Identification of marine bacteria affecting lithium adsorbents in seawater

Lithium manganese oxide–based adsorbents have been developed for the recovery of lithium from seawater. To maximize the recovery efficiency, it is important to prevent microfouling of lithium adsorbents by marine bacteria. To identify the marine bacteria that cause biofouling against the lithium adsorbents, lithium adsorbents were installed into a non-coated frame or a frame coated with an antifouling agent soaked in seawater. Microorganisms from the surface of lithium adsorbents were collected for 30 days at 10-day intervals, cultured in marine broth, isolated, and identified by 16S rDNA sequencing. Pseudoalteromonas and Vibrio were constituted to 35.6 and 28.8 % of total isolates, respectively, and were predominant in the non-coated frame, whereas Vibrio was poorly isolated (2.3 %) from the antifouling agent–coated frame. In this study, antifouling strategy for maximum lithium recovery efficiency in the marine area takes account of Pseudoalteromonas and Vibrio.     

Recycling behaviour and attitude: the case of the Hong Kong people and commercial and household wastes

The increasing environmental awareness caused by the green movement has led to changes in attitude towards our traditionally wasteful society. Recent surveys in Hong Kong have shown that waste recycling has gained increasing verbal support among its citizens. This paper reports on recent findings which reveals that some discrepancies exist between people's attitude and behaviour towards waste recycling. The implication of this phenomenon on how and when a waste recycling policy should be carried out is considerable. Two major types of barriers to waste recycling and reduction were evident. Technical barriers to recycling included lack of appropriate information, lack of conveniently located bins and of temporary storage space, whilst the most critical barrier to paper waste recycling was the presence of non-recyclable materials in some paper items. Psychological barriers included the attitude of being troubled, and that too little waste was involved to be worth the effort. Technical barriers were found to dominate in commercial paper waste recycling, and can usually be overcome while psychological barriers were more significant in household waste recycling and are more difficult to solve. Thus, it might be concluded that, if a large scale household waste recycling programme were in place in Hong Kong, more effort should be devoted towards educating the public, to eliminate as many psychological barriers as possible. Findings from attitude surveys on recycling can provide valuable information for policy makers. However, a review of the literature indicates that findings from attitudinal and self-reported behavioural surveys may exaggerate the proportion of those who have a favourable attitude towards the surveyed subject matter. Thus, it is prudent for policy makers to consider the response rate of the surveys also.     

A Comparison of Waste Reduction Practices and the New Environmental Paradigm in Four Southern Chinese Areas

On domestic waste recycling, it was found that source separation of domestic waste in mainland China was supported by 85% of the urban population and about 11–13% of the household waste was recovered and sold by the householders for financial gains. It was also found that the lower income group tended to recover a greater portion of waste, indicating that voluntary waste recovery activities in mainland China were carried out largely due to economic reasons. Thus, the Western type of source separation program in which residents are requested to separate recyclables for the community may not be welcomed in mainland China. In Hong Kong, despite the presence of community waste recovery programs, the recovery of domestic waste is only about 6% and is therefore less than those of the mainland Chinese cities surveyed. On the choice of source separation programs, it was found that Hong Kong people ranked familiarity a more important criterion than convenience. Therefore, the collection frequency of recyclables and time and place for setting out recyclables should be as similar to those of normal waste collection as possible to attract high participation in source separation programs.     

Simultaneous removal of COD and ammonium from landfill leachate using an anaerobic-aerobic moving-bed biofilm reactor system

The performance of a moving-bed biofilm reactor (MBBR) system with an anaerobic-aerobic arrangement was investigated to treat landfill leachate for simultaneous removal of COD and ammonium. It was found that the anaerobic MBBR played a major role in COD removal due to methanogenesis, and the aerobic MBBR acted as COD-polishing and ammonium removal step. The contribution of the anaerobic MBBR to total COD removal efficiency reached 91% at an organic loading rate (OLR) of 4.08 kgCOD/(m3d), and gradually decreased to 86% when feed OLR was increased to 15.70 kgCOD/(m3d). Because of the complementary function of the aerobic reactor, the total COD removal efficiency of the system had a slight decrease from 94% to 92% even though the feed OLR was increased from 4.08 to 15.70 kgCOD/(m3d). Hydraulic retention time (HRT) had a significant effect on NH+4-N removal; more than 97% of the total NH+4-N removal efficiency could be achieved when the HRT of the aerobic MBBR was more than 1.25 days. The anaerobic-aerobic system had a strong tolerance to shock loading. A decrease in COD removal efficiency of only 7% was observed when the OLR was increased by four times and shock duration was 24 h, and the system could recover the original removal efficiency in 3 days. The average sludge yield of the anaerobic reactor was estimated to be 0.0538 gVSS/gCOD rem.     

Effect of Fe-chelating complexes on a novel M2FC performance with ferric chloride and ferricyanide catholytes

As an effort to better utilize the microbial fuel cell (MFC) technology, we previously proposed an innovative MFC system named M2FC consisting of ferric-based MFC part and ferrous-based fuel cell (FC) part. In this reactor, ferric ion, the catholyte in the MFC part, was efficiently regenerated by the FC part with the generation of additional electricity. When both units were operated separately, the ferric-based MFC part produced approximately 1360 mW m⁻² of power density with FeCl₃ as catholyte and Fe-citrate as anolyte. The ferrous-based FC part with FeCl₃ as catholyte and Fe-EDTA as anolyte displayed the highest power density (1500 mW m⁻²), while that with ferricyanide as catholyte and Fe-noligand as anolyte had the lowest power density (380 mW m⁻²). The types of catholytes and chelating complexes as anolyte were found to play important roles in the reduction of ferric ions and oxidation of ferrous ion. Linear sweep voltammetry results supported that the cathode electrolytes were electrically active and these agreed well with the M2FC reactor performance. These results clearly showed that ligands played critical role in the efficiency and rate for recycling iron ion and thus the M2FC performance.     

Medical waste production at hospitals and associated factors

This study was conducted to evaluate the quantities of medical waste generated and the factors associated with the generation rate at medical establishments in Taiwan. Data on medical waste generation at 150 health care establishments were collected for analysis in 2003. General medical waste and infectious waste production at these establishments were examined statistically with the potential associated factors. These factors included the types of hospital and clinic, reimbursement payment by National Health Insurance, total number of beds, bed occupancy, number of infectious disease beds and outpatients per day. The average waste generation rates ranged from 2.41 to 3.26kg/bed/day for general medical wastes, and 0.19-0.88kg/bed/day for infectious wastes. The total average quantity of infectious wastes generated was the highest from medical centers, or 3.8 times higher than that from regional hospitals (267.8 vs. 70.3Tons/yr). The multivariate regression analysis was able to explain 92% of infectious wastes and 64% of general medical wastes, with the amount of insurance reimbursement and number of beds as significant prediction factors. This study suggests that large hospitals are the major source of medical waste in Taiwan. The fractions of medical waste treated as infectious at all levels of healthcare establishments are much greater than that recommended by the USCDC guidelines.     

Degradation of azo dye reactive violet 5 by TiO2 photocatalysis

The photocatalytic degradation of hydrolyzed reactive violet 5 (RV5) using titanium dioxide (TiO₂) was investigated in this study. The effects of various factors including the amount of photocatalyst, RV5 concentration, light intensity, and pH on photocatalytic degradation were evaluated. The photodegradation efficiency was 90% after 20 min of irradiation and reached nearly 100% after 80 min under the condition of pH 4 and temperature of 25°C. The decolorization rate typically followed first-order reaction, and increased markedly with increasing amount of photocatalyst, pH as well as light intensity. The total mineralization, based on total organic carbon (TOC) concentration was 53% after 20 min of UV light exposure and approached nearly 100% after 140 min. The final mineralization product was formylformamide. The photodegradation was faster than the mineralization, indicating that the intermediate products of decolorization were resistant to photodegradation. In this study, we found that toxicity of RV5 significantly decreased after decolorization. Our study suggests that the photocatalytic degradation treatment of RV5 with TiO₂ in wastewater is a simple and fast method.     

香港、广州、佛山和北京市政垃圾的成分比较及处理策略

现场采样分析了佛山市市政垃圾的组成和性质,比较了香港,广州,佛山和北京等４个城市市政垃圾的特征。４个城市的市政垃圾的组成和性质差别很大,北京市市政垃圾的煤灰含量很高,而香港的市政垃圾的张纸和塑料所占的百分比最大,根据香港固体废弃物的管理经验,广东省城市市政垃圾的处理方式和《中国二十一世纪仪程》,讨论了中国城市市政垃圾的性质和管理策略。     

Air pollution control costs and consumption pattern effects A regional analysis

The purpose of this study was to ascertain, through the use of an input-output model, the impact of air pollution control costs on income groups in the Philadelphia Region. The range of increases in consumption expenditure was found to be fairly narrow, with the middle-income group bearing the largest increase (2.9%) and the highest and lowest groups slightly lower increases (about 2%). This finding lends support to the proposition that all income groups would probably share the costs of control equally, which leads to a slightly regressive effect on income distribution. The sharing of the region's air quality costs by other areas was also analyzed.     

Biodegradable Chitosan-g-Poly(methacrylamide) Microspheres for Controlled Release of Hypertensive Drug

Chitosan-g-poly(methacrylamide) (CS-g-PMAAm) was synthesized by redox polymerization. The synthesized graft copolymers were used to prepare microspheres (MS) by water/oil (W/O) emulsion technique and cross-linked with glutaraldehyde (GA). Developed microspheres were encapsulated using enalapril maleate (ENAM) as a model drug (hypertension) and characterized by fourier transform infrared spectroscopy, differential scanning calorimetry and scanning electron microscopy. The physico-chemical properties of the microspheres were studied by calculating drug entrapment efficiency, and drug release kinetics. % of encapsulation efficiency (% EE) increased with increase in drug loading and methacrylamide (MAAm) content. The minimum % EE (65.2 ± 1.6) was observed in case of microsphere containing 40 % MAAm, 5 % ENAM and 10 mL glutaraldehyde. The release profiles indicate that formulation containing highest (10 mL) crosslinking agent microspheres has the slow release.