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81.
Degradation pathways of PCBs upon UV irradiation in hexane. 总被引:9,自引:0,他引:9
The photodegradations of eight individual PCB congeners (5, 31, 52, 77, 87, 126, 138, 169) in hexane have been investigated employing a mercury lamp. All degradation reactions of the above mentioned PCB congeners are of the pseudo first order. The principal products of PCB decomposition are the less chlorinated biphenyls, and no PCB-solvent adducts are found. Symmetrical and coplanar PCB congeners show lower photoreactivities. The reactivities of the chlorine atoms at various positions of PCB rings are generally in the order: ortho > meta > para. Photodechlorinations occur mainly on the more substituted rings, when the numbers of chlorine atoms on the two phenyl rings are unequal. During photodegradation, some coplanar PCB congeners are formed, which make the TEQ of solutions to decrease slowly or even to increase. 相似文献
82.
Fanling Meng Yunxue Xia Jianshuai Zhang Dong Qiu Yaozhu Chu Yuanyuan Tang 《Frontiers of Environmental Science & Engineering》2021,15(6):116
83.
A two-dimensional inviscid model of the gravity-current head produced by the release of a relatively small volume of dense fluid from behind a tall lock gate is constructed by Lagrangian block simulation. Three numerical experiments are conducted for the lock’s height-to-length aspect ratios H/L o = 8, 4 and 2. The front speeds obtained by the simulations agree with the laboratory observation for a similar range of aspect ratios. The floor velocity in the wake behind these heads is found to be greater than their front speed. The high floor velocity is caused by the impingement of the coherent wake vortex on the floor. It is a condition that permits these gravity-current heads to maintain their structural integrity so that the fine sediments can travel with the head over long distances on the ocean floor. The structural coherence of the current head depends on the lock aspect ratio. The gravity-current head produced by the release from the lock with the highest aspect ratio of H/L o = 8 is most coherent and relatively has the greatest floor velocity and the least trailing current behind the head. 相似文献
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Tham Trinh Thi Hung Trinh Le Thuy Trinh Thi Mai Vu Thi Trinh Le Thi Hai Chu Vu Minh Tu Binh 《Environmental science and pollution research international》2022,29(28):41992-42004
Environmental Science and Pollution Research - The Red River is the largest river in northern Vietnam, and it serves as the main water source for production and human activities in the Red River... 相似文献
87.
Zhao Huiying Wang Zhichun Li Xiufen Chu Zheng Zhao Chunliang Zhao Fang 《Environmental science and pollution research international》2022,29(1):509-517
Environmental Science and Pollution Research - In order to explore the characteristics of climate change in the future in the West Liao River Basin under the background of future climate change,... 相似文献
88.
Various clean-up technologies have been developed for the removal and/or destruction of trichloroethene (TCE) in the subsurface. Surfactant-aided soil washing followed by photodegradation could be a promising approach to such a task. The modelling of TCE photodegradation by UV in Brij 35 surfactant micelles is therefore investigated. Two stages of TCE degradation are observed in surfactant Brij 35 systems. A lag phase is observed at the commencement of the degradation, but the duration of the lag phase is significantly reduced as the initial pH increases. As the overall decay of TCE is also found to be faster at higher pH levels, it is suggested that the free radical reaction is dominant at high pH levels, and the formation of lag phases is mainly due to the deficiency of free radicals at lower pH levels. Since the period of the lag phase gradually decreases with the increase of initial pH level, and the two pseudo first-order reaction constants (one for the lag phase and one for the subsequent fast decay) for TCE decay in both stages are also pH dependent, a non-steady-state mathematical model is developed for the prediction of TCE photodegradation in Brij 35 solutions, in which the remaining fraction of TCE (C/C0) in the system can be determined at any instant by using a simple parameter of the initial system pH. 相似文献
89.
我国粮食安全保障中改善农业环境的途径 总被引:3,自引:0,他引:3
本文分析了我国粮食安全及粮食持续生产所依托的农业环境状况。从我国粮食生产状况与经济发展水平看,全国粮食生产处于结构性过剩与低水平安全中,区域性粮食安全与不安全并存;耕地资源、水资源以及农民的经济收入状况等均不容乐观,加之自然灾害加重,粮食生产的环境成本将随之增加,这将影响我国未来粮食安全。为此,本文提出了走农业集约化道路是解决我国粮食安全与改善环境的基本途径。 相似文献
90.