A novel wet-scrubbing process using Fe(VI) for simultaneous removal of SO2 and NO

The objective of this work was to develop a novel wet-scrubbing process using Fe(VI) for the simultaneous removal of gaseous NO and SO(2). The oxidation of SO(2) and NO with Fe(VI) was studied in aqueous solution at alkaline pH (9.0-11.0). A stoichiometric molar ratio for NO and SO(2) oxidation with Fe(VI) was determined to be nearly 3.0. Sulfate and nitrate was identified as final products by ion chromatography from the reaction at pH 9.0-11.0. The feasibility of simultaneous removal of multiple gas pollutants with the continuous feeding of ferrate in lab-scale was investigated from the view of industrial application. It was found that the removal efficiency of NO and SO(2) was enhanced with the increase of Fe(VI) concentration, more than 90% NO removal efficiency and 100% SO(2) removal efficiency were achieved by wet-scrubbing process using Fe(VI) at room temperature and ambient atmosphere. The results demonstrate that Fe(VI) could be an effective wet-scrubbing agent for the simultaneous removal of NO and SO(2).     

上海市水灾风险分析

利用1949-1990年上海市郊水灾历史灾情资料,分析其时空分布特征显示,自1949年以来,水灾受灾指数和相应粮食减产率呈阶段性下降,尤其自1977年水利控制片贯彻实施后,二者呈大幅度下降。各区县中,综合考虑水灾频次和受灾面积两个因素,得出南汇灾情最为严峻。最终,针对历史灾情资料缺乏、小样本数据使用传统统计模型进行风险分析精度不高的特点,基于信息扩散原理,利用正态信息扩散技术将单一的样本观测值变为一模糊集的模糊数学方法,对各区县受灾指数进行了风险分析,结果显示:南汇、浦东在受灾指数较低时,超越概率较高,即风险较高;崇明、金山在任一受灾指数下,风险都显示最高,受灾指数达0.8的超越概率为0.03345和0.01243,分别达到30年一遇和100年一遇。     

ASD-ICP-AES联用快速测定土壤中部分重金属

采用样品全自动消解系统(Automated Sample Digestion)对土壤样品进行前处理,采用ICP-AES对土样中的重金属元素一次性测定.通过优化实验,获得土壤中各种重金属的最佳消解条件.结果表明,经优化的消解程序A1能够快速、稳定消解土壤样品,并获得理想测试结果.经检验,ASD-ICP-AES联用的土样测...     

基于情景模拟的上海中心城区居民住宅的暴雨内涝风险评价

内涝是影响上海的主要灾害之一,上海城区居民住宅特别是旧式住宅容易因之受损乃至倒塌。基于情景模拟和指标体系方法,开展了上海中心城区住宅的风险评估。利用上海水务信息中心开发的内涝仿真模型,设置暴雨情景并对该情景下的内涝进行模拟,得到了区域水深分布状况,利用G IS技术求得每座住宅的水深,体现其在内涝中的暴露程度,并构造暴露性评价模型,综合反映区域总体暴露状况。根据旧式住宅较易受到影响的事实,构造脆弱性指数,最终衡量区域住宅面临灾害的整体风险状况,实现区域间居民住宅内涝风险的对比分析。设置了五十年一遇的暴雨内涝情景,针对中心城区各街道开展了实证研究,最终评价结果显示出的危险性、暴露性、脆弱性和风险分布规律,与实际情况基本符合。该方法可以为市政部门提供必要的信息,提高内涝灾害的管理水平。     

Evaluating the PM damage cost due to urban air pollution and vehicle emissions in Seoul, Korea

This study evaluated the prospective damage costs of PM(2.5) inhalation. We performed a health risk assessment based on an exposure-response function to estimate the annual population risk in the Seoul metropolitan city, Korea. Also, we estimated a willingness-to-pay (WTP) amount for reducing the mortality rate in order to evaluate a statistical life value. We combined the annual population risk and the value-of-statistical-life to calculate the damage cost estimate. In the health risk assessment, we applied the PM(2.5) relative risk to evaluate the annual population risk. We targeted an exposure population of 5,401,369 persons who were over the age of 30. Using a Monte-Carlo simulation for uncertainty analysis, we estimated that the population risk of PM(2.5) inhalation during a year in Seoul is 2181 premature deaths for acute exposure and 18,510 premature deaths for chronic exposure. The monthly average WTP for 5/1000 mortality reduction over ten years is $20.20 USD (95% C.I: $16.60-24.50) and the implied value-of-statistical-life (VSL) is $485,000 USD (95% C.I: $398,000-588,000). The damage cost estimate due to risk from PM(2.5) inhalation in Seoul is about $1057 million USD per year for acute exposure, and $8972 million USD per year for chronic exposure. It is important to note that this cost estimate does not reflect all health damage cost estimates in this urban area. This recommendation is a model for evaluating a mortality risk reduction and as such we must re-evaluate an integrated application of morbidity risk.     

顾及光滑拟合精度的地形曲线采样点布设规则研究

以加权平均抛物线拟合法为例,研究了顾及后期地形曲线光滑模型的采样点布设规则的确定问题.研究表明,对需要光滑拟合处理的地形曲线,除了传统的适当增加冗余采样点(采集质量检测点)外,还需要依据后期的光滑拟合模型,合理规划这些检测点的布点位置,才能有效保障地形曲线的科学采样与高保真重构.     

Ultrasound enhanced heterogeneous activation of peroxydisulfate by bimetallic Fe-Co/GAC catalyst for the degradation of Acid Orange 7 in water

Bimetallic Fe-Co/GAC （granular activated carbon） was prepared and used as heterogeneous catalyst in the ultrasound enhanced heterogeneous activation of peroxydisulfate （PS, S2O8 2-） process. The effect of initial pH, PS concentration, catalyst addition and stirring rate on the decolorization of Acid Orange 7 （AO7） was investigated. The results showed that the decolorization efficiency increased with an increase in PS concentration from 0.3 to 0.5 g/L and an increase in catalyst amount from 0.5 to 0.8 g/L. But further increase in PS concentration and catalyst addition would result in an unpronounced increase in decolorization efficiency. In the range of 300 to 900 r/min, stirring rate had little effect on AO7 decolorization. The catalyst stability was evaluated by measuring decolorization efficiency for four successive cycles.     

Photochemical properties and source of pollutants during continuous pollution episodes in Beijing, October, 2011

Beijing sufered from serious air pollution in October, 2011 with the occurrence of three continuous episodes. Here we analyze the pollution status of particulate matter, the relationship between the gaseous pollutants, physical and chemical properties of single particles, and the profile of watersoluble ions in PM2.5during the three episodes. Regional and photochemically aged air masses, which were characterized as having high values of O3and SO2, were hypothesized to have played a dominant role in the first episode. After mixing local air masses with freshly-emitted primary pollutants, the concentration of NOx continued to increase and the size of SO4 2, NO3 and NH4 +in the particle population continued to become smaller. The amount of elemental carbon-rich and organic carbonrich particles in the scaled single particles(0.2–2 μm) and water-soluble K+in PM2.5also increased in the episodes. All the available information suggests that the biomass or fuel burning sources in or around Beijing may have had a huge impact on the last two episodes.     

Hygroscopicity of particles generated from photooxidation of α-pinene under different oxidation conditions in the presence of sulfate seed aerosols

Smog chamber experiments were conducted to investigate the hygroscopicity of particles generated from photooxidation of α-pinene/NOx with different sulfate seed aerosols or oxidation conditions. Hygroscopicity of particles was measured by a tandem differential mobility analyzer （TDMA） in terms of hygroscopic growth factor （Gf）, with a relative humidity of 85%. With sulfate seed aerosols present, Gf of the aerosols decreased very fast before notable secondary organic aerosols （SOA） formation was observed, indicating a heterogeneous process between inorganic seeds and organic products might take place as soon as oxidation begins, rather than only happening after gas-aerosol partition of organic products starts. The final SOA-coated sulfate particles had similar or lower Gf than seed-free SOA. The hygroscopicity of the final particles was not dependent on the thickness but on the hygroscopicity properties of the SOA, which were influenced by the initial sulfate seed particles. In the two designed aging processes, Gf of the particles increased more significantly with introduction of OH radical than with ozone. However, the hygroscopicity of SOA was very low even after a long time of aging, implying that either SOA aging in the chamber was very slow or the Gf of SOA did not change significantly in aging. Using an aerosol composition speciation monitor （ACSM） and matrix factorization （PMF） method, two factors for the components of SOA were identified, but the correlation between SOA hygroscopicity and the proportion of the more highly oxidized factor could be either positive or negative depending on the speciation of seed aerosols present.     

非离子型表面活性剂强化混合菌降解间二甲苯的性能研究

从焦化废水厂的活性污泥中筛选间二甲苯混合降解菌,并研究非离子型表面活性剂吐温80(C_(64)H_(124)O_(26))对混合菌降解间二甲苯的强化作用.研究结果表明:驯化后的间二甲苯混合降解菌以产黄杆菌属(Rhodanobacter sp.)为主,占比41.2%;仅存在吐温80作为单一碳源时,高浓度的吐温80对混合降解菌没有明显的抑制作用;吐温80与间二甲苯共存时,当吐温80浓度为2 CMC,反应72 h后间二甲苯的降解率达到最高,为76%;提前12 h(较混合降解菌)投加浓度为2 CMC的吐温80,最利于菌种的生长繁殖及间二甲苯的降解.