Treatment of mercury‐contaminated soils with activated carbon: A laboratory,field, and modeling study

A series of laboratory batch leaching tests was conducted to evaluate the performance of different activated carbons in stabilizing mercury in soils. Based on the results of these experiments, an amendment application rate of 5 percent powdered activated carbon (PAC) was selected for in situ field application at a former industrial facility. A geochemical model was also developed to simulate the interactions between mercury and activated carbon in vadose‐zone soils. Modeling was used to (1) better understand possible mercury sequestration mechanisms and (2) predict the in situ performance of PAC. Model results indicate dissolved mercury concentrations observed in batch tests are consistent with equilibrium partitioning of mercury between dissolved organic matter, soil organic matter, and PAC. Activated carbon is predicted to reduce dissolved mercury concentrations via two mechanisms: (1) the formation of stable mercury complexes on PAC surfaces and (2) the direct adsorption of dissolved organic matter that would otherwise be available for mercury dissolution. Study results demonstrate PAC effectiveness for site soils with mercury concentrations below 200 mg/kg. © 2010 Wiley Periodicals, Inc.     

Reactivity of sulfate radicals with natural organic matters

Advanced oxidation processes based on sulfate radicals (SO ₄ ^·? ) are capable of efficiently degrade organic pollutants from ground, surface and wastewaters. However, this degradation may be limited by aqueous natural organic matter (NOM). Here we measured the absolute rate constants of reaction of SO ₄ ^·? with four types of organic matter: two fulvic acids and two lake organic matter. We used laser flash photolysis technique to monitor the SO ₄ ^·? decay and the formation of the transients from organic matters. Reaction rate constants comprised between 1530 and 3500 s^?1 mgC^?1 L were obtained by numerical analysis of differential equations and the weighted average of the extinction coefficient of the generated organic matters radicals between 400 and 800 M^?1 cm^?1.     

When is female leadership an advantage? Coordination requirements,team cohesion,and team interaction norms

This study seeks to understand to what extent and in what contexts women leaders may be advantageous for teams. More specifically, this study examines how team leader gender relates to team cohesion, cooperative learning, and participative communication. Furthermore, the study argues that advantages derived from female leadership may be contingent on teams' coordination requirements. I propose that as teams' coordination requirements increase (i.e., with functional diversity, size, and geographic dispersion), teams with women leaders report more cohesion and more cooperative and participative interaction norms than those with men leaders. I aggregated survey responses from the members of 82 teams in 29 organizations at the team level. Findings from hierarchical linear modeling analyses suggest that female leadership is more positively associated with cohesion on larger and more functionally diverse teams and more positively associated with cooperative learning and participative communication on larger and geographically dispersed teams. These results call for more research on boundary conditions on the relationship between leader gender and team outcomes, on the role of relational leadership on complex and diverse teams and, ultimately, on the potential mediating role of cohesion and team interaction norms on the relationship between leader gender and team performance. Copyright © 2015 John Wiley & Sons, Ltd.     

A Review of the Main Driving Factors of Forest Fire Ignition Over Europe

Knowledge of the causes of forest fires, and of the main driving factors of ignition, is an indispensable step towards effective fire prevention policies. This study analyses the factors driving forest fire ignition in the Mediterranean region including the most common human and environmental factors used for modelling in the European context. Fire ignition factors are compared to spatial and temporal variations of fire occurrence in the region, then are compared to results obtained in other areas of the world, with a special focus on North America (US and Canada) where a significant number of studies has been carried out on this topic. The causes of forest fires are varied and their distribution differs among countries, but may also differ spatially and temporally within the same country. In Europe, and especially in the Mediterranean basin, fires are mostly human-caused mainly due arson. The distance to transport networks and the distance to urban or recreation areas are among the most frequently used human factors in modelling exercises and the Wildland-Urban Interface is increasingly taken into account in the modelling of fire occurrence. Depending on the socio-economic context of the region concerned, factors such as the unemployment rate or variables linked to agricultural activity can explain the ignition of intentional and unintentional fires. Regarding environmental factors, those related to weather, fuel and topography are the most significant drivers of ignition of forest fires, especially in Mediterranean-type regions. For both human and lightning-caused fires, there is a geographical gradient of fire ignition, mainly due to variations in climate and fuel composition but also to population density for instance. The timing of fires depends on their causes. In populated areas, the timing of human-caused fires is closely linked to human activities and peaks in the afternoon whereas, in remote areas, the timing of lightning-caused fires is more linked to weather conditions and the season, with most such fires occurring in summer.     

Mapping wildland-urban interfaces at large scales integrating housing density and vegetation aggregation for fire prevention in the South of France

Every year, more than 50,000 wildland fires affect about 500,000 ha of vegetation in southern European countries, particularly in wildland-urban interfaces (WUI). This paper presents a method to characterize and map WUIs at large scales and over large areas for wildland fire prevention in the South of France. Based on the combination of four types of building configuration and three classes of vegetation structure, 12 interface types were classified. Through spatial analysis, fire ignition density and burned area ratio were linked with the different types of WUI. Among WUI types, isolated WUIs with the lowest housing density represent the highest level of fire risk.