全文获取类型
收费全文 | 341篇 |
免费 | 9篇 |
国内免费 | 5篇 |
专业分类
安全科学 | 7篇 |
废物处理 | 20篇 |
环保管理 | 37篇 |
综合类 | 45篇 |
基础理论 | 85篇 |
环境理论 | 1篇 |
污染及防治 | 105篇 |
评价与监测 | 29篇 |
社会与环境 | 24篇 |
灾害及防治 | 2篇 |
出版年
2023年 | 4篇 |
2022年 | 6篇 |
2021年 | 13篇 |
2020年 | 8篇 |
2019年 | 8篇 |
2018年 | 13篇 |
2017年 | 16篇 |
2016年 | 24篇 |
2015年 | 9篇 |
2014年 | 22篇 |
2013年 | 30篇 |
2012年 | 21篇 |
2011年 | 28篇 |
2010年 | 25篇 |
2009年 | 20篇 |
2008年 | 15篇 |
2007年 | 11篇 |
2006年 | 12篇 |
2005年 | 9篇 |
2004年 | 12篇 |
2003年 | 14篇 |
2002年 | 5篇 |
2001年 | 4篇 |
2000年 | 8篇 |
1999年 | 5篇 |
1998年 | 5篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1991年 | 1篇 |
1987年 | 2篇 |
排序方式: 共有355条查询结果,搜索用时 31 毫秒
21.
Rogério Luiz Da Silva Claudia Pereira Da silva Sandro Navickiene 《Journal of environmental science and health. Part. B》2013,48(6):589-594
An extraction method based on matrix solid-phase dispersion was developed to determine pirimicarb, methyl parathion, malathion, procymidone, α -endosulfan and β -endosulfan in lettuce using gas chromatography-mass spectrometry. The best results were obtained using 4.0 g of lettuce, 2.0 g of silica as dispersant sorbent, 0.1 g of activated carbon as clean up sorbent and acetonitrile as eluting solvent. The method was validated using lettuce samples fortified with pesticides at six different concentration levels (0.1 to 2.0 mg/kg). Average recoveries (7 replicates) ranged from 50 to 120 %, with relative standard deviations between 0.6 and 8.0 %. Detection and quantification limits for lettuce ranged from 0.01 to 0.02 mg/kg and 0.04 to 0.10 mg/kg, respectively. 相似文献
22.
Stereoselective dissipation of epoxiconazole had been studied in grape and soil during plant growing under field conditions in this paper. A sensitive and rapid chiral method was developed and validated for the determination of epoxiconazole stereoisomers in grape and soil based on liquid chromatography coupled with triple quadrupole mass spectrometry (LC-MS/MS). Phenomenex Lux Cellulose-1 column was used for enantioseparation with a mixture of acetonitrile/water (90/10, v/v) as mobile phase at flow rate of 0.3 mL min−1. Fortified recoveries in grape and soil samples ranged from 76.0% to 91.9% and relative standard deviations were less than 11.4% with fortified levels of 0.025-1.0 mg kg−1. The limits of detection and quantification were 0.005 mg kg−1 and 0.025 mg kg−1, respectively, with linear calibration curves extending up to 5.0 mg kg−1. The field experimental results showed that dissipations of epoxiconazole stereoisomers in grape followed first-order kinetics (R2 > 0.92) and stereoselectivity occurred in 2 h after spraying. The (−)-stereoisomer with half-life of 9.3 d degraded faster than (+)-stereoisomer with that of 13.2 d, and resulted in relative enrichment of (+)-stereoisomer. However, the stereoisomeric dissipations in soil were triphasic (“increase-decrease-steady”) with lower dissipation rates, and also occurred with preferential degradation of (−)-stereoisomer under field condition. The results for stereoselective dissipations can be applied for food and environmental assessments of chiral pesticides. 相似文献
23.
Flávio Henrique Tincani Osório Luis Felipe Oliveira Silva Laercio Dante Stein Piancini Ana Carolina Barni Azevedo Samuel Liebel Flavia Yoshie Yamamoto Vivian Prá Philippi Marcos Leandro Silva Oliveira Claudia Feijó Ortolani-Machado Francisco Filipak Neto Marta Margarete Cestari Helena Cristina da Silva de Assis Ciro Alberto de Oliveira Ribeiro 《Environmental science and pollution research international》2014,21(15):9145-9160
The Tubarão River rises in Santa Catarina, Brazil, and has been historically affected by coal mining activities around its springhead. To evaluate its water conditions, an investigation regarding a possible decontamination gradient associated with the increased river flow toward the estuary, as well as the influence of seasonality over this gradient was performed through a series of biomarkers (vitellogenin, comet assay, lipid peroxidation, protein carbonylation, gluthatione, gluthatione S-transferase, acetylcholinesterase, light microscopy in liver, and scanning electron microscopy in gills) and chemical analysis (polycyclic aromatic hydrocarbons (PAHs) in bile and metal analysis in sediment) in the cichlid Geophagus brasiliensis. Two collections (summer and winter) were made in four distinct sites along the river, while sediments were sampled between those seasons. As expected, the contamination linked exclusively to mining activities was not observed, possibly due to punctual inputs of contaminants. The decontamination gradient was not observed, although seasonality seemed to have a critical role in the responses of biomarkers and availability of contaminants. In the summer, the fish presented higher histopathological damages and lower concentrations of PAHs, while in the winter they showed both higher genetic damage and accumulation of PAHs. The Tubarão suffers impacts from diverse activities, representing health risks for wild and human populations. 相似文献
24.
东洞庭湖湿地生态系统健康状态与水位关系研究 总被引:1,自引:0,他引:1
基于CBERS卫星遥感影像数据,以东洞庭湖国家级自然保护区为研究区,通过光谱特征分析建立决策树分类模型,提取东洞庭湖湿地的地物类型。以生态系统健康理论为基础,依据东洞庭湖湿地的特点,综合湿地生产力、组织结构、弹性和功能4个方面,建立湿地生态系统健康状态评价指标体系和评价模型,利用GIS技术,分析东洞庭湖湿地在2000~2006年10个时相的生态系统健康状态。结合城陵矶水文站的水位数据,探讨了东洞庭湖湿地健康状态与城陵矶水位之间的相关性,并利用2007年两个时相的数据进行检验。研究结果表明:东洞庭湖湿地健康状态与城陵矶水位之间存在着较大的相关性,当城陵矶水位达到30 m左右时,东洞庭湖湿地健康状态达到最佳值 相似文献
25.
Emmanuelle Caron Annemieke Farenhorst Xiying Hao Claudia Sheedy 《Journal of environmental science and health. Part. B》2013,48(6):495-504
Livestock manure applied to agricultural land is one of the ways natural steroid estrogens enter soils. To examine the impact of long-term solid beef cattle (Bos Taurus) manure on soil properties and 17β-estradiol sorption and mineralization, this study utilized a soil that had received beef cattle manure over 35 years. The 17β-estradiol was strongly sorbed and sorption significantly increased (P < 0.05) with increasing soil organic carbon content (SOC) and with an increasing annual rate of beef cattle manure. The 17β-estradiol mineralization half-life was significantly negatively correlated, and the total amount of 17β-estradiol mineralized at 90 days (MAX) was significantly positively correlated with 17β-estradiol sorption. The long-term rate of manure application had no significant effect on MAX, but the addition of fresh beef cattle manure in the laboratory resulted in significantly (P < 0.05) smaller MAX values. None of the treatments showed MAX values exceeding one-third of the 17β-estradiol applied. 相似文献
26.
Leonardo Sabatino Michele Scarangella Francesco Lazzaro Monica Scordino Giavanna Picariello Claudia Leotta 《Journal of environmental science and health. Part. B》2013,48(12):862-870
A reversed phase high-performance liquid chromatographic method (HPLC/MS-MS) has been developed and validated for detection of alkaloids matrine and oxymatrine in fertilizer with labeled enhancer plant defense activities. The analytical method was validated statistically. The results show a strong matrix effect, requiring quantification by standard addition method. The regression lines showed r2 > 0.994. Recoveries ranging from 97 to 104% were obtained for the fortification level of 0.01% wt wt?1 and the relative standard deviations ranged from 3 to 4% (n = 10). The limits of detection were below 0.0001% wt wt?1, while the limits of quantification did not exceed 0.0004% wt wt?1. The method is currently applied in ICQRF Laboratory of Catania on fertilized and corroborant plant extract collected in the Italian market in the frame of MIPAAF institutional quality control activity, with the aim to dectect these unpermitted active substances. 相似文献
27.
Irene Kranzioch Claudia Stoll Andreas Holbach Hao Chen Lijing Wang Binghui Zheng Stefan Norra Yonghong Bi Karl-Werner Schramm Andreas Tiehm 《Environmental science and pollution research international》2013,20(10):7046-7056
Several groups of bacteria such as Dehalococcoides spp., Dehalobacter spp., Desulfomonile spp., Desulfuromonas spp., or Desulfitobacterium spp. are able to dehalogenate chlorinated pollutants such as chloroethenes, chlorobenzenes, or polychlorinated biphenyls under anaerobic conditions. In order to assess the dechlorination potential in Yangtze sediment samples, the presence and activity of the reductively dechlorinating bacteria were studied in anaerobic batch tests. Eighteen sediment samples were taken in the Three Gorges Reservoir catchment area of the Yangtze River, including the tributaries Jialing River, Daning River, and Xiangxi River. Polymerase chain reaction analysis indicated the presence of dechlorinating bacteria in most samples, with varying dechlorinating microbial community compositions at different sampling locations. Subsequently, anaerobic reductive dechlorination of tetrachloroethene (PCE) was tested after the addition of electron donors. Most cultures dechlorinated PCE completely to ethene via cis-dichloroethene (cis-DCE) or trans-dichloroethene. Dehalogenating activity corresponded to increasing numbers of Dehalobacter spp., Desulfomonile spp., Desulfitobacterium spp., or Dehalococcoides spp. If no bacteria of the genus Dehalococcoides spp. were present in the sediment, reductive dechlorination stopped at cis-DCE. Our results demonstrate the presence of viable dechlorinating bacteria in Yangtze samples, indicating their relevance for pollutant turnover. 相似文献
28.
In this study the black worm Lumbriculus variegatus was tested for suitability as biomonitor for moderately contaminated sediments. The response capacity of the biotransformation system phase II enzyme glutathione-S-transferase (GST) and the oxidative defense enzyme catalase (CAT) to contaminated sediment and atrazine was investigated to establish them as sensitive biomarkers. To get an integrated view on the enzyme activity kinetics, increasing concentrations of the herbicide atrazine were applied to stimulate GST response, and relationship between enzyme activity and herbicide concentration was observed at various exposure durations. Furthermore, animals were exposed for up to 1 week to sediments of four typical urban river sections with high anthropogenic impact. L. variegatus was capable to accomplish the environmental stress and the selected enzymes showed elevation. Significant changes of GST (membrane-bound and soluble) were detected after at least 4 days of exposure to atrazine and contaminated sediments. Although CAT increase could be observed already after 1 day of exposure to sediments, an exposure time of one week is considerable for accurate interpretation of the enzymatic response. The clear enzymatic response of especially the membrane-bound GST indicated charges with organic lipophilic substances at all sampling sites. 相似文献
29.
Claudia Voelckel Tamara Krügel Klaus Gase Nadja Heidrich Nicole M. van Dam Robert Winz Ian T. Baldwin 《Chemoecology》2001,11(3):121-126
30.
Bethwell C Müller HJ Eulenstein F Graef F 《Journal of environmental monitoring : JEM》2012,14(5):1453-1461
EU legislation stipulates that GM crops have to be monitored for potential adverse environmental effects. Monitoring preferably should take place in the most exposed areas-the cultivated fields and their neighbouring environment. Current monitoring designs do not give detailed consideration to the different exposure intensities in agricultural practice. At the same time, the selection of specific, more exposed sites is difficult considering the dynamic and diversity of crop cultivation and rotation systems and their environments. We developed an approach for prioritising the monitoring of on-farm and neighbouring sites based on differing exposure levels using a minimum dataset of cultivation and land use information. Applying a Bt-maize cultivation scenario to Brandenburg, Germany, where presently no GM crops are cultivated, we systemised and categorised areas with different spatio-temporal exposure intensities including 50 m, 200 m and 1000 m buffers. These categories correspond to different suitabilities to serve as monitoring sites. Sites are prioritised using a sequential scheme. This yields an improved and objective spatial monitoring design providing detailed exposure information. This methodology is flexible and transferable to any agricultural setting, therefore enabling superior statistical comparisons between locations and regions and thus enhancing monitoring data quality. 相似文献