in two species of heterotrophic protists, Oxyrrhis marina and Gyrodinium dominans

The kinetics and efficiency of sterol production and bioconversion of phytosterols in two heterotrophic protists Oxyrrhis marina and Gyrodinium dominans were examined by feeding them two different algal species (Rhodomonas salina and Dunaliella tertiolecta) differing in sterol profiles. R. salina contains predominantly brassicasterol (?99%) and <2% cholesterol. The major sterols in D. tertiolecta are ergosterol (45–49%), 7-dehydroporiferasterol (29–31%) and fungisterol (21–26%). O. marina fed R. salina metabolized dietary brassicasterol to produce 22-dehydrocholesterol and cholesterol. O. marina fed D. tertiolecta metabolized dietary sterols to produce cholesterol, 22-dehydrocholesterol, brassicasterol and stigmasterol. G. dominans fed either R. salina or D. tertiolecta metabolized dietary sterols to make cholesterol, brassicasterol and a series of unknown sterols. When protists were fed R. salina, which contains cholesterol, the levels of cholesterol were increased to a magnitude of nearly 5- to 30-fold at the phytoplankton-heterotrophic protist interface, equivalent to a production of 172.5 ± 16.2 and 987.7 ± 377.7 ng cholesterol per mg R. salina carbon consumed by O. marina and G. dominans, respectively. When protists were fed D. tertiolecta, which contains no cholesterol, a net production of cholesterol by the protists ranged from 123.2 ± 30.6 to 871.8 ± 130.8 ng per mg algal C consumed. Cholesterol is not only the dominant sterol, but a critical precursor for many physiologically functional biochemicals in higher animal. As intermediates, these heterotrophic protists increase the amount of cholesterol at the phytoplankton–zooplankton interface available to higher trophic levels relative to zooplankton feeding on algae directly.     

硫磺回收装置扩能改造及效果分析

介绍了回收酸性气体生产硫磺的工艺原理与工艺流程,论述了影响硫磺回收装置生产能力的诸多因素与扩能改造的情况。扩能改造后,该装置的酸性气体处理量平均为976m^3／h,瞬时处理量可达1200m^3／h,硫磺的生产能力从4450t／a提高到7500t／a,生产能力提高了68．5％,装置总硫回收率达到93．5％。